Characteristics of reaction and product microstructure during light calcination of magnesite in transport bed

A gas-heating laboratory transport bed was adopted to simulate the industrial transportbed reactor for flash calcination of magnesite, and a method based on TG analysis of a reacted sample was further developed to calculate the decomposition rate or conversion of its containing MgCO₃. The study investigated how the conversion and product reactivity as well as microstructure vary with reaction conditions including temperature, particle size and times of re-calcination for powder magnesite. Magnesite powder (<150 μm) calcination is a quick reaction that reaches 98% decomposition of its containing MgCO₃ in 1—2 s,corroborating the feasibility of magnesite flash-calcination in transport bed reactors. The coloration time given by the citric acid chromogenic method was 17—55 s and 294 s for the obtained products from transport and fixed beds, respectively. This proves the obviously higher activity and thus improved microstructure of the product from transport bed. During the calcination process, the MgO grain size of the product gradually increases, and the surface structure changes from loose and porous to dense and smooth. This structural change can be completed within a few seconds.     

传统古法与现代机制宣纸耐久性对比研究

利用QUV/SPRAY型紫外光照老化仪对传统古法和现代机制宣纸进行耐久性试验,并测试和对比老化前后两类宣纸的机械强度及颜色变化。研究结果表明:随着光照老化时间的延长,两类宣纸的机械强度下降明显,但古法宣纸的机械强度始终大于机制宣纸;从颜色变化来看,当光照老化时间小于160h时,两类宣纸的颜色变化不大,而随着光照老化时间的延长,机制宣纸的颜色比古法宣纸更稳定。     

Comparison of the crystalline properties and structural changes of starches from high-amylose transgenic rice and its wild type during heating

A transgenic rice line (TRS) enriched amylose and resistant starch has been developed by antisense RNA inhibition of starch branching enzymes. In this study, gelatinisation and crystalline properties, swelling power, water solubility, morphological and structural changes of starches from TRS and its wild-type Teqing (TQ) were carefully investigated during heating. Compared to TQ, TRS starch showed higher gelatinisation temperatures, lower gelatinisation enthalpy and swelling power. Morphological and structural changes showed that TQ starch drastically swelled after 70 °C, then gradually disrupted with increasing heating temperature. The surrounding band of TRS starch restrained granule swelling, though the subgranules disrupted to form the cavity. The results of spectroscopic analyses indicated that A-type crystalline of TQ changed to amorphous starch after 75 °C, while C-type crystalline of TRS gradually changed to B-type crystalline after 75 °C, then became amorphous starch at 95 °C. These results add to our understanding of the effect of heating on the high-amylose rice starch.     

HPLC-ELSD法测定苦杏仁中苦杏仁苷的含量

建立了苦杏仁中苦杏仁苷的高效液相色谱-蒸发光散射检测器检测方法。采用ZORBAX Eclipse XDB-C18色谱柱(4.6mm×150mm,5μm),流动相为V(甲醇)∶V(水)=40∶60,流速1.0mL/min,柱温40℃;蒸发光散射检测器漂移管温度60℃,载气(空气)压力0.2MPa。在上述条件下测得苦杏仁苷在0.28～5.5μg范围内的线性关系良好(r=0.9975),检出底限达58ng/L,平均加标回收率为96.2%。该方法简便快捷,重现性和准确度良好,可用于实际工作中样品的测定。     

钛宝石激光器中飞秒和皮秒脉冲被动同步的研究

在双波长钛宝石激光器中通过交叉相位调制实现了飞秒和皮秒脉冲的交叉锁模,得到了被动同步的飞秒和皮秒脉冲.自相关和交叉相关曲线表明飞秒和皮秒脉冲具有很高的同步性,脉冲之间的抖动为51 fs.在飞秒和皮秒激光腔分别独立自锁模的情况下,群速弥散和自相位调制决定了自锁模激光脉冲的频谱和时间宽度.在飞秒和皮秒激光腔交叉锁模的情况下,交叉相位调制和增益竞争是决定脉冲频谱和时间宽度变化的主要因素.此外,讨论了被动同步的机制、激光的调谐范围以及锁模的稳定性.     

甲基蓝体系共振瑞利散射法测定蛋白质

在pH2.36的BR介质中,甲基蓝与蛋白质相互作用生成复合物,使最大波长350nm的共振光散射光谱得到增强,增强程度与蛋白质浓度成正比。据此建立了测定蛋白质的新方法。人血清白蛋白、牛血清白蛋白的线性范围分别为0～2.4mg/L、0～2.8mg/L,相应检出限分别为39.3、43.4μg/L。方法的稳定性好,灵敏度高,用于牛奶、豆浆、人血清、尿液中总蛋白质的测定,结果与考马斯亮蓝法一致。     

饰面类人造板耐光色牢度的测定方法

阐述了氙孤灯耐光色牢度试验仪的结构与工作原理,以及目前国际通用ISO校准规程;深入剖析了影响耐光色牢度测试的关键因素,包括辐射能、热量、湿度和时间。     

消旋氧氟沙星抗体制备及其手性识别特性研究

采用活泼酯法（A）和直接EDC（1-乙基-3-（3-二甲氨丙基）碳二亚胺盐酸盐）法（D）,合成两种包被抗原（OFL-A-OVA和OFL-D-OVA）和两种免疫抗原（OFL-A-BSA和OFL-D-BSA）,然后分别用两种免疫抗原免疫小鼠获得与其对应的多克隆抗体,建立消旋氧氟沙星残留免疫检测方法。研究结果表明：紫外扫描图谱证明四种抗原均合成成功,OFL-A-BSA、OFL-D-BSA、OFL-A-OVA和OFL-D-OVA的偶联比分别为19.67、3.03、1.93和0.99。消旋氧氟沙星的间接竞争ELISA法的线性检测范围为16.35～444.10ng/mL,IC50为5.42ng/mL,最低检测限为6.23ng/mL。消旋氧氟沙星抗体与恩诺沙星、环丙沙星、加替沙星等其他同类药物的交叉反应率较低,表明消旋氧氟沙星抗体具有较高的特异性,且消旋氧氟沙星抗体对左旋氧氟沙星和右旋氧氟沙星的识别并非对等,对左旋的识别能力较大,左旋氧氟沙星对抗体的产生起主要作用。     

Photoluminescence properties of Tm~(3+)/Tb~(3+)/Sm~(3+)tri-doped Na_5Y_9F_(32)single crystal with high thermal stability for white light-emitting diodes

A novel Tm~(3+)/Tb~(3+)/Sm~(3+)tri-doped Na_5 Y_9 F_(32) single crystal was synthesized by a modified Bridgman method for the propose of white light emitting diodes.The fluorescence spectra of various Sm~(3+)ion concentrations and fixed 0.4 mol% Tm~(3+) and 0.5 mol% Tb~(3+) were measured and studied systematically excited by near-ultraviolet light of 355 nm.The Sm3+ion concentration takes apparent effect on the relative intensity of peaks in the visible region and the color coordinate combining from these emission bands.A near pure white light emission with color coordinates(0.3295,0.3057) and color temperature(5657 K) can be obtained when the concentrations of Tm~(3+),Tb~(3+) and Sm~(3+) ions are 0.4 mol%,0.5 mol%and 0.8 mol%,respectively.Furthermore,the practical down-conversion internal quantum yield was measured by integrating spheres at about 14.39%.The tri-doped Na_5 Y_9 F_(32) single crystal shows a high thermal stability inferring from the temperature dependent emission in which the integrated emission intensities are reduced only by～3% with the increase of temperature from 280 to 450 K.The present results demonstrate that the Tm~(3+)/Tb~(3+)/Sm~(3+)tri-doped Na_5 Y_9 F_(32) single crystal may provide a promising candidate for white light-emitting diodes,luminescent materials and fluorescent display devices.     

基于CMOS图像传感器的微光成像系统信噪比研究

信噪比是微光成像系统的关键参数,决定了成像系统的性能与成像质量。给出了互补金属氧化物半导体（Complementary Metal Oxide Semiconductor, CMOS）图像传感器微光成像系统的信噪比模型,仿真计算了系统的信噪比与信号、噪声的关系。搭建了信噪比测试环境,完成了系统信噪比测试实验。实验结果表明,理论值与实测值一致。最后,根据信噪比分析结果对给定系统进行了参数优化。计算结果显示,优化后的系统在1 mLux照度下,信噪比能达到4.5。信噪比的研究为基于CMOS微光成像系统的总体设计与优化提供了理论依据。