全文获取类型
收费全文 | 40395篇 |
免费 | 3994篇 |
国内免费 | 2318篇 |
专业分类
电工技术 | 1055篇 |
技术理论 | 1篇 |
综合类 | 2542篇 |
化学工业 | 11347篇 |
金属工艺 | 2258篇 |
机械仪表 | 1701篇 |
建筑科学 | 2117篇 |
矿业工程 | 454篇 |
能源动力 | 759篇 |
轻工业 | 1165篇 |
水利工程 | 318篇 |
石油天然气 | 2479篇 |
武器工业 | 434篇 |
无线电 | 3869篇 |
一般工业技术 | 7051篇 |
冶金工业 | 3323篇 |
原子能技术 | 215篇 |
自动化技术 | 5619篇 |
出版年
2024年 | 223篇 |
2023年 | 725篇 |
2022年 | 945篇 |
2021年 | 1216篇 |
2020年 | 1234篇 |
2019年 | 1106篇 |
2018年 | 1005篇 |
2017年 | 1280篇 |
2016年 | 1292篇 |
2015年 | 1309篇 |
2014年 | 1989篇 |
2013年 | 2240篇 |
2012年 | 2424篇 |
2011年 | 2984篇 |
2010年 | 2253篇 |
2009年 | 2393篇 |
2008年 | 2274篇 |
2007年 | 2708篇 |
2006年 | 2563篇 |
2005年 | 2184篇 |
2004年 | 1948篇 |
2003年 | 1721篇 |
2002年 | 1529篇 |
2001年 | 1335篇 |
2000年 | 1015篇 |
1999年 | 860篇 |
1998年 | 757篇 |
1997年 | 593篇 |
1996年 | 462篇 |
1995年 | 386篇 |
1994年 | 355篇 |
1993年 | 294篇 |
1992年 | 226篇 |
1991年 | 155篇 |
1990年 | 114篇 |
1989年 | 103篇 |
1988年 | 85篇 |
1987年 | 38篇 |
1986年 | 38篇 |
1985年 | 75篇 |
1984年 | 61篇 |
1983年 | 47篇 |
1982年 | 41篇 |
1981年 | 13篇 |
1980年 | 13篇 |
1979年 | 9篇 |
1977年 | 11篇 |
1964年 | 6篇 |
1963年 | 6篇 |
1961年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
Paul J. Flory 《Polymer International》1985,17(2):96-102
The earliest investigations on rubber elasticity, commencing in the 19th century, were necessarily limited to phenomenological interpretations. The realisation that polymers consist of very long molecular chains. commencing c. 1930, gave impetus to the molecular theory of rubber elasticity (1932-). according to which the high deformability of an elastomer, and the elastic force generated by deformation, stem from the configurations accessible to long molecular chains. Theories of rubber elasticity put forward from 1934-1946 relied on the assumption that the junctions of the rubber network undergo displacements that are affine in macroscopic strain. The theory of James and Guth (1947) dispensed with this premise, and demonstrated instead that the mean positions of the junctions of a ‘phantom’ network consisting of Gaussian chains devoid of material properties are affine in the strain. The vital significance of the distinction between the actual distribution of chain vectors in a network and their distribution if the junctions would be fixed at their mean positions went unnoticed for nearly 30 years. Experimental investigations, commencing with the incisive work of Gee in 1946. revealed large departures from the relationship of stress to strain predicted by the theories cited. This discrepancy prompted extensive studies, theoretical and experimental, during succeeding years. Inquiry into the fundamentals of polymer networks, formed for example by interlinking very long polymer molecules, exposed the need to take account of network imperfections, typically consisting of chains attached at only one end to a network junction. Various means were advocated to make corrections for these imperfections. The cycle rank ζ of the network has been shown (1976) to be the fundamental measure of its connectivity, regardless of the junction functionality and pattern of imperfections. Often overlooked is the copious interpenetration of the chains comprising typical elastomeric networks. Theories that attempt to represent such networks on a lattice are incompatible with this universal feature. Moreover, the dense interpenetration of chains may limit the ability of junctions in real networks to accommodate the fluctuations envisaged in the theory of phantom networks. It was suggested in 1975 that departures from the form predicted for the elastic equation of state are due to constraints on the fluctuations of junctions whose effect diminishes with deformation and with dilation. Formulation of a self-consistent theory based on this suggestion required recognition of the non-affine connection between the chain vector distribution function and the macroscopic strain in a real network, which may partake of characteristics of a phantom network in some degree. Implementation of the idea was achieved through postulation of domains of constraint affecting the equilibrium distribution of fluctuations of network junctions from their mean positions. This led in due course to a theory that accounts for the relationship of stress to strain virtually throughout the ranges of strain accessible to measurement. The theory establishes connections between structure and elastic properties. This is achieved with utmost frugality in arbitrary parameters. 相似文献
32.
3D characterization and analysis of particle shape using X-ray microtomography (XMT) 总被引:2,自引:0,他引:2
C.L. Lin 《Powder Technology》2005,154(1):61-69
33.
34.
Dongchang Sun Liyong Tong 《International journal for numerical methods in engineering》2004,60(11):1911-1932
A novel finite element model is presented for static and dynamic analysis of composite plates integrated with a laminated piezoelectric layer, a host laminated composite plate and an adhesive layer between them. A new adhesive element is developed which includes both peel and shear effects in the adhesive layer based on first‐order shear deformation plate theory. The thin adhesive layer between the piezoelectric layer and the host plate is modelled by assuming that it carries constant shear and peel strains throughout its thickness. In addition, a weighted static shape control scheme for finding the optimal voltage distribution for static shape control is given. By selecting different weighting matrices, a variety of items such as displacements, slopes, curvatures, strains and even generalized forces, can be included in finding the optimal actuating voltage for static shape control. The present model is validated by comparing with those results available in the literature. The numerical results show that the weighted linear least method can give a satisfactory voltage distribution to best match the desired shape. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
35.
Todd M. Alam Joshua U. Otaigbe Dave Rhoades Gregory P. Holland Brian R. Cherry Paul G. Kotula 《Polymer》2005,46(26):12468-12479
Nanostructured polymer blends prepared via anionic ring opening polymerizations of cyclic monomers in the presence of a pre-made polymer melt exhibit a number of special properties over traditional polymer blends and homopolymers. Here, we report on a simple and versatile method of in situ polymerization of macrocyclic carbonates in the presence of a maleic anhydride polypropylene (mPP) matrix and a surface-active compatibilizer (i.e. PC grafted onto a mPP backbone generated in situ) to yield a micro- and nanostructured polymer blends consisting of a polycarbonate (PC) minor phase, and a polypropylene (PP) major phase. By varying the processing conditions and concentration of the macrocyclic carbonate it was possible to reduce the size of the PC dispersions to an average minor diameter of 150 nm. NMR and TEM characterizations indicate that the PC dispersions do not influence crystal content in the PP phase. Overall, the results point to a simple strategy and versatile route to new polymeric materials with enhanced benefits. 相似文献
36.
Bedich ika Helena Bendov Ivan Macha
《Chemical Engineering and Processing: Process Intensification》2005,44(12):1312-1319
A procedure has been proposed for the estimation of the terminal falling velocity of non-spherical particles moving in a Carreau model fluid in the transition flow region. The procedure is based on a modification of the relationship formerly developed for the fall of spherical particles including the particle dynamic shape factor. The suitability of the proposed procedure has been confirmed by good agreement between experimental and calculated terminal falling velocity data. In the experiments, the terminal falling velocity of short cylinders and rectangular prisms in polymer solutions of different measure of shear thinning and elasticity has been measured. 相似文献
37.
38.
M. Guerioune Y. Amiour W. Bounour O. Guellati A. Benaldjia A. Amara N. E. Chakri M. Ali-Rachedi D. Vrel 《International Journal of Self-Propagating High-Temperature Synthesis》2008,17(1):41-48
Aiming at preparation of shape memory alloys (SMAs), we explored the SHS of Cu1 − x
Zn1 − y
Al1 − z
alloys (0.29 < x < 0.30, 0.74 < y < 0.75, and 0.83 < z < 0.96). The most pronounced shape memory effect was exhibited by the alloys of the following compositions (wt %): (1) Cu(70.6)Zn(25.4)Al(4.0),
(2) Cu(70.1)Zn(25.9)Al(4.0), and (3) Cu(69.9)Zn(26.1)Al(4.0). The effect of process parameters on the synthesis of CuZnAl
alloys was studied by XRD, optical microscopy, and scanning electron microscopy (SEM). The grain size of CuZnAl was found
to depend on the relative amount of the primary CuZn and AlZn phases. Changes in the transformation temperature and heat of
transformation are discussed in terms of ignition intensity and compaction. Mechanism of the process depends on the level
of the temperature attained relative to the melting point of components. At the melting point of AlZn, the process is controlled
by the solid-state diffusion of AlZn into a product layer. The ignition temperature for this system depends on the temperature
of the austenite-martensite transformation in CuZnAl alloys. The composition and structure of the products was found to markedly
depend on process parameters. The SHS technique has been successfully used to prepare a variety of SMAs.
相似文献
39.
Jiang Minhong Gu Zhengfei Cheng Gang 《中国稀土学报(英文版)》2005,23(6):723-723
Polymer matrix RE-Fe giant magnetostrictire composite (GMPC) was prepared using bonding and magnetic field forming technique, and magnetostriction of samples was measured for different compressive stress. The experimental results show thai there is certain compressive effect in GMPC. And the influence of compressive stress on magnetostriction of sample was investigated. It offers essential reference for application and device design of GMPC. 相似文献
40.
Takeshi Kondo Sang Min Lee Michal Malicki Benoit Domercq Seth R. Marder Bernard Kippelen 《Advanced functional materials》2008,18(7):1112-1118
We report on a single‐layer organic memory device made of poly(N‐vinylcarbazole) embedded between an Al electrode and ITO modified with Ag nanodots (Ag‐NDs). Devices exhibit high ON/OFF switching ratios of 104. This level of performance could be achieved by modifying the ITO electrodes with some Ag‐NDs that act as trapping sites, reducing the current in the OFF state. Temperature dependence of the electrical characteristics suggest that the current of the low‐resistance state can be attributed to Schottky charge tunnelling through low‐resistance pathways of Al particles in the polymer layer and that the high‐resistance state can be controlled by charge trapping by the Al particles and Ag‐NDs. 相似文献