A FT-IR assessment of iso-C4H8 reactivity with V2O5/TiO2 catalysts

Low-loaded vanadia-titania catalysts have been prepared by impregnation of titania P-25 (Degussa). The catalysts were characterized by X-ray diffraction, specific surface area and porosity assessment by nitrogen adsorption at 77 K. For very low vanadia contents the absence of surface acid Brønsted sites leads to dimerization on surface acid Lewis sites, whereas the presence of surface acid Bransted sites when the vanadia content is increased leads to oxidation to carbonyl and carboxylate species.     

Evolution of BET internal surface area in glassy carbon powder during thermal oxidation

It is demonstrated that glassy carbon powder can be thermochemically activated. During activation, a film with open pores is created on the glassy carbon particles. This film has a large internal surface area, which is accessible to liquids and gases. A simple model for the evolution of the internal surface area in glassy carbon powder during thermochemical gas-phase oxidation is also presented and compared with experimental data. Experimental results are in qualitative agreement with the model. We found that a sharp particle size distribution is desirable with regard to potential technical applications.     

砷化镓声电荷转移延迟线的设计与工艺研究

由于声电荷转移(ACT)这一新颖的高速缓冲抽样技术的发明,使得新一代高速高频信号处理器件的实现成为可能。本文研究了第二代平面结构的ACT器件转移沟道的电位分布特性,给出了平面结构ACT延迟线的设计,并研究了ACT器件的工艺实现。     

A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

航空齿轮表面硬化层断裂性能研究

按照航空齿轮的具体工艺过程，对材料12Cr2Ni4A的拉伸试样和断裂试样进行设计和加工，通过三点弯曲实验，重点研究了齿轮材料硬化层的硬度分布，硬化试样拉伸力学性能参数和断裂性能参数，实验结果表明，所采用试样的加工工艺方案是可行的，所获得的Kc基本反映我国航空硬化齿轮材料的断裂性能特征，为定量预测航空硬化齿轮疲劳寿命提供实验和理论分析的依据。     

优化SMC模压工艺控制制品收缩率和表面粗糙度

优化SMC模压工艺参数：模压压力分为二阶段，选定最佳压力释放时机和压力；适宜降低模压温度。可显著降低SMC制品的固化收缩率，提高其表观质量、试验表明，同时采用的线收缩率和表面粗糙度两种检测和村定方法具有很好的同一性。     

The amylose and lipid contents,dimensions, and gelatinisation characteristics of some wheat starches and their A- and B-granule fractions

Starches isolated from 23 bread wheats (Triticum aestivum) and 26 durum wheats (T. durum) contained 26.3-30.6% (mean 29.1%) total amylose, 19.3–25.1% (mean 22.9%) apparent amylose and 783–1144mg 100g^?1 (mean 977 mg 100g^?1) lysophos-pholipids. Gelatinisation temperatures were 57.3–64.9°C (mean 61.8°C) and enthalpies 6.4–11.8 Jg^?1 (mean 9.7Jg^?1) in excess water, measured by differential scanning calorimetry. There were no correlations between any of these parameters. Starch granule size distributions were determined with a Coulter Counter and 100–channel analyser. A-granule mean volumes were 1235–2585μm³ (av. 1778), modal volumes 863–1804μm³ (av. 1264), mean diameters 13.9–16.0μm (av. 13.99), and specific surface areas 0.236–0.302m²g^?1. B-granule mean volumes were 35.4–100.4μm³ (av. 55.9), modal volumes 16.5–54.5μm³ (av. 27.7), mean diameters 3.66–5.07μm (av. 4.09), and specific surface areas 0.684–0.920m²g^?1. The B-granule contents of the starches were 12.8–34.6% (av. 27.3) by weight (sedimentation method) and 13.0–37.3% (av. 24.0) by volume (Coulter method), the latter being the more accurate method.     

榆林气田低产低效井开发分析评价

榆林气田自1999年投入开发以来,产能建设大幅提高,生产规模成倍增长。随着气田开发规模的扩大,气井数量成倍增加,低产低效井的数量随之增加,对低产低效期间加强研究意义重大。以理论知识为指导,利用开发生产资料对榆林气田低产低效气井的地质特征,开发现状,管理制度,下步开发措施等方面予以分析与研究,提出具体建议或措施;寻找榆林气田低产低效井合理的开发方式及生产模式。     

The influence of additives on the rheological and sensory properties of nonfat yogurt

In this work, response surface methodology was applied to a study of the effects of the addition of skim milk powder and stabilizers on the apparent viscosity and sensory attributes of nonfat yogurt. The addition of stabilizers has been shown to produce a significant effect on sensory attributes, while high concentrations of xanthan and guar gum are seen to decrease the overall acceptability of the yogurt, with gelatin producing the higher apparent viscosity and consistency. The correlation among apparent viscosity, which is an instrumental measurement, and consistency, which is a sensory evaluation, was 0.72.     

薄板坯表面变形实验分析

对连铸薄板坯的坯壳表面变形的物理模拟实验方法进行了分析,提出一种"铜裹铅双金属"新实验方案,并对坯壳表面弯曲变形进行了分析.