Amide–acid functional SiO2 nanocomposites based on new semi‐crystalline poly(ether‐sulfone‐amide): thermal,combustion and mechanical studies

New amide–acid functional SiO₂ nanoparticle (FSNP)‐reinforced semi‐crystalline aliphatic–aromatic poly(ether‐sulfone‐amide) (PESA) was synthesized using a solution method in dimethylformamide. The surfaces of SiO₂ nanoparticles were functionalized with phthalic anhydride, and subsequently PESA was synthesized using direct polymerization with good yield and desired molar mass. PESA / SiO₂ nanocomposites (PSNCs) were prepared with three different contents of FSNP and the morphology and mechanical, thermal and combustion properties of the PSNCs were studied. The results of X‐ray diffraction, field‐emission scanning electron microscopy and transmission electron microscopy showed a uniform dispersion for FSNP in the PESA matrix. According to the results of mechanical tests, the tensile strength and the Young's modulus of PESA were enhanced by FSNP loading. Thermogravimetric analysis and derivative thermogravimetry results showed a substantial improvement in thermal properties of PESA. The temperature at 5% mass loss was increased from 371.7 to 395.8 °C for the PSNC containing 8 mass% of FSNP, as well as the char yield being enhanced greatly, which was about 30% higher than that of neat PESA. Significant improvements in combustion properties were observed for PSNCs from microscale combustion calorimetry. The peak heat release rate showed an obvious improvement and decreased by about 57% compared to that of neat PESA on 8 mass% loading of FSNP. © 2016 Society of Chemical Industry     

Preparation,optimization, characterization and in vivo pharmacokinetic study of asiatic acid tromethamine salt-loaded solid lipid nanoparticles

Purpose: To enhance the oral bioavailability of asiatic acid tromethamine salt (AAS) by encapsulation in solid lipid nanoparticles (SLN).

Methods: The AAS-loaded SLN (AASLN) was prepared by the modified solvent injection method with glycerin monostearate (GMS) as lipid and poloxamer 188 as surfactant. A Box–Behnken design was used to optimize the formulations. Physicochemical characterization was carried out by using dynamic light scattering, scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). Stabilities at 4?°C and pH 1.2 were investigated by particle size or/and entrapment efficiency (EE%). The in vivo pharmacokinetics was evaluated by HPLC-MS/MS.

Results: The optimal formulation of AASLN had an average size of 237?nm with zeta potential of ?35.9?mV, and EE% of 64.4%. SEM showed that the AASLN had spherical shape with smooth surface. Furthermore, DSC and X-ray analyses indicated that AAS was amorphous state and the crystal degree of GMS was significantly decreased in the formulation. AASLN showed excellent stability at 4?°C for 1 month and no coacervation at pH 1.2. The bioavailability of AAS in SLN was found to be 2.5-fold higher than that of AAS alone after a single oral administration in rats.

Conclusions: This study reveals that SLN is developed as a promising oral delivery system of AAS with significantly enhanced bioavailability and good storage stability.     

集中供暖换热站扩容供热方式的选择

通过对某换热站新增区域的供热方式与原采暖用户进行系统分析,建议新增区采用间接连接和混水直接连接两种方案,并对两种方案给出详细的设计说明;通过对两种方案进行整体比较分析,综合得出混水直供换热方式运行经济,供热效果良好,尤其是区域供热新增区或新建区采暖用户的供热选择方式。     

基于全过程动态仿真的发电机组涉网保护和限制自动校核

针对发电机涉网保护和限制的整定值保守、配合关系不合理,涉网保护和限制缺乏与实际电网之间的协调控制等问题,提出了一种基于全过程动态仿真的发电机组涉网保护和限制自动校核方法。该方法可自动识别运行方式变化,针对不同故障形式进行全过程动态仿真,校核涉网保护和限制的动作特性及其对电网稳定运行的影响,并评估相应运行风险。仿真结果表明,基于全过程的自动校核方法能够较为真实地反映实际电力系统发生故障后的动态过程,更好地发现由于保护和限制定值缺陷导致的问题,实现优化控制对象,为电网的安全运行分析和决策提供支撑。     

非平稳确定性信号与非平稳随机信号统一分类法的探讨

根据信号通过线性系统可产生新信号的理论,对非平稳确定性信号与非平稳随机信号的统一分类方法进行了深入研究,分别给出格林函数描述的线性时变系统法、调制函数作用于边界稳定线性系统的自激振荡正弦波法、随机输入线性时不变系统与边界稳定的与不稳定的线性系统组合法。这3种分类法便于对非平稳确定性信号与非平稳随机信号进行统一分类研究,并具有比较全面与系统性好的优点。     

航天高稳激光源温控电路设计

从航天实际应用角度出发,提出了基于MAX1968芯片的高稳激光源自动温控系统设计方法,介绍设计电路工作原理和组成的同时,给出了关键使用技术优化方案.结合某型号航天项目的具体测试,结果表明该温控电路在实际应用中能够达到双向无死区温控和0.01℃温度稳定性的要求.     

脂肪酸/无机纳米颗粒基定形相变材料的制备与热性能

以工业水玻璃为纳米SiO2前驱物,以癸酸(CA)和月桂酸(LA)二元低共熔酸为相变芯材,在表面活性剂的参与下,采用溶胶-凝胶法一步制备出纳米级复合定形相变蓄热材料.利用透射电子显微镜,扫描电子显微镜,傅里叶红外光谱仪,方差扫描量热法和热重分析等测试技术对此定形相变蓄热材料的结构和性能进行分析,并采用瞬态热线法测量了其导热系数.结果表明:相变芯材在吸热熔化后不会产生流动和渗漏;复合相变材料中脂肪酸含量(质量分数)为46％,具有良好的相变蓄热性能(相变温度19.57℃,相变潜热71.28 J/g)和热稳定性;复合相变材料导热系数为0.178 W/(m·K),可作为一种良好的隔热、保温建筑材料.     

含铜抗菌纤维

含铜抗菌纤维是一种功能性纤维,具有阻断疾病传播、消除异味、修复皮肤等效果,是新型的抗菌纺织品,目前流行于欧美等国。主要介绍了含铜抗菌纤维的分类、特点,着重陈述了以卡普龙含铜纤维为代表的接枝改性抗菌纤维的抗菌机制及优势。     

Oxygen-18 and Deuterium Fingerprinting of Tailings Seepage at the Sullivan Mine

Stable isotopes of water, ¹⁸O and ²H, were used to fingerprint and quantify the origin and percentage of mixing between tailings pond effluent, seepage collection waters, and background waters at the Sullivan Mill Site, which is located in Kimberley, British Columbia, Canada. The old iron and siliceous ponds are covered by a layer of permeable float rock, which allows meteoric waters to directly infiltrate without undergoing evaporation. In contrast, the east gypsum pond is covered with a layer of till and vegetation, which causes meteoric waters to pond and subsequently be subjected to evaporative processes. The different evaporative environments result in distinctly different isotopic compositions for the waters collected from these sources. The difference in surface cover was used advantageously to identify particular isotopic ratios for the different tailings sources. Water collected from the east gypsum pond is relatively enriched in the heavier isotopes (δ¹⁸O and δ²H), whereas water collected from various locations in the siliceous and old iron pond are relatively depleted in δ¹⁸O and δ²H. The various seepage collection waters were observed to plot at intermediate positions, corresponding either to the old iron pond mixing line, the gypsum pond evaporation line, or somewhere between the two.