ODS 反相键合相色谱柱的使用、维护

本文对ODS反相键合相色谱分析的核心部分——ODS色谱柱的使用、保存、维修及再生等方面的经验和技术作了详细的介绍,并总结了包括ODS柱在内的有关液相色谱柱的异常现象及原因一表,以利故障的查寻和排除。     

四面受热时型钢混凝土柱的简化计算方法研究

高温作用下型钢混凝土柱的力学性能的有限元分析是进行其抗火性能设计研究的重要途径。基于型钢和混凝土材料在高温下的力学性能曲线,简化得到其计算模型,通过ABAQUS软件分析,研究了高温下型钢混凝土柱在不同时刻的温度场分布,根据分析得到的结果确定了柱截面等温曲线的位置,结合常温下型钢混凝土柱的计算公式对高温下的计算公式进行了研究,简化得到了高温下型钢混凝土柱极限承载力的计算公式,根据已有的试验资料对所推导型钢混凝土柱简化计算方法的正确性进行了分析,结果表明:利用文中简化的计算公式计算所得的型钢混凝土柱的弯矩值为865 kN,轴力值为132 kN·m,与其试验值具有一定的吻合度。     

冷柱头进样气相色谱法分析橡胶防护蜡的碳数分布

研究冷柱头进样气相色谱法分析橡胶防护蜡的碳数分布以及正构烷烃/非正构烷烃比例。结果表明,采用冷柱头进样方法,在样品量为10 mg、样品完全溶解后静置10~30 min并取上层清液以及进样量为1μL时,分析得到的气相色谱峰的峰形和响应信号最优。本方法测定橡胶防护蜡的碳数分布以及正构烷烃/非正构烷烃比例结果准确、可靠。     

高层建筑抗震设计中短柱问题的分析与处理

指出在诸如图书馆的车库、层高较低的储藏室、高层建筑的地下车库等处,由于使用荷载大,层高又较低,在设计中就不可避免地会出现短柱。而短柱的延性很差,尤其是超短柱几乎没有延性,在建筑遭受本地区设防烈度或高于本地区设防烈度的地震影响,很容易发生剪切破坏而造成结构破坏甚至倒塌。笔者在文中详细讨论了建筑中短柱的判别方法,及改善短柱抗震性能的几种措施。     

Special-shaped tube drawing forming and conformal optimization of die cavity

Aiming at the issues in quick processing and modeling design of drawing special-shaped tube die, by Conformal Mapping Theory and the numerical trigonometry method of interpolation between odd points and even points, the conformal mapping function is obtained. As the result, three-dimension drawing forming were converted into that of two-dimension problems, and the plastic stream function was analyzed, die cavity modeling and its optimized function were set up. Combining with modern processing technology, NC program and CAM of die cavity can be realized. Taking the drawing forming of hexagon tube with arc radii r and ellipse-shaped tube as instances, the drawing die cavity optimization of special-shaped tube was achieved, as well as, the changing principle of wall thickness was analyzed.     

Flow of gas-liquid-solid system and its application in packed flotation column

A packed flotation column, which is packed with multiple board ripple packings, was described. Based on comprehensive steady state models, chemical reactor developed previously in chemical engineering subjects, have been extended to packed flotation column for mineral separation. The experimental results verify that tarts in series model is better than axially-dispersed plug flow model to describe flow pattern in the collection zone of column by RTD (residence time distribution), and the error of experimental data and calculated data of both models are 0. 07 % - 0. 1% and 0. 18 % - 0.45 % respectively. And, RTD of gas phase was also considered, results also show that gas in the whole column appears plug flow. The cleaning process through adding wash water in froth zone of column was described, and the effect of superficial air vdodty and superficial wash water vdocity on the cleaning action of froth zone were discussed. Flotation experiment for single column was conducted for phosphate ores. The recovery for P2Os was 85.8%, and the grade was 26.8%.     

基于Aspen Plus的聚甲氧基二甲醚精馏过程模拟分析

在装有θ环填料的精馏塔内进行了聚甲氧基二甲醚精馏实验。利用化工流程模拟软件.AspenPlus对聚甲氧基二甲醚精馏过程进行模拟,首先,采用DsTWU简捷蒸馏模型,运用软件中NRTL、WILSON、UNIQUAC,3种物性方法对精馏塔进行了计算,得到了回流比、塔板数和温度等操作参数。接着,采用RadFrac严格精馏模型对精馏塔进行了验证,其计算结果与实验结果吻合良好,满足工艺要求。最后,对精馏塔的操作变量进行了灵敏度分析,讨论了进料位置、进料流率和回流比等参数对精馏分离要求与能耗的影响,并确定了最优化方案,即:进料板为第50块,进料流率为35 mol/h,回流比为6。     

精馏塔时滞过程的分数阶PIλDμ控制器设计

本文针对精馏塔不稳定时滞过程,提出一种基于设定值加权的分数阶PIλDμ控制器设计方法.首先采用比例环节构成内环反馈镇定不稳定时滞过程,然后基于等效的过程模型,依据设定值加权方法设计分数阶PIλDμ控制器,并进行了控制器参数整定.仿真结果表明:分数阶PIλDμ控制器可以使精馏塔不稳定时滞过程系统获得良好的动态响应特性,干扰抑制特性以及克服系统参数变化的鲁棒性.     

具有耐火钢短梁的钢框架梁-柱连接抗火性能模拟

通过有限元模拟探讨将耐火钢短梁应用于钢框架梁 柱连接以提高连接抗火性能的可能性.考察三维有限元建模过程中模型简化、网格划分、求解方法和接触关系等关键技术,以提高计算效率并确保分析结果的可靠性.提出3个确定极限温度的准则并应用于钢框架,通过比较可知：对于采用普通钢的钢框架,采用准则1与准则2确定的极限温度与由最大挠度为L/20和L/10所确定的临界温度较接近,这有益于指导钢框架抗火设计.比较普通钢与耐火钢短梁的变形可知：耐火钢的使用可以有效控制跨中挠度变形,使最大变形值减小1/2以上.