填料粒子成型对泡沫铝合金孔结构的影响

在实验的基础上 ,绘制出填料粒子成型时的体积与泡沫铝合金的孔隙率相对应的变化曲线 ,并应用力学的基本原理对泡沫铝合金孔结构的成形机理进行了研究。确定填料粒子成型时的体积变化应在 0 %～ 12 %之间 (此时泡沫铝合金的孔隙率应在 41.6 %～ 47.6 %之间 ) ,才能稳定填料粒子尺寸 ,从而更好地控制泡沫铝合金的孔径尺寸 ,提高成型质量 ,稳定泡沫铝合金的使用性能。     

稀土和镁对热浸镀铝液和镀层组织的影响

研究了热浸镀铝液中添加微量稀土和镁对铝液质量和镀铝层厚度的影响及镀铝层的表面和第二相的形貌。结果表明，微量稀土改善了铝液的质量和镀层的组织，而微量镁有损铝液质量和镀层组织。     

FeAl/FeAlSi非对称膜材料的制备及膜基结合性能

目的制备高温腐蚀环境下应用的Fe Al/Fe Al Si非对称膜材料,研究膜与基体的结合性能。方法采用粉末反应合成法制备大孔径、高孔隙度的FeAlSi多孔体作为支撑体,通过浸渍法在支撑体表面制备小孔径的FeAl涂层作为膜层,再经烧结得到Fe Al/Fe Al Si非对称膜材料。研究Fe Al/Fe Al Si非对称膜材料的孔结构性能及膜基结合性能。采用XRD和SEM研究多孔膜材料的物相组成及微观形貌,采用孔结构测试仪及压汞法测试支撑体与膜层的孔结构参数,采用拉伸法和反吹实验研究Fe Al/Fe Al Si非对称膜材料的膜基结合性能。结果 Fe Al/Fe Al Si非对称膜材料表面膜层均匀、完整,膜层与支撑体之间具有冶金结合。支撑体的孔隙度和平均孔径分别为43.0%和22.7μm,膜层的孔隙度和平均孔径分别为36.5%和7.5μm。当膜层厚度增加时,膜材料的透气度下降,最大孔径在一定膜层厚度范围内变化不大,当膜层厚度在150～300μm范围内时,最大孔径约为7.8μm。膜层与支撑体的结合强度大于5.5 MPa。结论浸渍法制备的Fe Al/Fe Al Si非对称膜材料的孔结构性能优异,膜基结合性能满足工业应用。     

用偏钛酸作原料制备纳米TiO2粉末以及颗粒相结构与光催化性能关系的研究

米用常温氨水水解TiOSO4过程中加入自制的表面活性剂制备了超细纳米TiO2粉末,用XRD,TEM和比表面仪对不同煅烧温度下的纳米TiO2粉末结构、粒径大小和比表面等进行了表征,研究了纳米TiO2粉末对甲基橙的光催化降解能力。研究表明煅烧温度在400℃～800℃时得到的纳米TiO2粉末呈锐钛矿结构,粒径约为5．5nm～9．6nm,比表面积高达189．45m^2/g;在850℃煅烧后所得的纳米TiO2粉末为锐钛矿与金红石型混晶结构;在l100℃时得到的纳米TiO2粉末为金红石型纳米TiO2粉末,同时微粒出现团聚且粒径变大。光催化实验表明：纳米TiO2粉末的光催化活性与煅烧温度密切相关,850℃煅烧1．5h所制得的混晶结构纳米TiO2粉末表现出较高的光催化活性。与国产商品纳米锐钛矿型TiO2相比,其降解甲基橙的速率约为国产商品纳米TiO2的1倍。     

Investigation of microstructure of laser cladding Ni-WC layer on Al-Si alloy

A plasma-sprayed Ni-WC layer was deposited on an Al-Si cast alloy surface, and then it was further melted by a 5 kW CO₂ laser. The microstructure and chemical composition of the laser-melted zone were investigated, and the microhardness in different parts was measured. Experimental results showed that the chemical composition of the sample was not uniform. Compositional segregation in the laser-melted zone was found. Some amorphous structure appeared in the nickel-rich locations after laser melting. Owing to the thermal effect of the laser scanning, an intermediate-phase Ni₃Al segregated from this region and formed Ni₃Al grains and amorphous grains. Some WC particles melted in the matrix, and chromium carbide Cr2;|C6 and (Cr,W)C separated during the cooling process. The highest microhardness (1027HV) was found in the high-nickel region.     

湖南高等教育结构合理性分析

湖南省高等教育结构发展的现状表现为规模大、速度快、水平高、工科强、集中于长沙市的特点，从高等教育与经济社会发展水平、产业结构、就业结构等方面来看，二者并不十分协调，甚至可以说是不合理．但如果从历史、文化传统、社会心理等方面看，湖南高等教育结构又有其合理性。     

Study on interfacial structure and strength of Si_3N_4/Ti/Cu/Ti/Si_3N_4 PTLP bonding

0IntroductionRecently,the development of bonding technique ofhigh temperature structure ceramic Si3N4becomes a hottopic in the field of ceramic bonding[1].Partial transientliquid phase bonding(PTLP)has been applied in the fieldof high temperature ceramic bonding and made some pro-gress.The selection of interlayer materials is key to PTLPbonding.Since Bender discovered that Ag-based brazingmaterial including Ti could wet ceramic in1954,morestudies have shown that Ti has good wetting prope…     

Study of δ-hydrides in Ti-2Al-2.5Zr and Ti-4Al-2V alloys

The α alloy Ti-2Al-2.5Zr and near α alloy Ti-4Al-2V were hydrogenated to various levels. The morphology,orientation relation (OR), and habit plane of the hydrides were studied by means of transmission electron microscopy (TEM). It was found that in the two alloys most of the precipitates are δ-hydrides which have fcc structure with the lattice parameter a = 0.44 nm. Two basic orientation relationships and habit planes of the precipitates are determined. Twin structure was observed in both alloys.     

Crystal structures and phase transformation of deuterated lithium imide, Li2ND

Half-Heusler compounds of Sn-doped TiCoSb “TiCoSn_xSb_1−x (x = 0.0, 0.01, and 0.05)” were prepared and their thermoelectric properties were measured above room temperature. From the EDX analysis, all the samples have three phases: the TiCoSn_xSb_1−x, Co-rich, and Ti-rich phases. The values of the thermoelectric power increase with Sn doping, and a positive thermoelectric power is obtained in the sample of TiCoSn_0.05Sb_0.95. The thermal conductivity decreases both with increasing temperature and with Sn content. The maximum value of ZT for p-type material is 0.030 at 988 K in the sample of TiCoSn_0.05Sb_0.95.     

热处理对铁铝涂层相组成及滑动磨损性能的影响

采用粉芯丝材和高速电弧喷涂技术得到的铁铝金属间化合物涂层 ,研究了 5 5 0℃和 80 0℃热处理对涂层相组成及滑动磨损性能的影响。结果表明 ,涂层的主要组成相是铁铝金属间化合物 (FeAl和Fe3 Al)和α Fe ,另有少量的Al2 O3 和Al。热处理后 ,一部分Fe3 Al将转变成FeAl,对涂层的显微硬度有明显的影响。剥层磨损是铁铝涂层的主要磨损机理。通过热处理提高涂层的显微硬度 ,将有利于提高涂层的耐磨性