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101.
102.
Marianna Barbalinardo Marta Giannelli Ludovica Forcini Barbara Luppi Anna Donnadio Maria Luisa Navacchia Giampiero Ruani Giovanna Sotgiu Annalisa Aluigi Roberto Zamboni Tamara Posati 《International journal of molecular sciences》2022,23(12)
Skin disorders are widespread around the world, affecting people of all ages, and oxidative stress represents one of the main causes of alteration in the normal physiological parameters of skin cells. In this work, we combined a natural protein, fibroin, with antioxidant compounds extracted in water from pomegranate waste. We demonstrate the effective and facile fabrication of bioactive and eco-sustainable films of potential interest for skin repair. The blended films are visually transparent (around 90%); flexible; stable in physiological conditions and in the presence of trypsin for 12 days; able to release the bioactive compounds in a controlled manner; based on Fickian diffusion; and biocompatible towards the main skin cells, keratinocytes and fibroblasts. Furthermore, reactive oxygen species (ROS) production tests demonstrated the high capacity of our films to reduce the oxidative stress induced in cells, which is responsible for various skin diseases. 相似文献
103.
本文介绍了电阻蒸发ZnS∶Mn薄膜在硫饱和蒸汽压下进行热处理的工艺。通过AES和XRD分析及带隙宽度的测试,结果表明:此法所制备的薄膜有较好的化学计量比,且具有电致发光薄膜所需要的六方结构。 相似文献
104.
I. G. Voigt-Martin E. Zhou P. Simon R. W. Garbella D. Yan W. Paulus H. Ringsdorf 《Advanced functional materials》1993,2(5):245-268
The experiments described in this paper were undertaken in order to obtain information about the relationship between the structure and non-linear optical properties (second-harmonic generation) of organic thin films. For this purpose, two closely related dyes, diones and tetrones, were compared, both of which are shown to have large hyperpolarisabilities. Their microscopic properties are investigated by conformational analysis and electron diffraction. It could be shown that detailed knowledge about the structure and the adjacent neighbour packing can be obtained from conformational analysis and electron diffraction in order to understand the non-linear optical properties of the two dyes. 相似文献
105.
本文建立了真空电弧镀膜中液滴热过程的理论模型,求解了沉积TiN膜过程中液滴的温度与粒径变化。计算表明,液滴在飞行过程中温度和粒径不断减小;粒径较小的液滴温度降低较大,甚至可能发生凝固。计算实例能较好解释早期TiN膜的电镜分析结果,揭示液滴在薄膜中引起两种不同微孔的机理。 相似文献
106.
107.
以氯甲基化杂萘联苯聚醚酮(CMPPEK)为膜材料,通过溶液法制备了CMPPEK基膜,然后将其浸泡在三甲胺水溶液中进行季铵化反应得到季铵化杂萘联苯聚醚酮(QAPPEK)阴离子交换膜。比较了CMPPEK和QAPPEK的热失重性能,CMPPEK的5%热失重温度为330℃,QAPPEK的5%热失重温度为260℃,QAPPEK的5%热失重温度与CMPPEK的相比降低了70℃。考察了三甲胺浓度、胺化时间、胺化温度等反应条件对QAPPEK膜性能的影响。结果表明:三甲胺的质量分数为33%、胺化时间为12h、胺化温度为40℃时,得到的QAPPEK膜表现出了较优异的性能,其IEC值达1.64mmol/g,在2mol/LVOSO4+3mol/LH2SO4的混合溶液中测得的面电阻为0.73Ω·cm2,应用于全钒液流电池(VRB)中,电池的能量效率高达85.9%,电流效率为98.4%,电压效率为87.3%。 相似文献
108.
D.S. DhawaleC.D. Lokhande 《Journal of Alloys and Compounds》2011,509(41):10092-10097
In the present work, we report base free chemical bath deposition (CBD) of mesoporous zinc oxide (ZnO) thin films from urea containing bath for liquefied petroleum gas (LPG) sensor application. Mesoporous morphology with average pore size ∼2 μm and wurtzite crystal structure are confirmed from scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. The surface of ZnO is hydrophobic with water contact angle 128 ± 1°. Optical study reveals the presence of direct bad gap with energy 3.24 eV. The gas sensing study reveals the mesoporous ZnO is highly selective towards LPG as compared with CO2 and maximum LPG response of 52% is achieved upon the exposure of 3900 ppm LPG at 573 K as well as good reproducibility and short response/recovery times. 相似文献
109.
Lutz Prager Luise WennrichWolfgang Knolle Sergej NaumovAndrea Prager 《Materials Chemistry and Physics》2012
A simple but reliable method was developed for the determination of wavelength-dependent absorption coefficients in the vacuum-UV (VUV) spectral range 160 nm < λ < 195 nm. 相似文献
110.
Z.M. Wang 《Corrosion Science》2010,52(4):1342-1350
A model metallic glass Ni50Nb50, which would undergo a polymorphous transformation during devitrification, was selected to clarify the correlation of amorphous structure with corrosion. The electrochemical polarization behaviour, film breakdown and composition of surface film have been studied in detail by comparing the amorphous alloy with its crystalline counterparts. Interestingly, it was found that the pit initiation is inhibited greatly on amorphous sample relative to the crystallized one. The origin is thought to be related to the defective interface beneath passive film that inhibits the formation of pitting precursors in corrosion. 相似文献