Chemical Reaction Engineering and Research and development of gas solid systems

A general procedure is proposed for innovative research and development of gas-solid reactor systems, with a brief explanation of the significance of each step in the procedureBased upon the contacting mode between gas and solid phases, as well as the ways of supplying thermal energy to the reacting regions, various types of gas-solid reactor systems are classified by using tables of so called “matrix” form, for thermal cracking and gasification of heavy oils, gasification of coal, gasification of solid waste, calcination of limestone, clinkering of cement and reduction of iron ore.The importance of fundamental concepts is emphasized for successful research and development by presenting several examples; namely, calcination of limestone, thermal cracking of heavy oils and gasification of solid waste materials.In connection with the direction in which fundamental research should be oriented, four primary ways of thinking are proposed, which can be applied to obtain innovative ideas for further research and development in this field.One example of the author's practical experience was selected to show the role of the fundamental research in the course of large scale development. Finally the author outlines the role of chemical reaction engineering to innovate the novel gas-solid reactor systems which may be inevitable for simultaneous solution of the three big E's; namely, Energy, Environment and Economy.     

基于可调功率因数的单相AC－DC变换电路设计

本文以2013年全国大学生电子设计竞赛A题为依据,设计的单相AC-DC变换电路32位的STM32f103作为主控制器,主电路由220V市电经过自耦变压器,隔离变压器降至20-30V交流电,后接全桥整流电路,使电路稳定输出36V直流电,主电路通过硬件电流电压PI闭环控制,双环控制来调节输入的电流和输出电压,输入的交流电压和交流电流通过互感器采到单片机内,程序通过改变产生的正弦波的相位来改变功率因数,从而达到功率因数可调的目的,使设计的电路能包含题目中要求的所有部分,并通过优化而达到题目的要求,在主电路中加入继电器,控制继电器断开从而实现过流保护的功能。     

Rate of adsorption to and desorption from a langmuir surface: The case of zero activation barrier to adsorption without dissociation

Many rate constants of elementary steps on single crystals have been measured. Their pre-exponential factors can now be compared to those calculated by transition state theory. Such a calculation is presented in this Letter with due attention to microscopic reversibility, standard states, and configurational entropy.     

Discrete element approach for mine dump stability analysis

Mine overburden dumps have posed significant safety issues in the operations of various unit operations of open pit min-ing especially the external dumps. The external dumps are composed of a mixture of fragmented rocks and loose soil. Their charac-teristic is comparable to heavily discontinuous solid mass. The conventional approach of limit equilibrium methods provide safety factors for the slope but nothing about the stress-strain characteristics of the large dump mass. The designs of dump location and their respective geometry are integrated for the know-how of the stability characteristics of these dumps. The discrete element method uses a circular disk to represent the granular solid mass and their interactions are described by the Newton's third law of motion. The displacement is described by the sliding of the circular disk. This work is focused on the modeling efficiency of the discrete element methods to represent the behaviour of mine dump masses with the specified joint plane for the limit equilibrium method. The advantage of the work lies on the ease of information retrieval at any point at the dump mass concerning the stress and strain histories, displacement, failures etc. which when integrated produces a better understanding of the stability of the dump masses.     

有侧移半刚性连接组合框架柱的稳定分析

为了研究有侧移半刚性连接组合框架的稳定性能,利用三柱子框架模型,考虑了梁端和柱远端不同约束情况对柱有效长度系数的影响,提出柱有效长度系数的简化方法.通过算例研究了节点的非线性弯矩-转角关系和荷载水平大小对柱有效长度系数的影响,比较了简化方法、Barakat-Chen方法与精确方法的计算结果.研究表明:简化方法比Barakat-Chen方法有更好的精确度,与精确方法计算结果接近.     

外商直接投资类型转变的实证分析

论文在文献评述的基础上利用1992—2008年日本、美国等10个主要经济体对华直接投资数据,实证检验了外商直接投资(FDI)类型与中国市场规模、要素成本、投资环境之间的关系。结果表明:FDI在中国既具有垂直型FDI的特征,同时又具有水平型FDI的特征,但水平型特征更为突出。随着中国经济的迅速发展和市场规模的扩大,进入中国的FDI正由垂直型向水平型转变。在实证分析的基础上,针对当前的FDI类型转变提出了相关政策建议。     

倾斜疲劳裂纹在混合型应力下张开及滑移特性

对于存在裂纹的机械零件或者构件,它很有可能会受到来自不同方向的作用力, 因此有必要研究裂纹在混合型应力条件下的传播特性. 该文使用具有不同倾斜角度的裂纹--这些裂纹是在应力比R=0的Ⅰ型循环应力下制作的,通过测量裂纹的开口方向和滑移方向的位移量,计算了裂纹端部Ⅰ型应力强度因子(KⅠ)mes和Ⅱ型应力强度因子(KⅡ)mes.裂纹的倾斜角度是指载荷方向与裂纹间的夹角.结果表明,对于存在压缩残余应力的疲劳裂纹,当倾斜角度较大,即β=60°时,应力强度因子的实验值(KⅠ)mes小于理论计算值(KⅠ),但此时实验值(KⅡ)mes与理论值(KⅡ)基本一致.另一方面,对于倾斜角度较小β=45°的疲劳裂纹,其(KⅠ)mes减少的同时,由于裂纹上下表面相互接触,从而导致(KⅡ)mes同时下降.     

Discrimination for ablative control mechanism in solid-propellant rocket nozzle

The ablation in solid-propellant rocket nozzle is a coupling process resulted by chemistry, heat and mass transfer. Based on the heat and mass transfer theory, the aero-thermo-dynamic, and thermo-chemical kinetics, the thermal-chemical ablation model is established. Simulations are completed on the heat flow field and chemical ablation in the nozzle with different concentrations, frequency factors and activation energy of H2. The calculation results show that the concentration and the activation energy of H...     

因子分析法和熵值法在高校科技创新评价中的应用

在已有研究的基础上总结出了一套科学合理并具有可行性的高校科技创新评价指标体系,并把因子分析法和熵值法应用于高校科技创新评价.首先对高校科技创新评价体系的5个一级指标分别进行因子分析,然后运用熵值法对其确定权重.分析结果表明两种方法的结合使用能够简化分析对象的结构,使评价结果更具科学性、客观性.     

无机纳米-聚酰亚胺复合薄膜介电性研究

测试了纳米Al2O3-聚酰亚胺(PI)复合薄膜和纳米SiO2-聚酰亚胺复合薄膜的介电常数、介质损耗角正切和电导电流特性.结果表明,随着无机物含量的增加,两种复合薄膜的相对介电常数和介质损耗角正切增大,电老化阈值减小;无机物含量相同时,Al2O3-聚酰亚胺复合薄膜的相对介电常数和介质损耗角正切比SiO2-聚酰亚胺复合薄膜大,电导电流大,电老化阈值小.