全文获取类型
收费全文 | 6314篇 |
免费 | 781篇 |
国内免费 | 271篇 |
专业分类
电工技术 | 73篇 |
综合类 | 339篇 |
化学工业 | 3529篇 |
金属工艺 | 219篇 |
机械仪表 | 75篇 |
建筑科学 | 256篇 |
矿业工程 | 127篇 |
能源动力 | 152篇 |
轻工业 | 269篇 |
水利工程 | 45篇 |
石油天然气 | 268篇 |
武器工业 | 11篇 |
无线电 | 425篇 |
一般工业技术 | 1331篇 |
冶金工业 | 161篇 |
原子能技术 | 58篇 |
自动化技术 | 28篇 |
出版年
2024年 | 18篇 |
2023年 | 119篇 |
2022年 | 174篇 |
2021年 | 221篇 |
2020年 | 238篇 |
2019年 | 207篇 |
2018年 | 235篇 |
2017年 | 269篇 |
2016年 | 255篇 |
2015年 | 275篇 |
2014年 | 386篇 |
2013年 | 410篇 |
2012年 | 470篇 |
2011年 | 450篇 |
2010年 | 333篇 |
2009年 | 384篇 |
2008年 | 331篇 |
2007年 | 361篇 |
2006年 | 332篇 |
2005年 | 313篇 |
2004年 | 243篇 |
2003年 | 236篇 |
2002年 | 198篇 |
2001年 | 166篇 |
2000年 | 135篇 |
1999年 | 103篇 |
1998年 | 78篇 |
1997年 | 59篇 |
1996年 | 60篇 |
1995年 | 50篇 |
1994年 | 37篇 |
1993年 | 26篇 |
1992年 | 40篇 |
1991年 | 38篇 |
1990年 | 43篇 |
1989年 | 30篇 |
1988年 | 3篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1959年 | 2篇 |
1951年 | 5篇 |
排序方式: 共有7366条查询结果,搜索用时 15 毫秒
101.
采用两步法以非离子Tween 80为模板剂合成硅基介孔材料,研究了pH对值介孔材料结构的影响.结果表明:没有氟离子存在且模板剂浓度低(2wt.%)的条件下,在弱酸性环境中可以制备有序的MSU-X类硅基介孔材料,本研究表明不同酸度条件下、不同反应温度对产品的有序性有不同的影响. 相似文献
102.
以钛酸丁酯(TBT)为钛源,离子液体1-正己基-3-甲基咪唑溴盐([Hmim]Br)为模板剂和老化液,采用溶胶-凝胶法在低温常压下制备了锐钛矿相TiO2气凝胶。通过XRD、FT-IR、BET等方法对样品进行表征。结果表明,以2.5mol/L的[Hmim]Br作为老化液所制备的样品具有最佳的性能参数,其块体尺寸、比表面积、平均孔径和孔体积分别为14mm、208.1m2/g、28.13nm及0.293cm3/g。 相似文献
103.
原人参二醇类皂苷混合物经人参皂苷酶生物转化后可生成F2、C-Mc等7~10种稀有人参皂苷。天然人参中不含人参皂苷C-Mc,且F2的含量极低。在生物转化所得的人参二醇类皂苷酶反应产物中,分离纯化得到稀有人参皂苷F2与C-Mc,并进行HPLC检测。反应后得到粗产品40g,经脱糖脱色和硅胶柱分离后,成功得到稀有人参皂苷F23.49g,纯度为98.2%,得率8.72%;得到C-Mc 0.70g,纯度为82.2%,得率为1.80%。成功分离出了F2和C-Mc制品,建立了初步的分离制备方法。 相似文献
104.
采用硅溶胶、耐碱型苯丙乳液、云母粉、二氧化钛等颜填料制备有机-无机复合型建筑用非透明封闭底漆,以对比测试方法重点对其附着力、耐碱、抗渗透等性能进行验证,同时探讨了乳液、颜填料的选择因素以及硅溶胶对体系的作用和影响。 相似文献
105.
K. Rózga-Wijas U. Mizerska W. Fortuniak J. Chojnowski R. Hałasa W. Werel 《Journal of Inorganic and Organometallic Polymers and Materials》2007,17(4):605-613
Three types of silica particles modified with vinyl groups were obtained: (i) xerogel formed by hydrolytic polycondensation
of the mixture of tetramethoxysilane (TMOS) and 1,1,1,7−tetramethoxy-3,5,7-trimethyl-3,5,7-trivinyltetrasiloxane, (ii) mesoporous
silica obtained from the same precursors in the presence of the cetyltrimethylammonium bromide (CTAB), and (iii) commercial
Fluka silica gel 60A with a vinyltriethoxysilane-treated surface. Vinyl groups on these silica materials were transformed
into silyl chloride by hydrosilylation with HMe2SiCl. These groups were used to graft living polysiloxane that was synthesized by anionic ring-opening polymerization of 2,4,6-tri(3-chloropropyl)-2,4,6-trimethylcyclotrisiloxane
and initiated by BuLi. Chloropropyl groups on the grafted polymer were used to quaternize N,N-dimethyl-n-octylamine. Silica particles with grafted polysiloxane having quaternary ammonium salt (QAS) groups pendant to polymer chains
were obtained. Silica material with QAS groups directly attached to the surface were generated by the action of N,N-dimethyl-n-octylamine on particles obtained by the sol–gel process involving tetraethoxysilane (TEOS) with 3-chloropropyltriethoxysilane.
The bacteriocidal properties of all these materials were tested in water suspension against five representative strains for
Gram-positive and Gram-negative bacteria. Some of the silica–polysiloxane hybrid materials have good antibacterial properties
against Gram-positive strains, but not as good as the non-tethered QAS-substituted polysiloxane in water solution. The QAS
groups that are directly bonded to the silica material surface are inactive. 相似文献
106.
107.
介孔氧化硅薄膜在膜分离、传感器件、异相催化、低介电常数微电子绝缘片的应用方面具有潜在应用价值。首先简要介绍了介孔薄膜的制备途径,然后重点综述了介孔氧化硅薄膜的研究进展。 相似文献
108.
Malte H.G. Wichmann Jan Sumfleth Marino Quaresimin Karl Schulte 《Engineering Fracture Mechanics》2006,73(16):2346-2359
Nanoparticles and especially carbon nanotubes (CNTs) provide a high potential for the modification of polymers. They are very effective fillers regarding mechanical properties, especially toughness. Furthermore, they allow the implication of functional properties, which are connected to their electrical conductivity, into polymeric matrices. In the present paper, different nanoparticles, as fumed silica and carbon black, were used to optimise the epoxy matrix system of a glass-fibre-reinforced composite. Their nanometre-size enables their application as particle-reinforcement in FRPs produced by the resin-transfer-moulding method (RTM), without being filtered by the glass-fibre bundles. Additionally, an electrical field was applied during curing, in order to enhance orientation of the nanofillers in z-direction. The interlaminar shear strengths of the nanoparticle modified composites were significantly improved (+16%) by adding only 0.3 wt.% of CNTs. The interlaminar toughness GIc and GIIc was not affected in a comparable manner. The laminates containing carbon nanotubes exhibited a relatively high electrical conductivity at very low filler contents, which allows the implication of functional properties, such as stress-strain monitoring and damage detection. 相似文献
109.
Seogil Oh Jungwoo Moon Taewook Kang Surin Hong Jongheop Yi 《Journal of Electroceramics》2006,17(2-4):999-1003
The use of surface plasmon resonance (SPR) spectroscopy has been applied to a wide variety of fields such as biosensors and
surface analysis instruments. In general, a SPR substrate is prepared using self-assembled monolayer (SAM) method of organic
molecules as receptor for the target on a layer of gold or silver. However, mesoporous inorganic materials such as SBA-15
have benefits as sensor substrate for SPR. Mesoporous silica has a large surface area which receptor molecule can be attached
and has a rigid body which has an excellent stability in the extreme condition compared to organic sensing layer. We prepared
an organic modified mesoporous silica and successfully immobilized it on a gold surface, in an attempt to use as a substrate
for SPR spectroscopy. For the comparison of sensitivity of prepared substrate, Pt2+ detection was selected as a model system. Substrate prepared in this study exhibited the capability of selective sensing
for Pt2+ ions. 相似文献
110.
硅橡胶力学性能差,需要补强,这是硅橡胶产品开发的关键。本文报道用溶胶沉淀法制备具有核-壳结构的纳米CaCO3/SiO2复合粒子,将该复合粒子替代部分二氧化硅作为硅橡胶的补强材料。通过实验确定它对硅橡胶的力学性能和热稳定性能的影响。比较用纳米CaCO3/SiO2复合粒子以及用CaCO3补强的硅橡胶,前者不仅物理力学性能较佳,而且能降低材料的成本。但后者耐热性能较好。 相似文献