Intramolecular crosslinking of poly(vinyl alcohol)

Poly(vinyl alcohol) is crosslinked in dilute solution (c=0.1 wt%) with glutaraldehyde. The reaction product is characterized by viscometry and gel permeation chromatography (g.p.c.). The intrinsic viscosity decreases with increasing degree of crosslinking and does not depend on temperature. G.p.c. reveals that the reaction product is not homogeneous, but consists of a mixture of particles with different sizes, possibly both intra- and intermolecularly crosslinked molecules. The intramolecularly crosslinked molecules are smaller in size than the initial polymer molecules and their size depends on the degree of crosslinking. They possess a narrow particle size distribution even if the initial polymer sample had a broad molecular weight distribution.     

大坝安全信息权研究

大坝原型观测数据本身包含了丰富的信息，内在反映了监测项目之间的某种客观关系，基于此，应用PCA法及PPA法建立了确定大坝安全评价信息权重的正分析模型，一方面能够对数据进行降维处理，另一方面能挖掘数据内在信息，提取指标的相对重要性；并基于最优化准则，建立了信息赋权整合模型，解决了多种数学方法计算结果不一致性问题，最大限度地保持原始信息的完整性。     

旋转导向钻井偏心稳定器横向振动研究

旋转导向钻井偏心稳定器横向振动研究是国家863“可控(闭环)三维轨迹钻井技术”课题研究的部分内容。选取偏心稳定器的心轴作为研究对象,以偏心稳定器心轴连续梁系统的横向振动模型受力分析为基础,根据课题研究中所设计的心轴结构形式,建立了与实际情况较为接近的三铰支点的连续梁系统横向振动方程;并分析了偏心稳定器横向振动对钻井工具和钻具系统的影响,为合理进行心轴设计以及偏心稳定器样机在现场的正确使用和钻井参数的合理选择,提供了科学的理论依据和实用的计算方法。计算实例表明,当钻压范围选择在80~250kN时,215.9mm井眼钻进中的确存在19~20、61~63、162~163r/min前三阶横向共振转速区间,因此在选择钻井参数时应通过钻压与转速的配合,尽可能避开横向共振转速,以保证下部钻具组合系统及作业安全。     

均匀设计法分析制备过程对钴钼硫化物催化剂机械强度的影响

建立了CoMoP/Al2O3加氢精制催化剂机械强度及其可靠性在制备过程中的数学模型,采用均匀设计考察了浸渍、干燥、煅烧、硫化4个制备过程中,浸渍时间、干燥温度、干燥时间、煅烧温度、煅烧时间、硫化温度和硫化升温速率7个实验因子对催化剂强度均值、Weibull模量的影响,同时考察了这些因素对颗粒密度的影响。方差分析表明所有模型都是充足的。实验结果表明,硫化过程是影响催化剂强度均值的主要过程。在实验范围内提高硫化温度、降低硫化时的升温速率有利于提高催化剂的强度。影响催化剂Weibull模量的因素主要为各个制备过程的交互效应。要提高催化剂强度的可靠性就必须全面考虑催化剂制备的各个过程,特别是各个制备过程的交互效应。     

应用SPC技术对机械零件加工过程的管理和控制

介绍了SPC(统计过程控制)技术原理，以某传动轴外径φ45 0.50^0.90 mm为控制对象，提出应用SPC技术，对机械零件加工过程进行管理和控制，从而达到过程失控预警、过程不断改进、过程能力不断提高的目的，继而保证产品质量的稳定和不断提高。     

影响道路沥青低温抗裂性能的因素

用弯曲梁流变仪、直接拉伸试验机对7种国内外油源沥青样品进行了低温抗裂性能的评价，从沥青的四组分、相对分子质量及其分布来分析其对沥青低温抗裂性能的影响，结果表明，沥青的相对分子质量分布宽，对沥青的低温抗裂性能有利。     

Application of piece‐wise linear weight functions for 2D 8‐node quadrilateral element in contact problems

The present study is a continuation of our previous work with the aim to reduce problems caused by standard higher order elements in contact problems. The difficulties can be attributed to the inherent property of the Galerkin method which gives uneven distributions of nodal forces resulting in oscillating contact pressures. The proposed remedy is use of piece‐wise linear weight functions. The methods to establish stiffness and/or mass matrix for 8‐node quadrilateral element in 2D are presented, i.e. the condensing and direct procedures. The energy and nodal displacement error norms are also checked to establish the convergence ratio. Interpretation of calculated contact pressures is discussed. Two new 2D 8‐node quadrilateral elements, QUAD8C and QUAD8D, are derived and tested in many examples, which show their good performance in contact problems. Copyright © 2004 John Wiley & Sons, Ltd.     

A simple approximation algorithm for the weighted matching problem

We present a linear time approximation algorithm with a performance ratio of 1/2 for finding a maximum weight matching in an arbitrary graph. Such a result is already known and is due to Preis [STACS'99, Lecture Notes in Comput. Sci., Vol. 1563, 1999, pp. 259-269]. Our algorithm uses a new approach which is much simpler than the one given by Preis and needs no amortized analysis for its running time.     

高分子量丙烯酰胺-DAC共聚物的研制

采用复合引发体系 ,以丙烯酰胺 (AM)和阳离子单体丙烯酰氧乙基三甲基氯化铵(DAC)为共聚体 ,进行水溶液绝热聚合 ,研制了一种DAC单体含量为 4 0 %～ 5 0 %、相对分子质量大于 1× 10 7的阳离子型聚丙烯酰胺。     

Another Perspective on Vocabulary Richness

This article examines the usefulness ofvocabulary richness for authorship attributionand tests the assumption that appropriatemeasures of vocabulary richness can capture anauthor's distinctive style or identity. Afterbriefly discussing perceived and actualvocabulary richness, I show that doubling andcombining texts affects some measures incomputationally predictable but conceptuallysurprising ways. I discuss some theoretical andempirical problems with some measures anddevelop simple methods to test how wellvocabulary richness distinguishes texts bydifferent authors. These methods show thatvocabulary richness is ineffective for largegroups of texts because of the extremevariability within and among them. I concludethat vocabulary richness is of marginal valuein stylistic and authorship studies because thebasic assumption that it constitutes awordprint for authors is false.