Thermal Stability of Some Metabolically Conjugated Potential Precursors of Flavor Components in Meat and Milk

The stability of selected metabolic conjugates (phenylphosphate, phenylglucuronide, naphthylglucuronide, and naphthylsulfate) was evaluated in model systems. Phenylphosphate was less stable than the glucuronides and the sulfate, especially under neutral (pH 6.8) and acidic conditions (pH 1.5). Phenylphosphate was completely degraded after 1.7 hr at 100°C, and after 0.3 hr at 150°C at pH 6.8. The glucuronide and sulfate conjugates were especially stable under neutral conditions (pH 6.8) requiring > 5 hr for complete hydrolysis at 100°C. All conjugates were quite stable to hydrolysis under alkaline conditions (pH 11). The presence of certain organic solvents (ethyl acetate or ethyl ether) caused rapid hydrolysis of conjugates under very mild conditions (40°C for 30 min). This information may improve under-standing of flavor production from animal products.     

4，4＇－二苯醚二甲酸改性PET的热性能研究

采用示差扫描量热和热重分析的方法对合成的不同４，４＇－二苯醚二甲酸（ＯＢＢＡ）含量的共聚酯的热性能进行了研究。结果发现共聚酯的熔点和热结晶温度与ＰＥＴ相比有所降低；而冷结晶温度则升高。随着ＯＢＢＡ添加量的增加，在恒温热重分析中热失重速率常数减小；在升温热重分析中，热失重活化能则增加。所有的实验结果皆表明，芳族醚键的引入对提高共聚酯的热性能有重要作用。     

全液压稠油热力开采过程井下流体的传热

针对稠油黏度高、密度大、驱替效率低,常规方法开采困难等问题,开展了稠油开采装置研究。介绍了全液压稠油开采装置在原油开采过程中的加热功能,分析了采油装置系统井下流体流动及传热过程。结合理论研究方法和热力学计算,建立了井下流体热交换的物理和数学模型,并对模型进行了分析、矫正和求解。以实际油井参数和液压油的流量、温度为输入参数,通过计算机仿真模拟了井下热交换参数之间的关系,从而改进了已获得的热交换理论方程和模型,并得出了原油的产量与液压油的输入量之间的关系,以及保温提采原油所需要的最小液压油输入量。该模型的建立为进一步研究不同井况和不同输入状态下的流体传热提供了理论依据。     

高压注水管柱受力分析

进行高压注水管柱受力分析的目的就是根据注水条件研究注水管柱在不同过程中的各类效应，以及这些效应对管柱产生的受力和变形规律，从而明确注水管柱的工作状态，保障注水管柱有效合理地工作。较详细地分析了高压注水管柱在锚定、坐封以及注水3个过程中的受力状态和变形情况，并分析了高压注水管柱在不同过程中受到的各种效应的影响，推导出注水管柱在不同过程中的应力及变形的计算公式，并给出了算例。     

论提高罐式法海绵铁质量的途径

通过对原料的选择、热工制度的控制及操作等因素进行分析和论述，探讨了提高海绵铁质量的途径。     

纤维复合材料的热膨胀系数

提出了一种利用压电光声技术测量材料热膨胀系数的实验方法,并测试了单向复合材料C/C、C/Al的横向、纵向的热膨胀系数。根据已有的理论计算方法与实验结果对该方法的测试结果进行验证,证明了该检测方法的可靠性,进而又测量了C/C、C/Al材料在任一方向上的热膨胀系数。这种方法克服了理论计算过程复杂以及常规手段无法测量任一方向上热膨胀系数的缺陷。     

Modelling thermal degradation of composite materials

A one–dimensional, transient thermal degradation heat transfer model for the response of composite materials when exposed to fire is presented. The model can handle layers of different materials. Material properties are functions of temperature. The reaction can be specified using Arrhenius‐type parameters or by inputting a density–temperature relationship determined by any experimental technique such as thermogravimetric analysis. The model is validated against the experimental data presented in Boyer's 1984 dissertation. Overall, the model provides excellent agreement with the experimental data. It is shown that very little difference is found between results arrived at by Arrhenius kinetics and results obtained by specifying the easier to measure density–temperature relationship. From this it is concluded that this technique is a viable alternative to Arrhenius‐type models. Copyright © 2006 John Wiley & Sons, Ltd.     

激光结晶a-Si:H SOI离子注入和快速退火

本文对激光结晶a-Si∶H SOI结构砷注入和快速退火行为作了研究.a-Si∶H激光结晶有Lp-LCR,OD,FCR-2,FCR-1四个结晶区.用剖面电镜观察了结晶区的结构.扩展电阻测量表明Lp-LCR区中有两种扩散机制,即杂质在晶粒体内扩散和沿缺陷扩散.OD区中有三种扩散形式,除有上述两种以外,还有沿缺陷的扩散.首次比较了沿晶界和缺陷的扩散速度.     

A dynamic linear programming approach to market allocation of renewable resources in the italian energy system: The case of solar thermal and biogas technologies

In Italy solar thermal energy and energy from biogas are two possible means of reducing dependence on energy imports. Using a multiperiod LP model (MARKAL) the authors assessed the likely potential of both technologies under various circumstances. The study covered the period 1980–2005, in five segments of five years. It focused only on the subsystem of the energy end-uses which can be substituted for by solar thermal and biogas technologies. The overall non-renewable sources which can be saved in 20 years by these technologies total 450 PJ (1 PJ = 10^{1 5} J) if the fuel prices rise at 0 per cent average annual, 1450 PJ if the fuel prices rise at 4.2 per cent average annual, 1860 PJ if the fuel prices rise at 7.2 per cent average annual and 3780 PJ if the fuel prices rise at 15 per cent average annual. However the most competitive technologies appear to be solar water heaters used mainly in the private and commercial sectors and biogas systems used mainly in the agricultural sector. The study was carried out by APRE under ENEA (formerly CNEN) contract and was intended to serve as an analytical basis for establishing an overall development and demonstration strategy for end-use renewable technologies in Italy.