Electrochemical investigation of LiNi0.5Mn1.5O4 thin film intercalation electrodes

This work provides kinetic and transport parameters of Li-ion during its extraction/insertion into thin film LiNi_0.5Mn_1.5O₄ free of binder and conductive additive. Thin films of LiNi_0.5Mn_1.5O₄ (0.2 μm thick) were prepared on electronically conductive gold substrate utilizing the electrostatic spray deposition technique. High purity LiNi_0.5Mn_1.5O₄ thin film electrodes were observed with cyclic voltammetry, to exhibit very sharp peaks, high reversibility, and absence of the 4 V signal related to the Mn³⁺/Mn⁴⁺ redox couple. The electrode subjected to 100 CV cycles of charge/discharge delivered a capacity of 155 mAh g⁻¹ on the first cycle and sustained a good cycling behavior while retaining 91% of the initial capacity after 50 cycles. Kinetics and mass-transport of Li-ion extraction at LiNi_0.5Mn_1.5O₄ thin film electrode were investigated by means of electrochemical impedance spectroscopy. The apparent chemical diffusion coefficient (D_app) value determined from EIS measurements changed depending on the electrode potential in the range of 10⁻¹⁰-10⁻¹² cm² s⁻¹. The D_app profile shows two minimums at the potential values close to the peak potentials of the corresponding cyclic voltammogram.     

The evaluation of the polarization resistance in a tubular electrode and its application to the hydrogen electrode reaction

An alternative method for the determination of the kinetic parameters involved in the elementary steps of the reaction mechanism of the hydrogen electrode reaction is proposed. It is based on the determination of the variation of the polarization resistance in a tubular platinum electrode with a laminar flow of electrolyte as a function of the activity of protons of the electrolyte solution. A theoretical expression that relates the experimental variables and the equilibrium polarization resistance is developed, which takes into account the current distribution along the electrode surface. The results are compared with others obtained previously, contributing to the verification of the kinetic mechanism through a completely different experimental procedure.     

浸渍增重率和反渗率研究

对浸溃过程中浸渍剂沥青的浸入率和反渗率进行了分析与探讨。提出了理想增重率、理论增重率与实际增重率的概念和计算方法。并比较了实际增重率与操作增重率的差别。同时分析了抽真空的绝对压力与施压的绝对压力对各项增重率和反渗率的影响。     

锂离子电池正极材料的现状与发展

介绍了锂离子正极材料氧化钴锂、氧化镍锂、氧化锰锂、磷酸铁锂等研究开发和现状,对其特性进行了较为全面的总结。     

Ultrasonic spray pyrolysis of nano crystalline spinel LiMn2O4 showing good cycling performance in the 3 V range

Spherical lithium manganese oxide spinel was synthesized by an ultrasonic spray pyrolysis method, and has been characterized using X-ray diffraction, scanning electron microscopy, transimission electron microscopy and electrochemical cycling at 3 V regions. The LiMn₂O₄ powders were composed of about 10 nm-sized primary particles. The delivered discharge capacity of the synthesized nano-material was 125 mAh g⁻¹ between 2.4 and 3.5 V and its retention was about 96% upon 50 cycling. From the high resolution transmission electron microscopic study, it was found that structural transition of the parent material did not occur even after the 50th electrochemical cycling on the 3 V region. It seems that the reversible structural change is possible for nanocrystalline LiMn₂O₄ as observed by the X-ray diffraction and transition electron microscopic observations.     

基于区域权函数理论的多电极电磁流量计电极设计

基于Shercliff权函数提出区域权函数概念,设计多电极电磁流量计,通过测量管道截面不同位置的弦端电压,计算各区域的轴向平均速度,实现速度分布与体积流量的测量。着重研究了流量计电极设计,选取不锈钢平头方案的多电极电磁流量计,对于阀门下游的非轴对称单相流体积流量测量精度高于±1.0%,倾斜管固—液两相流实验证明:该设计对于两相流非轴对称的速度分布测量具备可靠性。     

阵列式多针-柱电极装置实现离子风的实验与分析

为了实现一定气体流速的离子风,设计了一种新型的阵列式三排3 ×3垂直放置的针-柱电极结构放电装置.在针-柱之间间距为3mm、排与排之间间距为8 mm、镇流电阻12 MΩ、放电电阻12 MΩ、测试电阻1 kΩ、大气压环境、室温、无外部通入气流时,阵列式针-柱电极实现了稳定的电晕放电,并通过示波器记录的放电波形、数码相机拍摄的发光图像以及放电伏安特性曲线进行了验证.同时,随着阵列式排数的增加,放电电流变大,离子风风速也随之增大.该针-柱结构易于用MEMS工艺加工制作,可应用于便携式分析仪器中.     

基于移动锚节点与多级通信的三维传感器网络节点自定位算法研究

在基于移动锚节点的三维传感器网络节点自定位算法SNLSFA(Sensor Node Localization Scheme based on Flying Anchors)的基础上,提出了一种新的基于移动锚节点与多级通信的三维传感器网络节点自定位算法SNLSFAMC(Sensor Node Localization Scheme based on Flying Anchors and Multi-level Communication)。首先由移动锚节点提供3个或4个辅助定位点,再由辅助定位点得到两条非平行线段,然后过线段中点分别做垂直于线段的平面,经两平面相交后得到一条经过待定位节点的直线,最后利用辅助定位点与待定位节点之间的距离作为通信半径即可得到待定位节点的位置。仿真结果表明,与SNLSFA相比,在相同锚节点数量下,SNLSFAMC提高了定位精度,且在相同定位精度下,SNLSFAMC降低了对锚节点数量的需求,提高了算法的响应时间。     

基于3DMax技术的胡杨茎生长模拟

植物生长模拟研究,是利用计算机技术以可视化的形式描述植物的生长状态。本研究在综合国内外相关研究成果的基础上,以南疆胡杨茎为研究对象,通过对胡杨茎的生长因子及结构形态的研究,提出一种基于三维结构的胡杨茎生长模型,并运用3DMax技术建模,实现胡杨茎的生长形态的可视化。本研究能促进人们对胡杨生长过程的理解和感知,为分析胡杨结构功能关系、调控生长模式等提供重要参考。     

Study of mass transfer in a vertically moving particle bed electrode

A study was made of the influence of process parameters on the mass-transfer coefficient in a flow-through cell with a cascade of rotating drums partially filled with conductive particles (called the vertically moving particle bed). Copper deposition from an acidic sodium sulphate solution was used as the model reaction. To evaluate the experimental data a macrohomogeneous mathematical model of potential and current density distribution inside the cell was developed. The electrolyte flow distribution between the empty space above the particle bed and through the bed was evaluated. On the basis of these results the following correlation is proposed: