Viscous behaviour of glass-forming liquids: a thermodynamic approach

The temperature dependence of the viscosity of the undercooled melts exhibits an important role in the study of nucleation, crystal growth and the glass-forming ability of materials. Several attempts have been made to study the viscous behaviour of the glass-forming melts and these investigations are mainly based on free volume theory as well as on the configurational entropy model. In the present investigation, an attempt has been made to correlate the thermodynamic parameters with the viscosity of the glass-forming melts and to study the temperature dependence of the viscosity of undercooled liquids on the basis of the free volume theory as well as on the basis of the configurational entropy model of Adam and Gibbs. The entire study is confined on the expression for thermodynamic parameters reported by the authors recently. The expression obtained has been successfully applied to study the temperature dependence of the viscosity of the metallic, molecular and oxide glass-forming liquids.     

低温下液体饱和蒸气压的测试

着重介绍了静态法测试低温下（－１００～５０℃）液体饱和蒸气压的原理及方法，给出了低温下液体全氟三乙胺饱和蒸气压的测试结果，并进行了讨论。     

Conductor design with high-Tc superconducting Bi(Pb)—2223/Ag multifilamentary tapes

With high upper critical fields, high temperature superconductors (HTSC) have been recognised as candidate materials for coil and magnet applications. High field devices, at one time or another, when operated close to their rated limits are often faced with instability problems which normally are electrical, magnetic or mechanical in nature. The determination of stability parameters, therefore, is of interest to the conductor designer which very much assists in the processing aspect of long length production of wires and tapes. Due to the morphology of the superconductor most HTSC devices made with Bi(Pb)—2223 precursor exist in tape form. Here the determination of stability parameters (for flux-jump and cryogenic stability) for multifilamentary Bi(Pb)—2223/Ag tapes are presented. Processing parameters such as intermediate deformation and filling factors have been found to play a crucial role, not only on the critical current density of the tapes but on the stability aspect in conductor design as well.     

Factors Affecting 1-Octen-3-ol in Mushrooms at Harvest and During Postharvest Storage

Harvesting experiments revealed that immature whole mushrooms with closed veils had higher 1-octen-3-0l levels than more mature whole mushrooms with open veils. The l-octen-3-01 content of the gills was higher in immature mushrooms with closed veils, gradually decreased with maturity as the veil opened, and finally increased after the gills were well exposed. Postharvest experiments demonstrated that storage temperature influenced the activity of lipoxygenase-hydroperoxide lyase, but no differences in 1-octen-3-01 content were observed. Enzyme activity as well as 1-octen-3-01 content decreased during storage. Addition of calcium chloride to irrigation water, employed to improve quality and shelf life of fresh mushrooms, increased the amount of l-octen-3-01 immediately after harvest.     

K202A压缩机电机轴瓦超温的原因及对策

K202A压缩机的电机轴瓦采用的是动压轴承,经常持续升温。其主要原因是由于滑动轴承和轴之间是半液体摩擦,润滑油在轴颈及轴瓦之间没有形成具有足够压力的油膜,造成滑动轴承和轴局部形成半液体摩擦而产生大量的热量,又无法被带走引起的。文章通过验算K202压缩机电机滑动轴承温度,分析影响滑动轴承运行温度的因素,提出在原滑动轴承上开油楔及加装一台齿轮油泵为滑动轴承强制润滑,并且通过联轴器把电机和压缩机连接起来,用压缩机轴瓦托起电机轴,使电机轴颈和轴瓦之间处于液体摩擦状态,可有效地降低滑动轴承的运行温度。     

20CrMo棒材带状组织的控制研究

通过Gleeble-1500热模拟机对20CrMo轧材精轧阶段轧制过程及冷却过程的模拟,研究了终轧温度、冷却速度对室温组织的影响,分析了形成带状组织的条件,最终得出了理想室温组织的终轧温度和冷却速度。     

Monolithic Catalysts with Low Noble-Metal Content for Exhaust Purification of Small Gasoline Engines

A series of low noble-metal coment monolithic catalysts for exhaust purification of small gasoline engines was investigated, and it was found that the Pt/Rh-OSM/Al2O3 （where OSM was oxygen storage material） catalyst with Ce0.5Zr0.5-MnOx（3%MnOx） OSM held low light-off temperature for CO, HC, and NO; quite wide three-way window, and outstanding thermal stability. The catalyst could efficiently comrol exhaust emission of small gasoline engines.     

Effect of Microstructure on the Accelerated Creep of 20CrMoV12‐1 and P 91 Steels

In the initial part the change of microstructure for steel X20 CrMoV 121 is discussed in terms of the distribution of carbide precipitates and its effects on accelerated creep resistance and hardness are presented. In the following, experimental results of microstructure and accelerated creep resistance are presented for the steels X20CrMoV 121 and P91 annealed for up to 8760 hours at 650°C and 750°C before the testing. A similar evolution of the distribution of carbide particles of a size above 102 nm is found for both steels, while the accelerated creep resistance is diminished much stronger for the steel X20CrMoV 121. This difference is due to a greater stability of NbC than that of VC precipitates, both related to the evolution of the chemical composition of complex chromium, molybdenum and iron carbide particles.     

温度场下超长楼板中抗裂筋的定量分析

本文对超长结构楼板在温度场下的行为进行理论研究和计算分析，并推导简便可行的计算公式。为超长楼板抗裂筋设计提供定量的方法，可供相关专业技术人员参考。     

ZST微波陶瓷在介质振荡器上的应用研究

用传统固相法制备ZST(氧化锆-氧化锡-氧化钛)系微波陶瓷,研究了ZST系微波陶瓷的组成对介电性能的影响。通过X-射线衍射(XRD)和HP8714ET网络分析仪对其晶体结构和微波介电性能进行研究,实验结果表明:少量掺Bi2O3的ZST系陶瓷材料可把烧结温度降低至1 260℃,微波介电性能较好;掺入量大于2%(质量分数)时,ZST系微波陶瓷在晶界偏析形成了Bi2Ti2O7新相,微波性能下降。用微波介电性能较好的ZST系陶瓷制成的介质振荡器进行测试,其电性能满足设计要求。