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41.
《岩石力学与岩土工程学报(英文版)》2020,12(3):630-641
Structure is an evident determinant for macroscopic behaviors of soils. However, this is not taken into account in most constitutive models, as structure is a rather complex issue in models. For this, it is important to develop and implement simple models that can reflect this important aspect of soil behavior. This paper tried to model structured soils based on well-established concepts, such as critical state and sub-loading. Critical state is the core of the classic Cam Clay model. The sub-loading concept implies adoption of an inner (sub-loading) yield surface, according to specific hardening rules for some internal strain-like state variables. Nakai and co-workers proposed such internal variables for controlling density (ρ) and structure (ω), using a modified stress space, called tij. Herein, similar variables are used in the context of the better-known invariants (p and q) of the Cam Clay model. This change requires explicit adoption of a non-associated flow rule for the sub-loading surface. This is accomplished by modifying the dilatancy ratio of the Cam Clay model, as a function of the new internal variables. These modifications are described and implemented under three-dimensional (3D) conditions. The model is then applied to simulating laboratory tests under different stress paths and the results are compared to experiments reported for different types of structured soils. The good agreements show the capacity and potential of the proposed model. 相似文献
42.
文章中主要采用有机溶剂萃取法(OSE)对高浓度石油污染土壤进行修复,经过精馏操作,有效回收原油,建立脱附等温曲线,研究了石油污染物在土壤-有机溶剂两相间的迁移规律。 相似文献
43.
提高电脱盐效果的措施 总被引:1,自引:0,他引:1
中国石油天然气股份有限公司庆阳石化分公司常压蒸馏装置一、二期技术改造结束后,装置加工能力由0.5 Mt/a增加到1.0 Mt/a,最高时达到1.3 Mt/a。但电脱盐装置脱后原油中盐的质量浓度一直在4.0-5.0 mgNaCL/L居高不下。为了降低脱后原油中盐的质量浓度,提高催化裂化装置催化剂活性,对电脱盐装置进行了技术改造,优化了操作参数,这到了脱后原油中盐的质量浓度小于3 mg- NaCl/L的预期效果,取得了较好的经济效益。 相似文献
44.
北部湾盆地福山凹陷CO2气成因探讨 总被引:2,自引:1,他引:1
北部湾盆地福山凹陷油气钻探中发现了高含CO2气的天然气气藏。对CO2气稳定碳同位素、伴生稀有气体氦和氩同位素进行了分析研究,结果显示,福山凹陷CO2气稳定碳同位素偏重,(13CCO2为-5.01~-10.08‰,绝大多数样品大于-7.0‰,为无机成因CO2气特征;伴生稀有气体氦同位素3He/4He值为(4.74~5.03)×10-6,R/Ra值为3.38~3.59;伴生稀有气体氩同位素40Ar/36Ar值为1881~2190,也显示出幔源或壳幔混合CO2气的特征。综合判定认为,福山凹陷CO2为壳幔混合成因。始新统流沙港组岩浆岩体分布特征与CO2气藏分布范围基本一致,也表明幔源-岩浆可能是福山凹陷CO2气的主要来源。与南海北部边缘盆地其它地区如珠江口盆地西部、琼东南盆地东部CO2气成因一致,都为幔源-岩浆来源,或壳幔混合来源。 相似文献
45.
G Garrote J
M Cruz H Domínguez J
C Paraj 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(4):392-398
Non‐isothermal processing of lignocellulosic materials in aqueous media (autohydrolysis reaction) under mild conditions leads to solutions containing valuable chemicals (oligosaccharides, sugars and acetic acid) and other, undesired, compounds (belonging to the extractive and acid‐soluble lignin fractions) which have to be removed in further purification treatments. Liquors obtained by non‐isothermal autohydrolysis of Eucalyptus globulus wood and corncobs under a variety of operational conditions were extracted with ethyl acetate in order to remove non‐saccharide components, and the suitability of the fraction dissolved in the organic phase was assayed for possible utilisation as an antioxidant. The yield and antioxidant activity of ethyl acetate extracts (measured by the α,α‐diphenyl‐β‐picrylhydrazyl (DPPH) radical scavenging capacity) showed a strong dependence on the autohydrolysis conditions. The antioxidant activity of extracts obtained under selected operational conditions compared well with synthetic antioxidants. © 2003 Society of Chemical Industry 相似文献
46.
47.
Saudino Kimberly J.; Wertz Annie E.; Gagne Jeffrey R.; Chawla Sonia 《Canadian Metallurgical Quarterly》2004,87(5):698
Twin studies suggest that parent ratings of temperament exaggerate differences between twins. The present study examined whether such contrast effects also operate for nontwin siblings. The activity level (AL) and shyness of 95 nontwin sibling pairs (ages 3 to 8 years) were assessed via parent ratings and objective measures (actigraph and observer ratings). Siblings showed no resemblance in either parent-rated AL or shyness; however, sibling resemblance for actigraph AL and observer-rated shyness was substantial. Thus, parents do contrast their nontwin siblings when rating these 2 temperament dimensions. Moreover, the importance of sibling differences in temperament to the sibling relationship and differential maternal treatment varied across the different measures of AL and shyness, suggesting that parent perceptions may play a role in these associations. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
48.
The role of Nb2O5 and γ-Al2O3 oxide supports on the ammoxidation of propane on supported mixed Sb–V oxide at different Sb+V surface coverages is studied. Sb and V oxide species on alumina and on niobia support show different structural features that reflect in different performance during the ammoxidation of propane to acrylonitrile. Niobia-supported catalysts are much more selective to acrylonitrile than alumina-supported ones. Alumina interacts weakly with the supported oxides while niobia forms new phases through solid state reactions with the supported oxides during catalytic operation that must account for its higher selectivity values towards acrylonitrile and higher specific rate of acrylonitrile formation per vanadium site. 相似文献
49.
高温酸化助排剂HC2-1的研究 总被引:12,自引:2,他引:10
为了满足高温油藏和深井酸化作业残酸返排的需要,通过表面活性剂的筛选和复配研究,得到了高温酸化助排剂HC2—1。其性能评价结果表明,HC2—1具有使用浓度低、表面活性高的特点,在20%的HCI溶液中,当其浓度为50mg/L时,表面张力为20.7mN/m;具有良好的耐温性能,在180℃下恒温48h,HC2—1仍保持较高的表面活性;具有良好的耐盐能力,加有HC2—1的20%HCl溶液和CaCO3反应至HCl完全消耗,整个反应过程体系无新相生成且表面张力基本不变;可增大酸液体系的润湿角,进一步降低毛细管阻力,使酸液返排率由46%提高到97%,在促进酸液返排的同时与原油不发生乳化反应。 相似文献
50.