压力和温度对瓦斯扩散规律的影响研究

针对瓦斯吸附解吸法测定瓦斯扩散系数时局限于颗粒煤、无法施加围压且气体压力不能任意设定等问题,采用规则块煤结合气相色谱分析法测定瓦斯在块煤中的扩散系数,分析了不同气体压力、温度下块煤瓦斯扩散规律。实验结果表明,随着气体压力的增大,煤基质吸附气体增加且发生膨胀变形,从而孔隙减小,扩散阻力增大,扩散系数减小;随着温度的升高,气体分子运动速度增大,扩散动力增强,扩散系数变大。     

Micromachined sol–gel carbon nanotube/SnO2 nanocomposite hydrogen sensor

A novel micromachined single wall carbon nanotube (SWCNT) reinforced nanocrystalline tin dioxide gas sensor has been developed. The presence of SWCNT in SnO₂ matrix was realized by a spin-on sol–gel process. The SWCNT/SnO₂ sensor's sensitivity for hydrogen detection has greatly increased by a factor of three, in comparison to that of pure SnO₂ sensor. The novel sensor also lowers the working temperature, response time and recovery time. The greatly improved performances are mainly attributed to the effective gas accessing nano passes through SWCNT plus the smaller distance between adjacent gas accessing boundaries formed by the distribution of tiny SWCNTs. Therefore, both the spatial requirement (D ≤ 2L, D is the distance between adjacent gas accessing boundaries and L is the space charge layer thickness) and surficial requirement (adequate gas activation area) are met and the maximum inherent sensitivity of SnO₂ is achieved.     

基于子空间方法的精馏塔系统辨识建模研究

子空间辨识方法作为一种有效的针对多输入-多输出系统(MIMO)的辨识建模方法近年来受到广泛的重视.目前主要采用的子空间辨识算法只能适用于白噪声环境,而实际的工业现场数据很多是受到较大有色噪声干扰的.针对问题采用了一种新的子空间辨识算法,利用马尔可夫参数用于处理随机性部分,同时引入辅助变量用以去除噪声的干扰,能够适用于存在较大有色噪声干扰情况下的辨识建模,并可得到对象的无偏模型,建模的精度优于通常所采用的子空间辨识算法.通过对精馏塔仿真模型的辨识结果证明了该方法的可行性和有效性,以及在实际工业过程对象建模中良好的应用前景.     

An overview on microwave processing of material: A special emphasis on glass melting

Material processing adopting microwave heating has emerged as an alternative tool owing to faster processing, a cleaner environment, and several other advantages. This review provides a summary of recent reports of microwave synthesis of materials. This study reviews the use of microwave energy for application in several material processing technologies apart from food processing. A special emphasis has been made in the processing of glass adopting microwave energy. Melting of glass comprising SiO₂, P₂O₅, B₂O₃ as the main building block has been discussed. It has been revealed that silica, a microwave transparent material as reported earlier, can be heated under microwave heating directly. Microwave absorption of raw materials and different glass system has been discussed. Dielectric properties, particularly loss tangent or loss factor, are presented for some glass composition. Less evaporation of ingredient and low contamination from the crucible wall are noticed during glass melting using microwave heating. Enhanced iron redox ratio (Fe⁺²/∑Fe) in microwave processing may be considered an advantage in the preparation of heat absorbing filter glass. Small-scale glass melting using the microwave heating has a significant impact on energy and time saving. However, the challenges associated with the upscaling glass melting with microwave heating and future scope have been talked about.     

The lateral load-deformation response of RC walls with a consideration of the height–length ratio

Reinforced concrete (RC) walls play an important role in resisting earthquakes, so understanding the lateral load-deformation response of an RC wall subjected to an axial load, shear, and moment is essential to nonlinear structural analysis. In this study, the moment-bending deformation response of an RC wall under an axial load and moment is obtained from moment–curvature analysis using the wall’s proper plastic hinge length. Furthermore, modified compression-field theory, adjusted according to the height–length ratio of the wall, is used to calculate the shear–shear deformation response of the wall under an axial load and shear. By integrating the moment-bending deformation and the shear–shear deformation responses, the lateral load-deformation response of the RC wall under axial load–moment–shear interaction can be reasonably determined. To confirm the reliability of the proposed method, experimental results for 67 RC walls are compared with analysis results from the proposed method. The statistical results show that the proposed method accurately predicts the lateral ultimate load but somewhat underestimates the lateral ultimate deformation. Finally, this paper gives an example using an equivalent column to simulate an RC wall using SAP2000 pushover analysis.     

聚甲基丙烯酸甲酯/二氧化硅复合材料的热性能

聚甲基丙烯酸甲酯/二氧化硅(PMMA/Si O_2)复合材料可以通过简便的单体浇铸、本体聚合方法制备,二氧化硅用硅烷偶联剂3-(异丁烯酰氧)丙基三甲氧基硅烷(γ-MPS)进行表面修饰,并用红外光谱表征其甲苯抽提后的组成。当加入量为11.76%时,PMMA/Si O_2复合材料的导热率达到0.23 W/(m·K),比基体PMMA提高了27.78%。用PMMA红外光谱的侧甲基弯曲振动峰(δCH3)与羰基(νC=O)的伸缩振动峰比值可以表示PMMA大分子的偶合终止与歧化终止的比例,随着二氧化硅含量的增加,歧化终止比例升高,从而使PMMA/Si O_2复合材料的热稳定性提高,与热重分析结果一致。     

电化学合成聚吡咯/二氧化硅复合膜及其防腐性能

采用循环伏安法,在316不锈钢电极表面原位生成聚吡咯-二氧化硅(PPy-SiO2)复合膜。红外光谱分析表明,通过电化学法可以在316不锈钢表面生成PPy-SiO2复合膜。利用扫描电镜考察了PPy与PPy-SiO2膜层形貌,发现相对于PPy膜层,PPy-SiO2膜层有着较为均一的表面状态。分别将316不锈钢、316不锈钢/PPy、316不锈钢/PPy-SiO2浸泡于3.5%(质量分数)Na Cl水溶液中,采用开路电位-时间(OCP-Time)曲线、电化学阻抗谱(EIS)考察了PPy膜层与PPy-SiO2复合膜层对不锈钢的防腐性能,结果表明,浸泡初期,影响膜层防腐性能的主要因素是膜层与不锈钢电极表面的吸附能力,PPy的金属防护效果高于PPy-SiO2;浸泡1 h后,影响膜层防腐性能的主要因素转变为膜层本身抑制水分子渗透的能力,PPy-SiO2的金属防护效果高于PPy。对PPy膜层与PPy-SiO2复合膜层进行了抗阴极剥离实验,结果显示,PPy-SiO2复合膜层具有更高的抗阴极剥离能力。     

燃料电池用QCS键和层析硅胶膜的制备及其性能表征

以季铵化壳聚糖(QCS)和层析硅胶为原料,制备了不同硅胶含量的多孔膜。用傅里叶变换红外(FTIR)和扫描电镜(SEM)对多孔膜的结构和形貌进行表征。同时,考察了层析硅胶的用量对多孔膜的含水率(WU)、溶胀度(SR)、机械性能和电导率的影响。结果表明,随着层析硅胶含量的增加,多孔膜的含水率、溶胀度和电导率均升高,但机械性能下降。当层析硅胶的用量为40%时,多孔膜的含水率高达816%,但是膜的溶胀度仅为189%,拉伸强度为5.6MPa,断裂伸长率为4.2%;在测试温度为70℃时,不同层析硅胶含量多孔膜的电导率数值分布在2.4~3.9×10~(-2)S/cm的范围内,且随硅胶含量的增加而增加。     

ROS scavenging Manganese-loaded mesoporous silica nanozymes for catalytic anti-inflammatory therapy

Reactive oxygen species (ROS) are reactive substances closely related to the inflammatory response, and previous studies have shown that anti-inflammatory therapy can achieve significant effects by scavenging ROS. Nanozymes are synthetic mimics of natural enzymes that are more stable, customizable, inexpensive, and catalytic for ROS. Therefore, we prepared a novel manganese-loaded mesoporous silica nanozyme (MnMSN) by template method and KMnO₄ oxidation surfactant templates. The physicochemical properties of the nanomaterials were investigated by XRD, TEM, SEM, size, Zeta potential and BET, etc. The results showed that MnMSN contains MnO₂ (Mn⁴⁺) and MnSiO₃ (Mn²⁺), and the particle size of MnMSN is smaller with the increase of KMnO₄ oxidation surfactant templates time, and the in vitro scavenging of ROS (H₂O₂, ·OH and ·O₂^–) is more effective. MnMSN has good cytocompatibility, scavenging intracellular ROS and inducing a shift from M1 to anti-inflammatory M2 phenotype. Furthermore, the intrinsic mechanism of MnMSN regulation of macrophage polarization was investigated by ELISA and qPCR, and the results showed that MnMSN is through scavenging ROS, leading to the down-regulation of NF-κB, which further leads to the down-regulation of TNF-α and IL-Iβ. The results of this work highlight the potential of MnMSN in catalyzing anti-inflammatory therapy.