Atomic Insights into Phase Evolution in Ternary Transition‐Metal Dichalcogenides Nanostructures

Phase engineering through chemical modification can significantly alter the properties of transition‐metal dichalcogenides, and allow the design of many novel electronic, photonic, and optoelectronics devices. The atomic‐scale mechanism underlying such phase engineering is still intensively investigated but elusive. Here, advanced electron microscopy, combined with density functional theory calculations, is used to understand the phase evolution (hexagonal 2H→monoclinic T′→orthorhombic T_d) in chemical vapor deposition grown Mo_{1− x} W _x Te₂ nanostructures. Atomic‐resolution imaging and electron diffraction indicate that Mo_{1− x} W _x Te₂ nanostructures have two phases: the pure monoclinic phase in low W‐concentrated (0 < x ≤ 10 at.%) samples, and the dual phase of the monoclinic and orthorhombic in high W‐concentrated (10 < x < 90 at.%) samples. Such phase coexistence exists with coherent interfaces, mediated by a newly uncovered orthorhombic phase T_d′. T_d′, preserves the centrosymmetry of T′ and provides the possible phase transition path for T′→T_d with low energy state. This work enriches the atomic‐scale understanding of phase evolution and coexistence in multinary compounds, and paves the way for device applications of new transition‐metal dichalcogenides phases and heterostructures.     

极薄煤层综采技术的研究与应用

介绍了我国极薄煤层采煤技术的现状,指出现有的综采设备不适用于极薄煤层开采;介绍了适合极薄煤层综采的新型采煤机、液压支架、刮板运输机的结构、性能特点,提出了极薄煤层综采工艺。实践表明,该新型极薄煤层综采装备与综采工艺有效提高了采煤效率,创造了很好的经济效益,但还需进一步研究爬底式采煤机滚筒可调高技术、如何减少端头开缺口的工作量以及极薄煤层工作面的自动化技术。     

煤矿机电及运输事故防治的紧迫性研究

分析了2005—2010年全国煤矿死亡事故中顶板、瓦斯、水灾、火灾、运输、机电、爆破等各类事故数占事故总数的比例及每起事故的平均死亡人数,指出运输和机电事故死亡人数分别居第3位和第5位,共占死亡总人数的13.72%;指出电气火源是引爆瓦斯的第一火源,且2010年由机电事故引发的矿井火灾占火灾事故总数的80%,得出加强煤矿机电事故防治工作是遏制瓦斯爆炸事故及矿井火灾的迫切需要的结论;最后指出,应加强机电及运输事故防治工作,以减少由煤矿机电、运输事故引发的瓦斯爆炸事故和火灾事故。     

高边界精度和抗噪的均值漂移图像分割算法

Mean shift(均值漂移)算法核函数窗口的带宽目前仍没有一个统一的确定标准.对整体图像根据Canny算子提取的边缘方向信息分成3类子图,一类是规则边缘子图,由规则边缘像素组成;第2类为非规则边缘子图,由边界方向变化剧烈的边缘像素组成;第3类是非边缘子图,由区域内部平坦区域和噪声区域组成.规则边缘子图和非边缘子图采用大窗口使区域内部更为平滑,并使噪声区域达到更高的抗噪性能,非规则边缘子图用小窗口可保持更高的边界精度.实验采用金属断口图像进行分割,结果表明,针对不同子图采用不同核函数带宽的方法使分割后的金属断口图像边界更准确,抗噪性能也更强.     

综采工作面支架安全快速拆除新工艺

针对传统综采工作面支架拆除工艺在安全、施工速度、材料耗费等方面的不足,以张集煤矿1214(3)工作面支架拆除工程为例,介绍了一种改进的综采工作面支架安全快速拆除新工艺。该新工艺顶部采用锚梁网支护,帮部只采用锚杆支护,简化了通道支护工艺;采用多台支架作为掩护架,提高了支架拆除的安全性;通道顶板随着掩护支架的前移自行垮落,不需维护。实践证明,该综采工作面支架拆除新工艺安全、快速,取得了明显的经济和技术效益。     

Modeling of thermodynamic properties of ABr-PrBr3 (A=Li-Cs ) systems

The thermodynamic properties of ABr-PrBr₃(A=Li-Cs) systems were assessed by the CALPHAD method. The liquid phase in the systems was described by the non-stoichiometric associate model. The entropies of mixing in the liquid were evaluated from experimental liquidus and enthalpy of mixing data. For the pseudobinary compounds A₃PrBr₆,APr₂Br₇, and A₂PrBr₅ (A=K,Rb) and Cs₃PrBr₆ and CsPr₂Br₇, the dependences of Gibbs energies of formation on temperature were calculated. The anomalies of sequences of thermodynamic properties in RbBr-PrBr₃ were observed and discussed. The nature of the liquid phase and precision of calculations of the Rb₂PrBr₅(s) compound were discussed.     

Structural and electrical properties of mixed oxides of manganese and vanadium: A new semiconductor oxide thermistor material

Binary oxides of manganese and vanadium have been synthesized by solid state sintering, in which the mass ratio of the individual components Mn₂O₃ and VO₂ have been varied from 90:10 to 5:95. The bulk ceramic samples were characterized by X-ray diffraction and scanning electron microscopy with energy dispersive X-ray analysis. The initial compositions either rich in Mn₂O₃ or in equi-proportion by mass with VO₂ yield β-Mn₂V₂O₇ or a new crystalline form of Mn₂V₂O₇, with unit cell parameters: a = 7.73091 Å, b = 6.640788 Å, c = 6.70779 Å α = γ = 90° and β = 98.7086° which is designated as γ-Mn₂V₂O₇. The compositions, richer in VO₂ produce MnV₂O₆ co-existing with V₂O₅ the proportion of which increases with increase in VO₂. The surface microanalysis shows a spherical-granular morphology in Mn₂V₂O₇ structure and plate/rod-like structures co-existing with granular morphology in case of MnV₂O₆ together with V₂O₅. The electrical parameters of the negative temperature coefficient thermistors were determined. Depending on the constituent oxide composition, the NTC thermistors showed room temperature resistivity in the range of 6.52 × 10² to 6.1 × 10⁶ Ω-cm. The thermistor constant and activation energy are in the range of 0.12–0.458 eV and 1393–4801 K, respectively.     

A new process for fabricating tip-shaped polymer microstructure array with patterned metallic coatings

In this paper, we present a new process for fabricating tip-shaped polymer microstructure array coated by patterned metal layer. This new process involves three techniques including: micro-molding, patterned metal layer transfer, and electrochemical-based sacrificial layer. As we know, it is very difficult to remove the extra photoresist (PR) in the concave areas in traditional micro-fabrication technology, which hinders patterning metal layers on three-dimensional (3D) microstructures. The electrochemical-based sacrificial layer technique can effectively resolve this problem, which is verified by scanning electron microscopy (SEM) characterization. Comparative study between the 3D metal-coated polyimide microstructures fabricated with and without the electrochemical-based sacrificial layer step is also performed and SEM images proved the effect of the presented process. The applicability of the developed process is also demonstrated with the successful fabrication of a pyramid-shaped polyimide microelectrodes array for neural stimulation.     

基于云化ANP的巷道冒顶影响因素重要性研究

为了解巷道冒顶事故影响因素之间的关系及导致事故发生的重要性排序,根据专家评判语言的特点及各因素之间存在的语义网络联系性,提出了将云模型嵌入ANP来解决上述问题,即云化ANP模型。该模型既有云模型处理不确定信息的能力,也具有ANP处理网状因素系统的能力,尤其适合处理冒顶这类具有不确定性数据的分析问题。给出了云化ANP的构建过程和分析步骤。结合专家调查所得数据分析了影响冒顶因素的重要性排序,所举实例分析的因素重要性排序为:稳定岩层距巷道顶板表面的距离 >地下水渗水量 >巷道的跨度 >稳定岩层厚度 >顶板岩石的抗压强度 。最后将云化ANP算法应用于类似算法所处理的例子,通过这些例子的结果分析了云化ANP算法的正确性。     

基于Seam Carving的图像放大算法研究与改进

针对Seam Carving图像放大算法中,能量值前k小的像素带可能出现共用点的情况,提出了一种改进的图像放大自适应算法,通过判断图像中出现共用点的像素带的情况及计算其共用率的值,经过一定的策略确定待新增的像素带位置,该算法使得图像中视觉关注非重要信息区域像素带的增加能得到较均匀的分布;实现了人工干预选择视觉关注重要区域的方法,避免了自适应算法本身因误判视觉关注重要区域而带来关注对象发生变形扭曲的情况.实验证明,改进的算法能得到更好的放大效果.