Hydrocarbon synthesis over sulfide catalysts. Break-down of the Anderson-Schulz-Flory distribution

The kinetics of hydrocarbon synthesis over sulfide-based catalysts was studied. It appears that the formation of methane follows another reaction path than that of higher hydrocarbons. This might explain the very high selectivities for ethane and propane as compared with conventional Fischer-Tropsch catalysts. Reference is made to testing of the catalysts at industrial conditions.     

双峰分子量分布聚乙烯的研究进展

双峰聚乙烯是目前用途很广、市场前景很好的一种通用树脂。国内外双峰分子量分布聚乙烯研究取得了很大进展，重点领域为双峰分子量分布聚乙烯制备工艺和催化剂的研究。双峰聚乙烯具有优异的性能，为进一步开拓市场，我国应着力开展这方面的研究开发生产工作。     

Effect of molecular weight and branch content on the creep behavior of oriented polyethylene

Creep studies were carried out on a range of homopolymers and copolymers of polyethylene with well‐defined molecular weight and branch content. The creep data were analyzed in terms of two thermally activated processes acting in parallel and the effects of molecular weight and branch content are discussed. It is shown that increasing either the number‐average molecular weight or the weight‐average molecular weight gives improved creep behavior at all stress levels. The introduction of butyl branches leads to lower creep at low‐stress levels but can give rise to higher creep at high stress. Plots of the equilibrium log₁₀(strain rate) versus stress at fixed draw ratio (strain) can be used to define sections through a unique true stress/true strain/strain rate surface for each material. These creep results have an additional value in terms of the link between slow crack propagation (SCG) in polyethylene and fibril creep, confirming the proposal made elsewhere that SCG can be quantified in terms of creep to failure across the true stress/true strain/strain rate surface. © 2003 Wiley Periodicals, J Appl Polym Sci 89: 1663–1670, 2003     

Smallholders’ Soil Fertility Management in the Central Highlands of Ethiopia: Implications for Nutrient Stocks, Balances and Sustainability of Agroecosystems

Low agricultural productivity caused by soil degradation is a serious problem in the Ethiopian Highlands. Here, we report how differences in soil fertility management between farming systems, based either on enset (Ensete ventricosum) or on teff (Eragrostis tef) as the major crops, affect the extent of nutrient stocks, balances and ecosystem sustainability. We collected information on farmers’ resources and nutrient management practices from stratified randomly selected households in two watersheds in the Central Highlands of Ethiopia. In addition, we collected soil samples from each land use and calculated nutrient stocks, partial and full nutrient balances (N, P and K) for one cropping season. Our results show that farmers in the two farming systems manage their soils differently and that nutrient inputs were positively related to farmers’ wealth status. The watershed with the enset-based system had higher soil N and K stocks than the watershed with the teff-based system, while P stocks were not different. Management related N?and K fluxes were more negative in the teff-based system (?28 kg N ha^?1 yr^?1 and ?34 kg K ha^?1 yr^?1) than in the enset-based system (?6 kg N ha^?1 yr^?1 and ?14 kg K ha^?1 yr^?1) while P fluxes were almost neutral or slightly positive. Within the enset-based system, a strong redistribution of N, P and K took place from the meadows and cereals (negative balance) to enset (positive balances). Although in the teff-based system, N, P and K were redistributed from meadows, small cereals and pulses to maize, the latter still showed a negative nutrient balance. In contrast to nutrient balances at land use level, nutrient balances at the watershed scale masked contrasting areas within the system where nutrient oversupply and deficiencies occurred.     

Detailed Molecular Structure Modeling – A Path Forward to Designing Application Properties of ldPE

Summary: This paper describes a step on the ambitious aim to “design” application properties of ldPE by first simulating the detailed molecular structure of a high‐pressure tubular reactor product. The reactor of a certain configuration produces under well‐defined operating conditions. The next step is to correlate the structure with the application properties. Finally, the sequence will be reversed in order to deduce the operating conditions, which lead to the desired product quality. Two‐dimensional distributions, in molecular weight and branching frequency, as well a two compartment models with a core and a shell stream were simulated and compared with experimental results. Therefore, CFD simulations were carried out to discretize the reaction medium. Samples were taken from both pilot and commercial plants. The TREF‐SEC analytical method was successfully applied in order to measure the microscopic structure of the material. The tremendous numerical problems were solved with the help of the software PREDICI .

Detailed MWD for a pilot scale reactor product.     

我公司进行热电联产的可行性分析

大压差减温减压是能的严重贬值。根据公司供热现状，分析了热电联产的可行性，利用蒸汽余压发电后，再供生产系统各热用户，这样既节约了能源又缓解了集团公司用电紧张的局面，而且有相当可观的经济效益。     

Influence of Distributed Particle Size on the Determination of the Parabolic Rate Constant for Oxidation by the Powder Method

The established analysis for the study of oxidation using powder specimens is based on the assumption of monosized particles. The experiments, however, are conducted on powders with a distributed particle size. Here we present a statistical approach for the calculation of the rate constant for oxidation. The results of the analysis are applied to new data on oxidation studies of dense powders of silicon carbonitride amorphous ceramics. The monosized model requires a wide range of values for the rate constant to fit the short term and the long-term data, leading to considerable ambiguity in the estimate of the parabolic rate constant, k _p, for oxidation. In contrast the statistical model fits over the entire range of data, yielding a much more reliable value for k _p. For example, the monosized approach gave a value in the range 19.7 × 10⁻¹⁸ < k _p < 2.7 × 10⁻¹⁸ m²/s. In contrast, the statistical model yields a specific value of 4.5 × 10⁻¹⁸ m²/s.     

常减压蒸馏装置中和缓蚀剂的研制

针对炼油厂常减压塔塔顶冷凝系统现存的腐蚀问题,研制出以有机胺、咪唑啉衍生物为主要组分复配而成的新型中和缓蚀剂。通过模拟蒸馏实验表明:液相部位的缓蚀率达到99%以上,在初馏区露点部位的缓蚀率达到98%以上该中和缓蚀剂性能优良。     

Phase behavior and density of polysulfone in binary fluid mixtures of tetrahydrofuran and carbon dioxide under high pressure: Miscibility windows

Mixtures of tetrahydrofuran (THF) and carbon dioxide (CO₂) were identified as new solvent systems for polysulfone. The miscibility and density of polysulfone in binary fluid mixtures of THF and CO₂ were investigated from 300 to 425 K at pressures up to 70 MPa. The influence of the CO₂ and polysulfone concentrations was studied, with the concentrations of the other two components kept constant. At a 4.5 wt % polymer concentration, the demixing pressures in a 10 wt % CO₂ and 90 wt % THF mixture increased with temperature (310–425 K) from 15 to 40 MPa. With increasing CO₂ concentration (from ca. 10 to 14 wt %), a significant increase (from 15 to 70 MPa at 310 K) was observed in the demixing pressures. Furthermore, with an increasing amount of CO₂, the nature of the phase boundary shifted from lower critical solution temperature behavior to upper critical solution temperature behavior. The influence of the polymer concentration was studied in the 0–5 wt % range at two CO₂ levels, with solvent compositions of 10 wt % CO₂ and 90 wt % THF and 13 wt % CO₂ and 87 wt % THF. The system with a higher level of CO₂ (13 wt %) showed highly unusual phase behavior: on pressure–composition and temperature–composition diagrams, the system displayed two distinct regions of miscibility. In the system with 10 wt % CO₂, the distinct regions of miscibility that were observed in the system with 13 wt % CO₂ partially overlapped and led to a W‐shape phase boundary. The densities of the polymer solutions were measured from the one‐phase region through the demixing point into the two‐phase region at a constant temperature. No significant change in density was found around the phase boundary; this indicated that the coexisting phases had similar densities, as is often the case with liquid–liquid phase separation in polymer solutions under high pressure. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2357–2362, 2002     

Prediction of minimum velocity and minimum bed pressure drop for gas-solid fluidization in conical conduits

Experimental investigations have been carried out for spherical and non-spherical particles using beds comprised of single-sized particles and mixtures in the size and particle density ranges of 439 to 1524 μm and 1303 to 4948 kg/m³, respectively. Five conical fluidizers with varying apex angles of 8.86, 14.77, 19.60, 32.0 and 43.2 degrees were used. Experimental values of minimum velocity and bed pressure drop with air as the fluidizing medium have been compared with their respective values obtained from different models available in the literature. Deviations for each chosen model have been presented.