全文获取类型
收费全文 | 18951篇 |
免费 | 1916篇 |
国内免费 | 1456篇 |
专业分类
电工技术 | 1144篇 |
综合类 | 1892篇 |
化学工业 | 1521篇 |
金属工艺 | 1611篇 |
机械仪表 | 226篇 |
建筑科学 | 2204篇 |
矿业工程 | 1034篇 |
能源动力 | 873篇 |
轻工业 | 228篇 |
水利工程 | 6790篇 |
石油天然气 | 307篇 |
武器工业 | 61篇 |
无线电 | 478篇 |
一般工业技术 | 1169篇 |
冶金工业 | 2395篇 |
原子能技术 | 83篇 |
自动化技术 | 307篇 |
出版年
2024年 | 69篇 |
2023年 | 253篇 |
2022年 | 435篇 |
2021年 | 478篇 |
2020年 | 559篇 |
2019年 | 498篇 |
2018年 | 438篇 |
2017年 | 516篇 |
2016年 | 610篇 |
2015年 | 636篇 |
2014年 | 950篇 |
2013年 | 834篇 |
2012年 | 1209篇 |
2011年 | 1348篇 |
2010年 | 1004篇 |
2009年 | 1097篇 |
2008年 | 1044篇 |
2007年 | 1194篇 |
2006年 | 1218篇 |
2005年 | 1153篇 |
2004年 | 997篇 |
2003年 | 1016篇 |
2002年 | 784篇 |
2001年 | 707篇 |
2000年 | 637篇 |
1999年 | 514篇 |
1998年 | 413篇 |
1997年 | 327篇 |
1996年 | 317篇 |
1995年 | 274篇 |
1994年 | 223篇 |
1993年 | 152篇 |
1992年 | 124篇 |
1991年 | 90篇 |
1990年 | 51篇 |
1989年 | 47篇 |
1988年 | 27篇 |
1987年 | 32篇 |
1986年 | 17篇 |
1985年 | 6篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1975年 | 1篇 |
1959年 | 1篇 |
1957年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
31.
《中国稀土学报(英文版)》2022,40(10):1509-1518
Gd2O3:Eu3+@CsPbBr3 quantum dots (QDs) mesoporous hollow nanocomposites with good luminescent properties and high stability were built. Among which, the hollow Gd2O3:Eu3+ spheres and CsPbBr3 QDs were prepared by urea homogeneous precipitation and hot-injection method, respectively. Finally, the Gd2O3:Eu3+@CsPbBr3 QDs shell–core compounds were constructed through mechanical stirring. The structure, morphology, stability and luminescent properties were studied by Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry/thermogravity (DSC/TG), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), photoluminescence excitation/photoluminescence (PLE/PL) and life decay tools. Compared to the original CsPbBr3 QDs, Gd2O3:Eu3+@CsPbBr3 QDs display better photostability, thermal stability and current stability. The resulting Gd2O3:Eu3+@CsPbBr3 QDs composite exhibits good yellow emission. The Gd2O3:Eu3+@CsPbBr3 QDs mixed silicone resin was directly coated on the blue LED chip, then the w-LED device with the color coordinate of (0.31, 0.32) was successfully assembled. The Gd2O3:Eu3+@CsPbBr3 QDs compounds with excellent luminescent properties and stability are expected to be widely used in lighting and display areas. 相似文献
32.
为探究稀土Ce对440C不锈轴承钢中夹杂物的改性作用,利用实验室MoSi2电阻炉对440C不锈轴承钢进行稀土Ce处理,采用OM、SEM等系统分析了Ce的添加对440C不锈轴承钢脱氧及夹杂物演变的影响。结果表明,随着Ce加入量的增加,其收得率逐渐升高。Ce的加入使钢中TO质量分数由0.002 5%降低至0.001 2%。未加入Ce的钢中夹杂物主要为Al2O3、MnS以及镁铝尖晶石;加入质量分数为0.011 5%的Ce后,夹杂物被改性为以Ce-Al-O为主的夹杂物;当Ce的添加量达到0.036 4%时,夹杂物被完全改性为Ce-O-S夹杂物。适量的Ce可以降低夹杂物尺寸及面积比例,但过量加入会使夹杂物尺寸变大。在本试验条件下,当Ce质量分数为0.011 5%时,钢中夹杂物细小弥散效果最明显。以上结论可为Ce在高碳铬不锈轴承钢中的应用提供参考。 相似文献
33.
Xinhua Wang Changyao Wang Changpin Chen Qidong Wang 《Journal of Alloys and Compounds》2006,420(1-2):107-110
In this paper, we deduced an empirical equation for predicting the stabilities of the hydrides of AB5-type compounds with the consideration of the effects of geometrical factor and electric factor. The theoretical curves derived from this equation are in good agreement with the test results of La1−xCaxNi5, Ml1−xCaxNi5 and La1−xCexNi5 compounds. With this model, we can easily interpret the phenomenon that the initial partial substitution of R by Ca in R1−xCaxNi5 (R is rare earth metal) compounds cause an increase of hydrogen desorption pressure to a maximum value, whereas in the range of larger Ca content x the hydrogen desorption pressure decreases with increasing x. 相似文献
34.
萃取预分离法分离富铕中钇矿新工艺 总被引:2,自引:0,他引:2
采用一种新的串级萃取方式--萃取预分离法分离富铕中钇矿的新工艺.原料首先流入十几的三出口预先粗分离工艺,其萃余液La~Gd(TbDy)直接流入Nd/Sm工艺;中间出口流入(Gd)Tb~HoY(Er)Gd~Dy/Ho~LuY细分离工艺;出口负载有机相(Ho)Er~LuY流入Gd~Dy/Ho~LuY的洗涤段.结果表明,新工艺的粗分离工艺将占原料约70%的La~Gd(TbDy)预分离掉,使流入Gd~Dy/Ho~LuY工艺的稀土量减少约70%;由于Gd~Dy/Ho~LuY分组的萃余液GdTbDy含Ho2O3小于0.03%,省去原工艺的GdTbDy/HoY分离;新工艺的处理能力提高30%,酸碱消耗减少20%以上,贵重稀土元素Eu和Tb的存槽量大大减少. 相似文献
35.
稀土稳定氧化锆超细粉末的合成机理研究 总被引:5,自引:0,他引:5
依据Al(Ⅲ )、Zr(Ⅳ )的水解聚合机理 ,把锆、铝和钇的无机盐溶液按一定组成混合在一起 ,通过加入乙二醇作为络合剂和调节溶液的PH值来获得溶胶 ,并直接蒸馏溶胶来获得干凝胶 ,最后制得ZrO2 (Y2 O3 ) -Al2 O3 系粉末。研究结果表明 :该工艺不仅制粉时间快、成本低、产量大 ,而且粒子均匀 ,粒径在 2 0~ 5 0nm之间 ,具有一定的可行性 相似文献
36.
We report a novel method of polyimide (PI) synthesis from prepolymers based on dianhydrides and diacetyl derivatives of aromatic diamines that facilitate the preparation of a melt processable mixture at 300 ± 10°C of the prepolymer and magnetic Nd‐Fe‐B alloy to provide PI‐bonded magnets with enhanced properties. It is shown that chemical structure of the prepolymers strongly influences viscosity behavior via crystallization of the oligoimide in the melt, leading to formation of PI with rigid‐rod like structure. This structural ordering of the prepolymers based on diacetyl derivative of diamine used in this study, if not controlled, leads to exponential increase of melt viscosity with time, making it practically impossible to prepare melt processable mixture of the magnetic particles and the PI prepolymers at elevated temperatures. The results obtained demonstrate that appropriate dianhydrides and diacetyl derivatives of diamines that do not lead to crystallization of oligoimides in prepolymer mixture can be used under controlled processing conditions to prepare melt‐processable PI‐bonded magnets containing rigid‐rod like PI structure that significantly increases thermal stability of the magnets. The temperature dependencies of the magnetic properties of the PI‐bonded magnets under conditions that they are likely to encounter during their service life were found to be remarkably similar to that of commercial thermoplastic magnets such as injection‐molded nylon magnets. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 478–485, 2006 相似文献
37.
38.
Lithium manganese oxides LiMn2O4 and rare earth elements doped LiNd0.01Mn1.99O4 were synthesized by microwave method. The structure and the electrochemical performances of the samples were characterized. XRD data shows both samples exhibit the same pure spinel phase. But due to the introduction of Nd3+ ion into the unit cell, the lattice parameter of the Nd-doped spinel was larger than that of the undoped one. The two samples had a similar morphology including small particle size and homogeneous particle distribution as tested by SEM. The cyclic voltammmetry and constant-current charge-discharge tested that Nd-doped spinel displayed a better reversibility and cycleability. 相似文献
39.
40.
LEI Peng CHANG XiaoLin XIAO Feng ZHANG GuiJin & SU HuaiZhi School of Hydraulic Engineering Changsha University of Science Technology Changsha China College of Water Resources Hydroelectric Engineering Wuhan University.Wuhan Mid-south Design Research Institute China Hydropower Engineering Consulting Group Co Changsha College of Water Conservancy Hydropower Engineering Hohai University Nanjing 《中国科学:信息科学(英文版)》2011,(6)
Owing to the deficiency in early warning for high concrete dam,a formula was established to characterize the deformation behavior of high concrete dam as a whole.The early warning index of spatial deformation was calculated by low probability principle on the basis of the deformation entropy formula proposed.The steps were as follows.Firstly,the probability method was utilized to define the degree of order and degree of chaos for each survey point.Secondly,the weight distribution among the survey points was... 相似文献