基于混合图像分割与梯度算法的发光物体图像重建技术研究

传统的图像重建算法存在光源分布不均以及噪声干扰等问题,导致图像重建效果差。针对该问题,提出了一种改进的混合图割算法和梯度算法的发光体图像重建技术。算法首先采用图像分割算法得到在未知先验条件的情况下的发光源情况;然后利用不同的梯度算法,根据重建状态得到发光源准确的分布情况;最后利用内部光源的多级网络提高计算速度和重建的准确性。仿真实验结果表明,本方法即使在存在检测噪声和模型结构误差的情况下,仍然能够得到很好的重建性能,具有较高的实际应用价值。     

无线传感器网络不确定数据PT-Top k查询处理技术

在无线传感器网络现实应用中,感知数据普遍存在不确定性。由于不确定数据引入了概率维度,使得不确定数据查询种类更加丰富,同时也给查询处理带来困难。不确定数据Top-k查询是一个典型的不确定数据查询任务。考虑到无线传感器网络查询处理技术对查询响应时间和网络通信消耗的高要求,研究了面向层次聚簇结构的无线传感器网络不确定数据Top-k查询处理技术。通过分析不确定数据特点,基于x-tuple规则元组模型,采用簇内与簇间的两阶段数据查询处理机制,提出了基于Poisson分布的分布式不确定数据PT-Top k查询处理近似算法TPQP。通过实验,从总体通信消耗、与概率阈值p相关分析、与排序数k相关分析以及数据敏感度分析等方面,说明了TPQP算法在通信消耗、查询响应时间上的优越性。     

聚醚型聚氨酯的氢键、微相分离及性能

用本体一步法合成了5种不同硬段含量(11.0％～46.9％)的二苯甲烷-4,4′-二异氰酸酯/环氧乙烷封端型聚环氧丙烷聚醚/乙二醇的聚醚型聚氨酯,并借助于IR,DSC,DMS和材料试验机等手段对该聚氨酯的氢键、微相分离及力学性能进行了表征。结果表明:随着硬段含量的增加,其>NH与微区中的>C=O的氢键化程度逐渐提高,软段微区中—O—的氢键化程度逐渐降低;微相分离程度逐渐提高;拉伸强度及硬度随之增加,扯断伸长率在硬段含量40％左右出现极大值。     

Thermal properties measurements of renatured gelatin using conventional and temperature modulated differential scanning calorimetry

The thermal properties of amorphous gelatin films and gelatin films with renatured structural order were measured by using conventional and temperature modulated differential scanning calorimetry (DSC). Different amounts of gelatin structural order associated with a melting enthalpic change in the DSC measurement were prepared based on different gelatin drying conditions. Two consecutive heating and cooling DSC measurements on the gelatin films showed that there was no change in the glass‐transition temperature (T_g) for the amorphous gelatin but there was a decrease in the T_g for the structural gelatin on the second DSC scan. This decrease was attributed to the plasticizing effect from the release of originally hydrogen‐bonded water associated with the structural gelatin. In addition, a reversing endotherm observed upon melting of the structural gelatin during a temperature modulated DSC measurement indicated that the transition of bound water to free water occurred as the partial triple‐helix gelatin melted. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1795–1801, 2006     

重防腐涂料在冶金行业的应用

阐述了涂料的防腐蚀机理，并结合冶金企业设备防腐蚀应用实例，介绍了两种新型防腐蚀涂料。     

循环流化床中流动结构的动态变化

采用激光相位多普勒粒子分析仪（ＰＤＰＡ）测量了二维循环流化床中局部颗粒运动行为及流动结构．通过将ＰＤＰＡ采集的数据进行动态图形化处理，研究了稀、密相的结构以及颗粒聚团的形成和分解．研究结果表明：在循环流化床中不仅存在稀、密两相的不均匀流动结构，而且密相和稀相自身内部也存在不均匀性；颗粒聚团的形成和分解是一个动态过程，颗粒间不同速度造成颗粒相互碰撞，密相能够分解形成稀相，稀相能够合并成为密相．在流动过程中稀相、密相及介于稀、密相间的乳相以动态的形式存在和分解，形成复杂的动态流动结构．     

RF sputter deposition of poly(tetrafluoroethylene) films as masking materials for silicon micromachining

Polymers have been studied extensively because of their wonderful array of properties. Their properties can be tailored by many means and can be made useful in many ways. Polymers can be crosslinked or branched and can provide different properties, such as conduction and passivation. This study dealt with the RF sputter deposition of poly(tetrafluoroethylene) (PTFE) films with the aim of using them as masking materials during the fabrication of various micromachined structures. The films were deposited on silicon substrates at different plasma powers (100, 150, and 200 W) for a constant deposition time (60 min). To test the masking properties, the deposited films were immersed in a 20 wt % aqueous KOH solution at 80°C for 60 min. The films showed lower contact angles and interfacial tension, and this indicated good adhesion of the films to the silicon substrates. Good adhesion is an essential quality of masking materials during micromachining. The structural properties of the as‐deposited and etched films were studied with Fourier transform infrared and X‐ray photoelectron spectroscopy. These indicated that the bonding groups and binding energies of C? F and C? CF matched the reported values well. Furthermore, the presence of C? F and C? CF bonds, even after the etching of silicon substrates in highly alkaline KOH solutions for 60 min, showed that the PTFE films remained unchanged in the etchant and, therefore, could function as good masking materials during the fabrication of micromachined structures. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1183–1192, 2004     

2,2￠,6,6￠-四甲基-4,4￠-二苯氧基二苯砜、二苯醚和对苯二甲酰氯三元无规共聚物的合成与表征

以2,2￠,6,6￠-四甲基-4,4￠-二苯氧基二苯砜(o-M2DPODPS)、二苯醚(DPE)和对苯二甲酰氯(TPC)为单体，在无水AlCl3和N,N-二甲基甲酰胺(DMF)存在的条件下，于1,2-二氯乙烷(DCE)中进行低温溶液无规共缩聚，合成了一系列新型线型高分子量含双邻甲基取代结构的聚醚砜醚酮酮(DM-PESEKK)/聚醚酮酮(PEKK)无规共聚物，并用IR, DSC, XRD, TGA和1H-NMR等方法对共聚物进行了表征分析，考察了共聚物的溶解性能. 结果表明，随着DM-PESEKK含量的增加，玻璃化转变温度(Tg)逐渐升高，熔融温度(Tm)逐渐降低，结晶度下降，溶解性得到明显改善.     

渣油加氢催化剂孔结构对反应活性的影响

在3L中型加氢试验装置上考察了渣油加氢脱硫催化剂孔结构对反应活性的影响，试验结果表明，当孔结构发生变化时，催化剂的脱硫、脱氮、脱残炭及脱金属反应活性呈现不同的变化规律。     

多壁纳米碳管的超声短切处理

采用超声方法对多壁纳米碳管进行短切处理，比较系统地考察了超声时间对纳米碳管的长度、孔结构和形貌的影响。结果表明，超声粉碎可以有效地短切多壁纳米碳管，随超声时间的延长，纳米碳管的长度显著减小。在超声处理120min后，纳米碳管被短切到平均长度为400nm。超声短切后的纳米碳管比表面积和孔容均显著增加。进一步延长超声时间，其比表面积和孔容反而下降。