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Synthesis of novel nonionic surfactants has attracted attention of synthetic chemists due to the issues of the currently used commercial surfactants. The synthesis of three biocompatible triazole-based nonionic surfactants is reported for nanovesicular drug loading. The surfactants were synthesized in a three-step reaction and characterized using 1HNMR and mass spectroscopy techniques. They were investigated for their critical micelle concentration (CMC) using a UV–Visible spectrophotometer. Their biocompatibility was investigated against cell culture and in blood. All the synthesized nonionic surfactants were further explored for their nanovesicular drug loading using clarithromycin as a model hydrophobic drug. Nonionic surfactants revealed lower CMC in 35–45 μM and were less hemolytic and cytotoxic. They were capable of self-assembling in nanosize niosomal vesicles encapsulating increased amounts of drug. The results suggest the synthesized nonionic surfactants as biocompatible nanotechnology-based drug-delivery vehicles. 相似文献
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《Particulate Science and Technology》2007,25(1):77-89
The removal of particulate contamination is a critical issue for many manufacturing processes. It is particularly critical to the electronics industry in which small pieces of microscopic debris remaining after chemical mechanical planarization (cmp) using submicron polishing particles can cause device failure. One way to enhance particle removal following the cmp process is to utilize surfactants. Recent research has shown ways to model the effect of surfactants on enhanced particle removal. However, previous research has not demonstrated the effect of ionic strength on enhanced particle removal associated with surfactant use. Past research has also not shown the combined effects of ionic strength and surfactant concentration on enhanced particle removal using surfactants. This article summarizes the parameters affecting particle removal, and it provides data and analysis on the effect of ionic strength as well as the combined effects of ionic strength and surfactant concentration on particle removal following cmp processing. 相似文献
5.
The biochemical basis for considering tannins as digestion inhibitors has been reexamined. Both stimulatory and inhibitory effects of tannins on tryptic hydrolysis are reported. We show how stimulation may result from tannin-induced structural changes in the substrate protein, effectively denaturing it. The surfactant and bile constituent cholic acid also produced similar stimulatory effects. These results have considerable implications for normal digestive physiology as well as for the impact of tannins on argicultural and natural herbivore populations. 相似文献
6.
A seed-growth method has been applied to synthesize gold (Au) and Au-silver (Ag) bimetallic nanoparticles (NP) by using 12-3-12, a cationic Gemini surfactant, as a capping agent as well as micellar template. A systematic increase in the [12-3-12] from pre- to post-micellar region (up to 5 times the critical micelle concentration, cmc) produces Au NP from spherical to large plate like structures. Keeping [12-3-12] constant (equal to 1 / 2 cmc) and increasing ascorbic acid (AA) concentration lead to the formation of core shell type Au-Ag bimetallic NP. At maximum AA concentration (i.e. [AA] = 5.6 mM), fused bimetallic Au-Ag NP are obtained. The anisotropic growth of such materials is a key factor for various applications in nanotechnology. 相似文献
7.
Akihiko Sakurai Mina Masuda Mikio Sakakibara 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(9):952-958
The removal of phenol by peroxidase‐catalysed polymerization was examined using Coprinus cinereus peroxidase in the presence of surfactants. The non‐ionic surfactants with poly(oxyethene) residues, Triton X‐100, Triton X‐405 and Tween 20, enhanced the phenol removal efficiency at a level similar to high relative molecular mass poly(ethylene glycol) (relative molecular mass 3000). Although the improvement in the removal efficiency was less than that of Triton X‐100, Span 20, sodium lauryl sulfate (SDS) and lauryl trimethylammonium bromide (DTAB) also enhanced the removal efficiency. The requirement of the enzyme for almost 100% removal of 100 mg dm?3 phenol decreased to one‐fourth by the addition of 30 mg dm?3 Triton X‐100. Triton X‐100, Triton X‐405, Tween 20 and DTAB could reactivate the enzyme precipitated with the phenol polymer, leading to the restarting of the phenol removal reaction. Copyright © 2003 Society of Chemical Industry 相似文献
8.
Sushama Mishra B K Mishra D K Chokappa D O Shah C Manohar 《Bulletin of Materials Science》1994,17(6):1103-1108
It is conjectured that anionic-cationic surfactant combination can be regarded as equivalent to a double chain surfactant
and using molecular packing considerations it is shown that vesicles, viscoelastic solutions and liquid crystals can be designed
by the proper choice of chain lengths of the pair. Using these concepts new systems are designed, from mixtures of cetyltrimethyl
ammonium bromide and sodium alkyl sulfonates, to produce both viscoelastic gels and vesicles. 相似文献
9.
N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠的合成及性能研究 总被引:1,自引:1,他引:0
用 N,N′-二羟乙基乙二胺、氯乙酸钠合成了 N,N′-二羟乙基乙二胺二乙酸钠(中间体),中间体再与硬脂酰氯反应制备了一种新型 Gemini 两性表面活性剂 N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠。对产物合成条件进行了考察,优化的反应条件为:n(硬脂酰氯):n(中间体)=2.5,溶剂 V(水):V(氯仿)=1:2,pH=9.0~10.0,反应温度15~20℃,反应时间5 h。通过红外光谱和质谱分析确定了产物结构,并测试了产物的表面性能。结果表明,在25℃时,该产物的临界胶束浓度为0.24 mmol/L,临界胶束浓度下的表面张力为35.7 mN/m;即时泡沫高度为250 mm,5 min 后泡沫高度为220 mm;乳化时间为22.48 min(甲苯-水物系)和4.65 min(正己烷-水物系),亲水-亲油平衡值为5.4,等电点为 pH 3.3~6.5。 相似文献
10.
Ravan A. Rahimov Gulnara A. Ahmadova Seyid-Zeynab F. Hashimzade Elmar Imanov Hajibala G. Khasiyev Nazani K. Karimova Fedor I. Zubkov 《Journal of surfactants and detergents》2021,24(3):433-444
Two new classes of gemini cationic surfactants—hexanediyl-1,6-bis[(isopropylol) alkylammonium] dibromide {in the abbreviation form: CnC6Cn[iPr-OH] and CnC6Cn[iPr-OH]2; alkyl: CnH2n + 1 with n = 9, 10, 12 and 14}—have been synthesized by interaction of alkyl bromides with N,N′-di-(isopropylol)-1,6-diaminohexane and N,N,N′,N′-tetra-(isopropylol)-1,6-diaminohexane. The surface tension, electrical conductivity, and dynamic light scattering (DLS) techniques were used to investigate the aggregation properties of the gemini cationic surfactants in aqueous solution. The formation of critical aggregates at two concentrations in an aqueous solution from obtained gemini cationic surfactants were determined via the tensiometric method. Thus, these gemini cationic surfactants start to form aggregates at concentrations well below their critical micelle concentrations (CMC). The surface properties and the binding degree (β) of the opposite ion were tested against the length of the surfactant hydrocarbon chain and the number of the isopropylol groups in the head group. By applying the DLS technique, it was explored that how the number of isopropylol groups in gemini cationic surfactants with C12H25 chain affects the sizes of micelles at concentrations greater than CMC. It was discovered that the obtained gemini cationic surfactants have a biocidal character. 相似文献