用于玻纤增强粒料制备的啮合同向双螺杆挤出机的螺杆构型

阐述了玻纤增强粒料用啮合同向双螺杆挤出机的螺杆构型及设计时应注意的问题。     

热致感应型形状记忆高分子材料及其研究进展

讨论了热致感就型形状记忆高分子材料的记忆原理和对材料的基本要求厅求,介绍了目前已遥产品品种及制备方法,并进一步评述阳了近的研究进展。     

Experimental investigation of the morphology development of polyblends in corotating twin‐screw extruders

Compounding extruders are still designed based on experience and time‐consuming experimental examinations. This work investigates the morphology development of incompatible polyblends along a mixing zone at the end of a corotating twin‐screw extruder. During the process, the samples are taken from the running extruder using special barrel plates. These samples are subsequently examined by means of scanning electron microscopy (SEM). This method allows sampling in less than 1 min and thus extremely fast and almost unaffected. The experimental investigation of the morphology development improves the knowledge about the factors essentially influencing the blending process. It also allows the verification as well as improvement of theoretical models. Polyblends of polypropylene (PP) and polyamide (PA) with 7.5, 15, and 30 wt % PA were examined. As well as the relevance of the mass percentage of the dispersed phase, the influence of the screw geometry, the screw speed, the melt temperature, the melt throughput, and the pressure profile was investigated. Apart from the melt throughput, all varied factors show an influence on the resulting blend morphology that may not be neglected. However, the changes of the mean particle sizes in the observed mixing zones are only gradual (mean particle size ≈ 1–4 μm), which can be attributed to the extremely fine blend morphology already existing during or after the melting. That means that the application of “classic melting zones” generally already produces finely dispersed blend morphologies, thus proving the essential importance of the melting zones regarding the development of the blend morphology. Consequently, the mean particle sizes, calculated by means of quantitative image analyses of SEM micrographs in the mixing zones following the homogenizing section only slightly depend on the compounding conditions (screw speed, melt throughput, screw geometry, melt temperature, and pressure profile). However, the direct visual analysis of the SEM images, especially in the first parts of the mixing zones, shows the simultaneous existence of large PA6 particles in the PP matrix. In addition, a downstream unification of the particle size distribution can be observed. Especially the number and size of the coarser particles decreases in the mixing zones. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 76: 708–721, 2000     

Modes of gasless combustion and macrostructure of combustion Front (for the Ti-Si system as an example)

Gasless combustion of Ti+Si mixtures (taken as an example) was investigated by high-speed video recording followed by computer-assisted processing of stored still frames. The three-dimensional shape of the combustion front was reconstructed, and explanations were proposed for the combustion front propagation modes along the surface of cylindrical samples. The reconstructed front configuration was found to be nearly paraboloidal. The modes of unsteady combustion in T-rich and Si-rich mixtures turned out to be strongly different. The results were used to rationalize the available experimental data on unsteady combustion in terms of microheterogeneous theory. __________ Translated from Fizika Goreniya i Vzryva, Vol. 45, No. 4, pp. 147–155, July–August, 2009.     

冷喂料挤出机螺旋啮合喂料装置的性能分析与研究

针对新型的螺旋啮合喂料装置进行分析,从机理上讨论了螺旋啮合喂料装置的优越性,同时就实验结果,讨论分析了啮合量、螺杆转速、胶料种类等对挤出机性能参数的影响程度,为后续的结构设计和研究提出了一定的参考基础。     

元素成分对磁控溅射TiNi薄膜结构性能的影响及其控制

描述了TiNi形状记忆合金薄膜的一般特性及成分对其组织及性能的重要影响.磁控溅射法是应用最为广泛的制备TiNi基形状记忆薄膜的方法之一,但由于Ti与Ni的溅射产额不同,很难得到理想成分的TiNi薄膜.目前主要采用改变工艺参数或靶材成分补偿的方法控制薄膜的成分.借鉴反应磁控溅射沉积薄膜时成分控制方法,提出了一种利用溅射靶表面光发射谱的控制技术,理论上可以达到精确检测或控制TiNi形状记忆合金薄膜成分的目的.     

沸腾状态下十二烷基甲基二羟乙基溴化铵微波合成的动力学研究

通常,人们利用微波进行化学合成,如果反应温度控制在低于溶剂的沸点温度,反应体系一旦达到所设定温度,自动控温系统就会自动切断加热电源,停止加热。对于微波反应来说,也就停止了微波的连续作用,而系统仅仅是保持在恒温状态。如果系统的保温效果很好的话,微波的作用可能就比较少,而仅仅是热效应对化学反应作用,没有体现出微波的持续作用。该研究选择特定的溶剂体系,采用在溶剂沸点温度下进行微波有机合成反应,以保证微波始终持续作用。结合题示表面活性剂的合成,探讨了微波合成反应的动力学参数,分析了微波作用原理。分别在微波作用以及传统加热两种方式下,考察了十二烷基甲基二羟乙基溴化铵合成动力学,获得了两种方式下的反应动力学参数,结果表明,微波的作用没有改变反应级数,两种情况下都是一级反应。微波作用下的活化能为ΔH=33.59 kJ/mol;而传统加热的活化能为ΔH=55.83 kJ/mol。该文提出以单位时间单位容积内、微波作用下反应物的变化量减去相同温度条件下传统加热时的变化量,作为微波对反应速率的贡献量Δ(-rA)的概念。实验结果表明,在同一温度条件下,反应时间越短,即反应物浓度越高,微波对反应速率的贡献量Δ(-rA)就越大;在其他条件相同时,反应温度越低,微波对反应速率的贡献量Δ(-rA)就越大。     

双根对称轧制34#球扁钢的工艺特点

针对球扁钢轧制过程中变形不对称的特征,采用双根对称轧制法解决了非对称球扁钢轧制困难和冷却弯曲等问题,介绍了孔型强迫宽展、冷床冷却、剖分矫直的独特设计,保证了生产稳定和产品质量。     

气体的温度和压力及颗粒形状对固定床压降的影响

本文在Ａ－Ｓ方程的基础上推导出气体流经固定床时的压降表达式。     

1101汽车底盘专用漆的研制

研制了性能优异的汽车底盘专用漆,介绍了该漆的生产配方及工艺流程,列举了该漆的性能指标及检测结果,讨论了影响该漆性能、质量的各种因素.