结合图论和基团贡献法进行分子设计

提出了一种新的计算机辅助分子设计策略—结合图论和基团贡献法的分子设计方法。提出基团触角数、基团特征因数、分子特征因数的定义和分子结构完整定理使基团组合为分子过程自动完成 ,通过予选基团、限定分子基团数及有机物分类法减小合成问题尺寸。给出了系统的设计方法和设计步骤 ,并编制了相应的计算机程序。通过无毒高温载热剂设计和芳烃与非芳烃分离的萃取精馏溶剂设计 2个实例 ,检验了方法的可靠实用性     

用神经网络模型预测饱和液体的传递性质

使用神经网络模型 ,对纯物质的饱和液体传递性质粘度、导热系数及表面张力与温度的函数关系进行预测。对常见的 35 0多种有机物的预测结果表明 ,在熔点到临界点的温度范围内 ,粘度、导热系数及表面张力的平均预测误差分别为 0 12 %、 0 0 9%及 0 0 3%。     

Premelting transition in uranium dioxide

Thermal analysis of the cooling curves of small samples of uranium dioxide, laser heated in a high-pressure autoclave on a subsecond time scale to a temperature just below the melting point, reveals, in the case of nominally stoichiometric UO_2.00, a significant -like heat capacity peak, indicating a premelting transition in this material. The results are discussed and a simple model is presented in terms of which the observed behavior can be described.Summary of a paper presented at the Third Workshop on Subsecond Thermophysics, September 17–18, 1992, Graz, Austria. Because of its length, the full paper was published in a regular issue of this journal (Vol. 14, No. 2, 1993).     

换热器计算机辅助设计

把换热器的设计和计算机辅助设计的概念相结合,提出了换热器设计的一个系统模型。考虑到换热器结构形式的多样性及影响换热性能因素的复杂性,较好地解决了人机互补问题及与绘图软件AutoCAD的相结合问题。对列管式换热器进行了具体实现。整个系统分成两部分:辅助设计计算部分和辅助设计制图部分。具有良好的适应性和人机友好性。     

对流换热理论在玻璃窑炉换热器设计中的应用

本文主要分析了管内层流对流换热时两种不同情况下努谢尔特准数的数值及在换热器设计中的指导意义。     

管壳式换热器传热强化技术进展

介绍了国内外传热强化技术研究的发展概况 ,简述了典型的强化传热元件开发、新型壳程结构设计及国内外推出的各种新型高效换热器的有关情况 ,指出了国内近期开发研究的发展方向。     

Thermal conductivity and heat capacity of solid AgCl under pressure

Using the transient hot-wire method, measurements were made for solid AgCl of both the thermal conductivity, , and the heat capacity per unit volume, c _p, where is the mass density. Measurements were made in the temperature range 100 to 400 K, and at pressures up to 2 GPa. c _p(P, T) could be adequately described if the acoustic modes were represented by a Debye model and the optic modes by an Einstein model. Analysis of (T) showed that only the acoustic modes needed to be taken into account up to 300 K, but that the optic modes were increasingly effective in carrying heat at higher temperatures. (P) was adequately described by the Lawson formula, but not by the Leibfried-Schlömann formula, to which it is formally equivalent. Agreement with experiment could be achieved by two different modifications of the Leibfried-Schlömann formula, although neither has a firm theoretical basis.     

耐温保气型热熔胶的研制

本文以二聚脂肪酸聚酸股为主基村，研制了一种通信电缆接头用热可缩材料用热熔胶。讨论了主基材的选择、辅料对胶性能的影响，且与EVA型常规胶性能作了比较．     

我国塑料热稳定剂生产现状与研究进展

介绍了国内塑料热稳定剂生产、市场和发展趋势。目前我国塑料热稳定剂无论是品种和产品质量等与国外先进水平仍有较大的差距，提出了我国热稳定剂的发展建议。     

不连续双斜向内肋强化换热管性能

引言管壳式换热器在石油化工、能源动力、造纸、制药等领域应用十分广泛,换热强化对于其节能降耗具有十分重要的意义.近30年研制开发出几十种强化换热管,例如螺旋槽管、波纹管和翅片管等,并得到了比较成功的应用.但相关的研究多数仍然停留在经验的基础上,即研究者根据其经验设计出某种具体的强化技术,然后通过实验和数值计算归纳出适用于一定范围的经验关联式.因此,传热强化研究目前仍属于技术领域[1],研究人员通常所采用的经验性的研究方法不可避免存在着一定的局限性.过增元等[2]提出了一种新的强化换热理论———对流换热场协同理论,为对…