Corrosion protection of iron by polypyrrole coatings electrosynthesised from a surfactant solution

This work is a study of the electropolymerisation of pyrrole onto iron electrodes in the presence of sodium bis(2-ethylhexyl) sulfosuccinate in a wide pH interval. The characterisation of the films was done using electrochemical techniques, SEM/EDX and IR spectroscopy. We show that it is possible to synthesise homogeneous, adherent and very compact films in the pH range between 7 and 12 under potentiodynamic, galvanostatic and potentiostatic conditions without substrate dissolution. The effects of various parameters on electrodeposition were investigated. The new procedure for the electrochemical synthesis of polypyrrole results in improved anticorrosion properties. The inhibition is proposed to be due to the sum of a repulsion of chloride ions because AOT remains entrapped in the polymer matrix and the presence of the iron oxide. Advantages of the use of surfactants in the electropolymerisation solution are discussed.     

Poly(N-methylaniline) coatings on stainless steel by electropolymerization

Poly(N-methylaniline) (PNMA) coatings have been electropolymerized on 304 stainless steel alloy by potentiodynamic, galvanostatic and potentiostatic synthesis techniques from aqueous solutions of 0.1 M N-methylaniline (NMA) and 0.3 M oxalic acid. Characterization of PNMA coatings was carried out by cyclic voltammetry, UV-Vis and FTIR spectroscopy techniques. Corrosion behavior of PNMA coated stainless steel electrodes was investigated using linear anodic potentiodynamic polarization, Tafel test, chronoamperometry and electrochemical impedance spectroscopy (EIS) techniques in 0.5 M aqueous HCl solutions. Corrosion test results showed that PNMA coatings possessed protection to uncoated stainless steel against corrosion.     

调制波长对Cu／Ni金属多层膜力学性能的影响

用电沉积法在低碳钢基体上制备了具有不同调制波长(一个调制波长等于单层Cu膜与单层Ni膜厚度之和)的Cu/Ni金属多层膜，研究了多层膜硬度与其中单层膜厚度之间的关系。结果表明，当膜厚在亚微米范围内时，Cu/Ni多层膜的屈服强度(为硬度值的1/3)与单层膜厚之间符合基于位错塞积模型的Hall-Pctch(H-P)关系式；而当单层膜厚小于100nm时，屈服强度与膜厚的关系偏离了H-P线性关系。基于程开甲等人位错稳定性理论首次对金属多层膜变形行为偏离Hall-Petch关系的现象作了定量解释。     

Co/Cr/Pd多层膜的磁性及其准确性

研究了测量程序对不同Cr层厚度的Co／Cr／Pd多层膜磁性的影响，分析了反磁化机理在不同测量程序中对磁性准确性的影响。     

Interface reactions in film materials

Interface reaction (IR) is a frequently observed phenomenon in the study of advanced thin film materials. It is very important to study the reaction conditions at which IR happens and then to suppress or make use of it, the necessary conditions, including both thermodynamical and dynamical conditions of IR were discussed in detail. IRs in various systems, including oxide/silicon, oxide/metal, metal/metal, metal/semiconductor and semiconductor/semiconductor, were reviewed. Methods to suppress and make use of IR were also introduced.     

抑制BaF2晶体闪烁光慢成分的选择吸收膜系的研究

根据BaF2晶体闪烁光快、慢成分波段的不同，设计并制备了用于抑制该晶体闪烁光慢成分的Al2O3／MgF2／Al／MgF2…金属-介质选择吸收膜系．透射光谱、发射光谱和发光衰减时间谱的实验结果显示，所研制的选择吸收膜系达到了预期的要求，BaF2晶体闪烁光快、慢成分比提高了80倍以上，有效地提高了：BaF2闪烁晶体在高计数率测量中的应用价值．     

中非铜矿带多层位成矿特征及成因

中非铜矿带位于刚果(金)—赞比亚的Lufilian造山带,新元古界加丹加超群发育有大量的沉积岩容矿层状铜矿(SSC),为了解铜矿床的成矿特征和矿床成因,对矿床地质特征进行总结,发现中非铜矿带主要为还原相型和砂岩型层状铜矿床,具有明显的多层位层控特征.其中加丹加铜钴矿带(KCB)盛产还原相型铜矿床,主要赋存于Roan群M...     

电沉积Ni80Fe20/Cu纳米多层膜及其巨磁电阻效应

采用单槽控电位双脉冲技术在n-Si（111）晶面上制备了［Ni₈₀Fe₂₀/Cu］_n多层膜,用SEM观测了多层膜的断面形貌,利用X射线衍射（XRD）表征了多层膜的超晶格结构。采用四探针法研究了多层膜的巨磁电阻（GMR）性能,结果表明,多层膜的GMR值随着Cu层厚度的变化发生周期性振荡,随着NiFe层厚度的增加先增大后减小;当样品结构为［NiFe（1.6 nm）/Cu（2.6 nm）］₈₀时,GMR值可达6.4%;多层膜的最低饱和磁场仅为750Oe。磁滞回线测试结果表明,反铁磁耦合多层膜具有较小的矩形比,更适宜作为磁头材料。     

Optical Electron Spectroscopy and Electronic Properties for Multilayers ofal/Al203

Al/Al203 multilayers with nanometer scale are fabricated by thermal evaporation and natural oxidizationtechniques. The detection of X-ray and photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS) is performed, and the curve ofei (ki ) is got. The properties of the negative resistance for the multilayers are found.