Beam quality characterization of a radial laser array

Abstract

With the Hermite-Gaussian mode used to describe radial laser arrays and the M²-factor and power in the bucket (PIB) chosen as criteria for characterizing beam quality, a detailed study of beam quality of coherent and incoherent radial laser arrays is made. The closed-form expression for the M²-factor of incoherent radial arrays, which depends upon the Hermite-Gaussian order m, inverse radial fill factor r' and aspect ratio w _0x /w _0y , is derived. Numerical examples are given to illustrate and compare beam quality of coherent and incoherent radial arrays.     

Influence of Hydride Re-orientation on BWR Cladding Rupture under Accidental Conditions

Hydride precipitation along the radial-axial plane increases in high burn-up boiling water reactor (BWR) fuel claddings. The radially-oriented hydrides may have an important role during fuel behavior in a reactivity-initiated accident and may reduce ductility of the cladding under pellet-cladding mechanical interaction (PCMI) conditions. In order to promote a better understanding of the influence of the radial hydrides on cladding failure behavior under the PCMI conditions, tube burst tests were conducted for unirradiated BWR claddings charged with 200 to 650 ppm of hydrogen. About 20 to 30% of hydrides were re-oriented and precipitated along the radial-axial plane. The claddings exhibited large rupture openings with an axial crack at room temperature and 373 K. The crack penetrated through cladding wall preferentially along the radial hydrides, and radial cross section showed cladding failure in a brittle manner. However, reduction in residual hoop strain by precipitation of the radial hydrides was very small. It is accordingly expected that ductility of high burn-up BWR cladding is significantly reduced not only by precipitation of radial hydrides as far as hydrogen concentration and radial hydride fraction range in the present study.     

Highly efficient photocatalytic activity and mechanism of novel Er3+ and Tb3+ co-doped BiOBr/ g-C3N5 towards sulfamethoxazole degradation

Bismuth oxyhalides (BiOX (X = Cl, Br, I) are considered to be an important p-type semiconductors in the photocatalysis applications. In particular, tetragonal BiOBr is considered as a stable photocatalyst due to its resilient absorption in the visible region with an band gap energy of 2.8 eV. In the meantime, lanthanide ions (with 3+ oxidation state) implies as conversion catalyst gained huge impact and remain a serious topic in materials chemistry. Here we synthesized upconversion photocatalyst mainly consists of BiOBr with the Er ³⁺ and Tb ³⁺ ions along with low band gap g-C₃N₅ for the improved photocatalytic performances. The synthesized Er³⁺/Tb³⁺@BiOBr-g-C₃N₅ heterojunction was systematically characterized by XRD, and FT-IR for the confirmation of the composite and their morphology were analysed with FESEM and HR-TEM analysis which revealed that the sheets of g-C₃N₅ were decorated by Er³⁺/Tb³⁺ loaded BiOBr microspheres. The XPS analysis confirmed the suitable oxidation state of all the individual elements existing in the composite. As the UV-DRS analysis showed that the band gap of the Er³⁺/Tb³⁺ BiOBr-gC₃N₅ heterojunction was narrowed to 2.64 eV. To evaluate the photocatalytic efficiency of the synthesized g-C₃N₅, Er³⁺/Tb³⁺@BiOBr and Er³⁺/Tb³⁺@BiOBr-gC₃N₅ heterojunction under the simulated visible light irradiation source towards the aqueous sulfamethoxazole degradation. The Er³⁺/Tb³⁺@BiOBr-gC₃N₅ heterojunction shows maximum degradation efficiency of 94.2% after 60 min of visible light irradiation whereas the pure g-C₃N₅ provided about 43.8% and Er³⁺/Tb³⁺@BiOBr implies 55.2% degradation efficiency. The plausible degradation mechanism of pollutant removal was proposed.     

Dry Fractionation of Cupuassu (Theobroma grandiflorum) Fat: Physical–Chemical Properties and Polymorphic Behavior

Physical chemical properties of cupuassu fat were modified by dry fractionation. Stearin and olein fractions were obtained at 29, 26, and 24 °C. Polymorphic behavior of unfractionated cupuassu fat (UCF) and its fractions were studied in situ by small-angle (SAXS) and wide-angle (WAXS) X-ray scattering using synchrotron light. Polymorphic transitions were followed in real time tempering samples with a thermal cycle. For UCF, the main polymorphic form crystallized under selected conditions was the β’₂. α and β’₁-forms appeared in trace amounts. β₂-form was obtained after storage at 25 °C for 3 months. Stearins obtained at 26 (S-26) and 24 °C (S-24) showed a similar polymorphic behavior. However, S-26 with improved physical properties might be more suitable for chocolate production or as a trans-fat alternative than UCF. Stearin fraction obtained at 29 °C (S-29) had a complex polymorphic behavior. The α-form was the first polymorphic form detected followed by β’₂-form. There was a polymorphic transition from α to β’₁-form but no transition between β’-forms. They were independent to each other showing fractionation in two different solid solutions. Increased contents of the triacylglycerols (TAG) SOA and SOB together with lower contents of SOO compared to UCF led to co-crystallization because there was no complete compatibility among all TAG present in S-29. β₁-form crystallized after storage forming crystals with a double-layer arrangement and a characteristic morphology. This form could be useful for accelerating crystallization process in melted liquid systems.     

Influence of the rigidity of the steroid core in the structure of chiral dopants on the temperature dependence of cholesteric short pitch

New chiral compounds of the steroid type, namely, 3-alkanoyl- and 3-alkyl derivatives of 16-arylidene estrone, were synthesized and exhibited high helical twisting power (HTP) in nematic liquid crystals E63 and LC-1289. The peculiarities of the molecular structure of chiral compounds (CCs) and their high degree of chirality were discussed. Quite small concentrations of chiral compounds in both nematic solvents were needed to obtain a short-pitch cholesteric helical macrostructure with the selective light reflection in the visible range of the spectrum. The insignificant temperature dependence of the maximum wavelength of the selective light reflection obtained on the whole cholesteric range for all studied liquid crystalline (LC) systems could be related to relatively rigid molecular structure of the chiral compounds. The cholesteric LC mixtures comprising 3-alkanoyl- and 3-alkyl derivatives of 16-arylidene estrone were characterized by the phase stability and the stability of reflective characteristics in time that makes it possible to consider this series of dopants as appropriate for development of bistable cholesteric reflective LC displays.     

Testing the performance of CIECAM02 from 100 to 3500 cd/m2

Color appearance models were developed to characterize the color attributes of stimuli under different viewing conditions based on data collected through magnitude estimation or color matching experiments. Although human beings experience very high light levels under daylight and the reproduction of colors under daylight is important in the color and imaging industries, the existing color appearance models were developed based on the data that were collected under the conditions with luminance levels below 700 cd/m² due to the lack of facilities to produce stable illumination at high light levels. A recent study investigating color preference of an artwork under a wide range of light levels from 20 to 15 000 lx suggested that CIECAM02 cannot accurately characterize the color appearance under extremely high light levels. This study was designed to directly test the performance of CIECAM02 from 100 to 3500 cd/m². Human observers performed color match for four hues under a series pairs of adapting conditions with a haploscopic viewing condition. It was found that CIECAM02 had the best performance in characterizing the hue angles but the worse performance in characterizing the brightness with a maximum underprediction around 200% across a wide range of luminance. This was mainly due to the fact that CIECAM02 was developed based on the data collected under relatively low adapting luminance levels. The color appearance model that was proposed to use the adapting luminance levels in characterizing the cone compression in the postadaptation process was found to have a much better performance in characterizing the brightness.     

Electrochemical growth of tin(II) oxide films: Application in photocatalytic degradation of methylene blue

We have investigated the semiconducting and photoelectrochemical properties of SnO films grown potentiostatically on tin substrate. The oxide is characterized by X-ray diffraction, scanning electron microscopy and Raman spectroscopy. The anodic process corresponds to the formation of SnO·nH₂O pre-passive layer that is removed upon increasing potential due to surface etching at the metal/oxide interface. SnO films deposited for long durations (>50 mn) are uniform and well adhered; they thicken up to ~50 nm by diffusion-controlled process and the growth follows a direct logarithmic law. The thickness is determined by coulometry and the X-ray diffraction indicates the tetragonal SnO phase (SG: P4/mmm) with a crystallite size of 32 nm. The Mott–Schottky plot is characteristic of n type conductivity with an electrons density of 5.72×10¹⁸ cm⁻³, a flat band potential of −0.09 V_SCE and a depletion width of ~10 nm. The valence band, located at 5.91 eV below, vacuum is made up of hybridized O²⁻:2p Sn²⁺:5s while the conduction band (4.45 eV) derives from Sn²⁺:5p orbital. The electrochemical impedance spectroscopy (EIS) measured in the range (10⁻²–10⁵ Hz) shows the contribution of the bulk and grain boundaries. The energy band diagram predicts the photodegradation of methylene blue on SnO films. 67% of the initial concentration (10 mg L⁻¹) disappears after 3 h of exposure to visible light (9 mW cm⁻²) with a quantum yield of 0.072.     

An Artificial Nocturnal Flower via Humidity‐Gated Photoactuation in Liquid Crystal Networks

Beyond their colorful appearances and versatile geometries, flowers can self‐shape‐morph by adapting to environmental changes. Such responses are often regulated by a delicate interplay between different stimuli such as temperature, light, and humidity, giving rise to the beauty and complexity of the plant kingdom. Nature inspires scientists to realize artificial systems that mimic their natural counterparts in function, flexibility, and adaptation. Yet, many of the artificial systems demonstrated to date fail to mimic the adaptive functions, due to the lack of multi‐responsivity and sophisticated control over deformation directionality. Herein, a new class of liquid‐crystal‐network (LCN) photoactuators whose response is controlled by delicate interplay between light and humidity is presented. Using a novel deformation mechanism in LCNs, humidity‐gated photoactuation, an artificial nocturnal flower is devised that is closed under daylight conditions when the humidity level is low and/or the light level is high, while it opens in the dark when the humidity level is high. The humidity‐gated photoactuators can be fueled with lower light intensities than conventional photothermal LCN actuators. This, combined with facile control over the speed, geometry, and directionality of movements, renders the “nocturnal actuator” promising for smart and adaptive bioinspired microrobotics.     

IC基板传输机器人末端执行器结构拓扑优化设计

在半导体封装基板检测的传输过程中,末端执行器对其快速稳定高效率的传输起着关键作用。在满足设计强度、刚度的条件下,以末端执行器轻量化为目标,建立了末端执行器的三维模型,利用有限元分析软件ANSYS对基板传输机器人末端执行器进行静力学和模态分析,得到末端执行器在最大载荷情况下的应力、应变特性和对应的振型,并对其进行拓扑优化设计,根据拓扑优化结果建立新的末端执行器结构,对新的结构进行强度校核,验证设计方案的有效性。研究结果表明,优化后末端执行器的前四阶固有频率都大于伺服电动机的回转频率(50Hz),质量减少了26.7%,较好地实现了轻量化的目标,同时为后续的相关产品研制提供了一种新的技术方案。     

基于变步长差分迭代方法的河道水面线计算

在计算天然河道水面线时，由于河道的不规则性，导致计算断面间距往往是不相等的。为此，依据水力学能量方程，建立了变步长差分迭代的水面曲线模型。该数学模型简单易行，适应性强，便于程序化实现。通过对河南省南部某河道治理工程水面线的推求验证，证明该方法可有效解决非等间距断面的水面线推求问题，且计算效率和精度较高，可为计算类似工程问题提供参考。