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101.
102.
《Organic Electronics》2014,15(7):1672-1677
In this paper organic thin film transistors (OTFTs) are directly fabricated on fabric substrates consisting of Polyethylene Terephthalate (PET) fibers. A key process is coating the polymer layers on the fabric in order to reduce the large surface roughness of the fabric substrate. Two polymers, i.e. polyurethane (PU) and photo-acryl (PA), are used to reduce the large surface roughness and simultaneously improve the process compatibility of the layers with the subsequent OTFTs processes while also retaining the original flexibility of the fabric. The surface roughness of the PU/PA-coated fabric is significantly reduced to 0.3 μm. Furthermore, the original flexibility of the PET fabric remained after coating of the PU/PA polymer layers. The mobility of the OTFTs fabricated on the PU-PA coated fabric substrate is 0.05 ± 0.02 cm2/V s when three PA layers and 90 nm thick pentacene layer were used. The performance does not vary even after 30,000 bending test. 相似文献
103.
104.
相对于Ⅱ-Ⅵ族二元化合物,三元合金在调节带隙宽度和晶格常数上的灵活性使其应用前景更加广阔,并有希望解决Ⅱ-Ⅵ族材料普遍存在的单极性掺杂难题而成为未来新型光电器件发展的一个重要方向.文章着重介绍了分子束外延(MBE)技术生长ZnSeTe、CdZnTe、CdSeTe等Ⅱ-Ⅵ族三元合金单晶薄膜的研究现状,分析了MBE生长三元合金时需要考虑的问题,介绍了Ⅱ-Ⅵ族半导体材料n/p型掺杂的常用元素和掺杂方式,讨论了限制Ⅱ-Ⅵ族材料有效掺杂的物理机制和三元合金在掺杂方面的研究动态,并对三元合金薄膜的发展前景进行了展望. 相似文献
105.
Paul Sonntag Jan Haschke Sven Kühnapfel Tim Frijnts Daniel Amkreutz Bernd Rech 《Progress in Photovoltaics: Research and Applications》2016,24(5):716-724
We present an interdigitated back‐contact silicon heterojunction system designed for liquid‐phase crystallized thin‐film (~10 µm) silicon on glass. The preparation of the interdigitated emitter (a‐Si:H(p)) and absorber (a‐Si:H(n)) contact layers relies on the etch selectivity of doped amorphous silicon layers in alkaline solutions. The etch rates of a‐Si:H(n) and a‐Si:H(p) in 0.6% NaOH were determined and interdigitated back‐contact silicon heterojunction solar cells with two different metallizations, namely Al and ITO/Ag electrodes, were evaluated regarding electrical and optical properties. An additional random pyramid texture on the back side provides short‐circuit current density (jSC) of up to 30.3 mA/cm2 using the ITO/Ag metallization. The maximum efficiency of 10.5% is mainly limited by a low of fill factor of 57%. However, the high jSC, as well as VOC values of 633 mV and pseudo‐fill factors of 77%, underline the high potential of this approach. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
106.
Very thin films, less than 100 nm-thick, are used in a variety of applications, including as catalysts and for thin film reactions
to form patterned silicides in electronic devices. Because of their high surface to volume ratio, these very thin films are
subject to cap-illary instability and can agglomerate well below their melting temperatures. In order to develop a general
understanding of agglomeration in very thin films, we have studied initially continuous and patterned films of gold on fused
silica substrates. Two in situ techniques were used to monitor agglomeration: 1) heating and video recording in a transmission
electron microscope, and 2) measurement of the intensity of laser light transmitted through a sample heated in a furnace.
Electron microscopy allowed inves-tigation of the role of the microstructure of the Au film and analysis of light transmis-sion
during heating allowed determination of temperature-dependent and film-thick-ness-dependent agglomeration rates. These results
will be described along with models for the agglomeration process. 相似文献
107.
为提高薄膜电池对光的捕获能力, 将平面硅薄膜电池制 作成矩形空芯波导结构,对其太阳光注入方式、光捕获能力和光-电转换效能进行了理论和 实验探讨。基于 多层膜反射理论和波导反射模型对波导电池光捕获效果的预测表明,波导电池能够将入射光 限制在空芯结 构内多次反射和吸收,具有较平面电池更高的光捕获能力。测定了不同平行光束在不同入射角度 下平面和波导 电池的光捕获功率和光-电转换效能的结果表明,波导电池对入射光功率近似全部捕获,其 光-电功率转换效能 较对应的平面电池有3~5倍的提升。对不同截面尺寸和长度的单结空芯波导电池光捕获率 进行了计算,提 出从电池膜层结构和空芯几何尺寸参数优化硅薄膜矩形空芯波导电池的思路,通过优化有 望实现用小于多结平面电池外形尺寸的单结空芯波导电池达到更好的光捕获效果。 相似文献
108.
109.
The unique properties of 2D-materials like graphene are exploited in various electronic devices. In sensor applications, graphene shows a very high sensitivity, but only a low specificity. This shortcoming can be mastered by using heterostructures, where graphene is combined with materials exhibiting high analyte selectivities. Herein, this study demonstrates the precise deposition of nanoporous metal-organic frameworks (MOFs) on graphene, yielding bilayers with excellent specificity while the sensitivity remains large. The key for the successful layer-by-layer deposition of the MOF films (SURMOFs) is the use of planar polyaromatic anchors. Then, the MOF pores are loaded with ionic liquid (IL). For functioning sensor devices, the IL@MOF films are grown on graphene field-effect transistors (GFETs). Adding a top-gate electrode yields an ion-gated GFET. Analysis of the transistor characteristics reveals a clear Dirac point at low gate voltages, good on-off ratios, and decent charge mobilities and densities in the graphene channel. The GFET-sensor reveals a strong and selective response. Compared to other ion-gated-FET devices, the IL@MOF material is relatively hard, allowing the manufacturing of ultrathin devices. The new MOF-anchoring strategy offers a novel approach generally applicable for the functionalization of 2D-materials, where MOF/2D-material hetero-bilayers carry a huge potential for a wide variety of applications. 相似文献
110.
Harvesting Lost Photons: Plasmon and Upconversion Enhanced Broadband Photocatalytic Activity in Core@Shell Microspheres Based on Lanthanide‐Doped NaYF4, TiO2, and Au 下载免费PDF全文
Zhenhe Xu Marta Quintanilla Fiorenzo Vetrone Alexander O. Govorov Mohamed Chaker Dongling Ma 《Advanced functional materials》2015,25(20):2950-2960
Efficiently harvesting solar energy for photocatalysis remains very challenging. Rational design of architectures by combining nanocomponents of radically different properties, for example, plasmonic, upconversion, and photocatalytic properties, offers a promising route to improve solar energy utilization. Herein, the synthesis of novel, plasmonic Au nanoparticle decorated NaYF4:Yb3+, Er3+, Tm3+‐core@porous‐TiO2‐shell microspheres is reported. They exhibit high surface area, good stability, broadband absorption from ultraviolet to near infrared, and excellent photocatalytic activity, significantly better than the benchmark P25 TiO2. The enhanced activity is attributed to synergistic effects from nanocomponents arranged into the nanostructured architecture in such a way that favors the efficient charge/energy transfer among nanocomponents and largely reduced charge recombination. Optical and energy‐transfer properties are modeled theoretically to support our interpretations of catalytic mechanisms. In addition to yielding novel materials and interesting properties, the current work provides physical insights that can contribute to the future development of plasmon‐enhanced broadband catalysts. 相似文献