Effect of degree of polymerization on gelation and flow processability of poly(vinyl chloride)

The effect of degree of polymerization (DP) on the gelation and flow processability of poly(vinyl chloride) (PVC) was studied. Sheets with adjusted degree of gelation were prepared by rolling rigid pipe formulation suspension PVC compounds with DPs of 800, 1050 and 1300 by changing the milling temperature. Their degrees of gelation were measured with DSC and their capillary flow properties were measured with a capillary rheometer at 150, 170 and 190°C and the effect of DP on the relation between gelation and flow processabilities was studied. Because of the higher shearing heat during milling, the sample with the higher DP had a higher history temperature and thus tended to show a higher degree of gelation. The viscosity increased as the gelation increased. The dependency of viscosity on DP was higher at higher milling and extrusion temperatures and thus at a higher degree of gelation and a lower shear rate. This was assumed to be attributed to the more prominent uniform molecular flow as against the particle flow. The die swell increased with increasing the milling and extrusion temperatures and hence with increasing the gelation. A sample with a lower DP tended to show a larger die swell and this tendency was even more pronounced at the higher extrusion temperature. The melt fracture easily occurred when a sample with advanced gelation was extruded at low temperature. Whereas at low milling temperatures a sample with the lower DP showed a lower critical shear rate at onset of melt fracture, and thus easily generating melt fracture, at high milling temperatures it showed a higher critical shear rate and hence scarcely generated melt fracture. These experimental results were explained by the fact and concept that a sample with a lower DP shows a higher increase in the gelation during extrusion and/or the slighter feature of particle flow as against the uniform molecular flow at the same gelation level. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 1915–1938, 2004     

尼龙66/乙烯-醋酸乙烯酯共聚物接枝马来酸酐共混体系的研究(Ⅰ)乙烯-醋酸乙烯酯共聚物熔融接枝马来酸酐的制备与表征

以马来酸酐为单体、过氧化物为引发剂，采用熔融挤出法制备了乙烯-醋酸乙烯酯共聚物接枝马来酸酐(EVA-g-MAH)。重点讨论了不同型号的EVA、过氧化物引发剂品种及用量、单体MAH用量和加工工艺条件等因素时接枝反应的影响。通过化学滴定法和傅立叶红外光谱法(FTlR)证实部分马来酸酐确实以化学键连接到EVA分子链上。与聚乙烯(PE)、聚丙烯(PP)相比，EVA中由于含有醋酸乙烯(VA)基团，极性较大，与MAH的相客性较好，因而在相同的条件下接枝效率也更大；而且VA含量越大，越有利于接枝反应。比较不同的过氧化物引发剂BPO和DCP。发现DCP的引发效果更好。实验结果还表明，在EVA进行接枝反应的同时存在着交联反应，引发剂DCP的用量不宜过高，为得到接枝率适中，交联度很小的接枝产物，还要选择合适的MAH与DCP的用量。     

CGA560增强助磨剂在水泥粉磨中的应用研究

研究了CGA560增强助磨剂在水泥粉磨中对台时产量和水泥质量的影响。试验结果表明:在磨机状况不改变的条件下,CGA560增强助磨剂的加入可提高磨机产量10%-30%;同时可有效减少过粉磨现象,优化水泥颗粒级配,提高了水泥粉磨细度及比表面积;因而使水泥强度等性能得到了明显改善和提高。     

Influence of chitosan characteristics on coagulation and flocculation of organic suspensions

Several samples of chitosan with different degrees of deacetylation and of different molecular weights were tested for the coagulation–flocculation of organic suspensions. Organic suspensions were prepared by mixing mushroom powder with tap water. Experiments were carried out at pH 5, pH 7, and pH 9. Because decreasing the pH reduced the amount of chitosan required to reach the required turbidity, at pH 9, a high concentration of chitosan was required to achieve the required treatment levels, whereas the difference was less significant between pH 7 and pH 5 (the required concentration of chitosan was halved). Though viscosity, correlated to the molecular weight of chitosan, affected treatment performance, its influence on the efficiency of coagulation–flocculation could be substantially reduced by slightly increasing the concentration of the polymer. This is of importance in the processing of industrial effluents: the aging of a chitosan solution, which may cause partial depolymerization, and loss of viscosity, will have a limited impact on process efficiency. The degree of deacetylation also has a limited effect on treatment performance, especially when the degree of deacetylation exceeds 90%. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 2070–2079, 2005     

基于红外偏振的入射角确定

提出基于红外光的偏振度来确定透明物体形状检测中的入射角的方法。在可见光域,偏振度是入射角的二阶函数,即在布儒斯特角两侧各有一个入射角,不能唯一确定入射角。而在红外域,偏振度与入射角之间是一一对应关系,可以对可见光域的两个入射角做出区分,得到正确的入射角。这种方法提高了透明物体形状检测的精度,还可用于复杂形状的物体检测。     

未确知均值聚类

利用未确知系统理论分析特征对样本分类所作贡献,定义特征的分类权重,并作为启发性知识用于确定样本与各类间的加权距离及样本属于各类的隶属度,建立未确知均值聚类算法。IRIS数据检验表明,未确知均值聚类算法误判样本数少、收敛速度快、鲁棒性好,是一种实用、有效的无监督聚类算法。     

基于满意度和GA的区间系数多目标规划求解*

在缺乏先验知识的前提下,提出了约束条件的一种满意度,按照遗传算法求解多目标问题的步骤,求出非劣解集;然后根据适应度大小选出最优解;最后算例证明了该算法的有效性和可行性。     

具偏差变元泛函微分方程周期解的存在定理

利用Mawhin重合度拓展定理研究了一类具偏差变元的泛函微分方程x″（t）＋h（x（t））f（x′（t））＋g（x（t-τ（t）））=p（t）的周期解问题,得到了周期解存在性的若干新结果,推广了已有的结果。     

R&D项目价值评估的灰色B-S模型

针对传统净现值法不能有效评估RD项目价值的缺点,探讨了RD项目价值评估的适用方法,建立了基于区间灰数的RD项目价值评估灰色B-S模型,通过实例说明了该模型的有效性,并与传统净现值法的评估结果进行比较.结果表明,实物期权方法在评估RD项目价值时具有优势,为RD项目投资决策提供了一条新思路.     

基于模糊决策的P2P流量优化

在研究优化P2P网络流量的过程中,通过对P2P网络的特殊性质的分析,确定其速度、时间、跳数I、SP数以及占用带宽比为流量优化的切入点,并引入模糊数学优化理论的思维,对这些参数进行模糊数学分析,在传统优化方法基础上通过模糊优化的方法达到对P2P网络流量进行优化的目的.