Charge transfer resistance of spray deposited and compressed counter electrodes for dye-sensitized nanoparticle solar cells on plastic substrates

Electrochemical impedance spectroscopy was used to determine the effective charge transfer resistances of porous dye-sensitized solar cell counter electrodes prepared by low-temperature spray deposition and compression of conductive carbon and platinized Sb-doped SnO₂ powders on indium tin oxide-coated plastic substrates. The charge transfer resistances were 0.5–2 and 8–13 Ω cm², respectively, when using 3-methoxypropionitrile as the electrolyte solvent. The manufacturing method used lends itself to produce mechanically stable and even-quality electrodes in an easy and fast manner.     

碎丝埋弧焊在大型立式储罐中的应用

大型储罐底板焊接及变形控制是保证储罐整体施工质量的关键环节,采用碎丝填充的焊接方法可以防止变形,同时可以有效地避免应力集中,提高施工质量。文章介绍了碎丝埋弧焊的原理、工艺参数和焊接方法。实践证明,填充碎丝不仅是一种减小底板焊接变形的手段,同时可以充分利用焊接热能,节约焊接时间和焊剂用量,经济效益好,是一种值得推广的技术。     

NiCuZn铁氧体和银内电极的共烧行为

NiCuZn铁氧体正作为磁介质广泛地应用于低烧多层片式电感，因此有必要对其与银内电极的共烧行为进行研究。该文主要介绍NiCuZn铁氧体／银内电极多层复合体共烧过程中的烧结收缩、界面反应、扩散对介质性能的影响。尖晶石结构中存在相当数量的空位，这为银离子提供了一定的溶解度，因此在共烧过程中银对铁氧体的相组成影响较小。银对铁氧体性能的影响体现在两个方面。一方面是由于银具有相对低的烧结温度，从而在烧结过程中起到助烧剂的作用，促进致密化过程，提高烧结体的密度和磁导率；另一方面，银促使铁氧体中的铜在晶界处析出，导致晶界处应力，使磁导率降低，晶粒生长也被一定程度地抑制。     

FAFFA加速的PO-MM研究复杂金属载体上线天线电磁特性

本文提出了一种快速远场近似(FAFFA)加速的混合物理光学矩量法(POMM),利用FAFFA加速计算矩阵方程中的矩阵矢量积,明显提高了计算效率.对物体表面上的远场组之间的耦合作用推导出了一组简洁的计算公式,并分析了计算复杂度.复杂金属组合体上线天线输入导纳、互导纳和方向性图的计算结果与文献结果一致.利用该方法分析计算了一个舰船模型上线天线的电磁特性.数值结果表明了这种方法的正确性和工程应用中的有效性.     

系列尼古丁PVC膜选择性电极的研制

以尼古丁为研究对象 ,研制了一系列含有不同增塑剂 (苯二甲酸二辛酯、苯二甲酸二壬酯和癸二酸二辛酯 )和电活性物质 (尼古丁 四苯硼缔合物、尼古丁 硅钨酸缔合物、尼古丁 磷钨酸缔合物和尼古丁 雷氏盐缔合物 )的PVC膜电极。所有的 8支电极均对尼古丁盐酸溶液有Nernst响应。所制备的电极中 ,以尼古丁 四苯硼缔合物、尼古丁 硅钨酸缔合物、尼古丁 磷钨酸缔合物或尼古丁 雷氏盐缔合物为活性物的电极 ,其线性范围达到 10 - 4～ 10 - 1 mol/L ,以尼古丁 硅钨酸缔合物为活性物的电极线性范围达到 10 - 5～ 10 - 1 mol/L。电极响应的均匀性还在进一步的研究和改善中     

高硬度耐磨电弧喷涂管状丝材的研究

利用自熔性合金与非晶态材料的特点，研制了Fe—B系管状丝材作为电弧喷涂材料，其形成的涂层具有良好的结合强度、低的孔隙率、高的硬度和耐磨损性能。     

Investigation of electrode and hydrogen induced crack in welded joint of dissimilar steel

The welded joint of dissimilar heat-resisting steels 20Crl2MoV(F12)and 12 Cr2MoWVTiB(102)generally works around 600°C.In this paperthree kinds of ferritic electrodes are used for testing.They are R817 high-strength electrode(CrllMoVNi),R347 low-strength electrode(Cr2MoVWB)and newly-developed R507MoNb medium-strength electrode.The study on theinfluence of those three different electrodes on carbon migration,HIC and hy-drogen diffusion shows that medium-strength electrodes can well control thecarbon migration,and that the tendency to HIC in the joint formed by R817 issmaller than that by R347 instead.Considering the effect of weld metal transfor-mation on the restraint stress and hydrogen concentration of a joint,the hydro-gen distribution in the heat-affected zone(HAZ)is calculated by using finite ele-ment method(FEM)with stress and strain changing,and so the effect of thetransformation behaviour on HIC is revealed.In addition,newly-developedR507MoNb electrodes,tested the elevated-temperature property,oxidation re-sistance and creep rupture strength,have fulfilled the technical standards con-cerned and passed the examination of on-the-spot operation.     

钢丝绳抽油杆抽油超冲程分析

通过对钢丝绳抽油杆和常规钢杆振动模型固有频率的分析，从理论上分析了钢丝绳抽油杆和常规钢杆振动形成谐振(超冲程)的奈件；同时讨论了振动阻尼系数对共振的影响关系，从理论上得出了钢丝绳抽油杆在抽油时更易形成超冲程，进而从理论上解释了钢丝绳抽油杆在抽油过程中的泵效较高的事实，进一步解释了当前人们对钢丝绳应用和研究中的一些疑点和难点，为钢丝绳抽油系统的设计和应用提供了重要的理论指导。     

Effects of thermal oxidation conditions of silicon electrodes on cathodic electrochemiluminescence of Ru(bpy)3 chelate

Hot electrons emitted from thin oxide film-coated heavily doped silicon electrodes by cathodic pulse polarization can induce electrochemiluminescence from luminophores. The intensity of electrochemiluminescence produced at the electrode surface is dependent on the features of thin oxide films formed by thermal oxidation. As a preliminary study, we investigated the effect of thermal oxide growth conditions on the intensity of electrochemiluminescence produced at these electrodes, such as oxidation atmospheres, oxidation temperature, oxidation time and pre-treatment of wafers, using ruthenium(II) tris-(2,2′-bipyridine) chelate as a model luminophore. Optimal oxidation conditions of heavily doped silicon electrodes were obtained for the generation of intense electrochemiluminescence at this kind of silicon electrodes.     

石墨电极高温抗氧化技术研究现状

概述石墨电极抗氧化技术的研究现状，重点介绍选择抗氧化涂层体系的要求及涂层制备方法，包括包埋浸渗法、化学气相沉积法、等离子喷涂法及溶胶--凝胶法．展望了石墨电极材料高温抗氧化涂层研究的方向．