Fresh and frozen-thawed (F-T) pork meats were classified by Vis–NIR hyperspectral imaging. Eight optimal wavelengths (624, 673, 460, 588, 583, 448, 552 and 609 nm) were selected by successive projections algorithm (SPA). The first three principal components (PCs) obtained by principal component analysis (PCA) accounted for over 99.98% of variance. Gray-level-gradient co-occurrence matrix (GLGCM) was applied to extract 45 textural features from the PC images. The correct classification rate (CCR) was employed to evaluate the performance of the partial least squares-discriminate analysis (PLS-DA) models, by using (A) the reflected spectra at full wavelengths and (B) those at the optimal wavelengths, (C) the extracted textures based on the PC images, and (D) the fused variables combining spectra at the optimal wavelengths and textures. The results showed that the best CCR of 97.73% was achieved by applying (D), confirming the high potential of textures for fresh and F-T meat discrimination. 相似文献
In the present work, the prospects and trends of solid electrolyte membrane reactors (SEMRs) towards hydrogen production, are discussed. Initially, an overview of the principles, the properties and the techniques related to the usage of the SEMRs, are presented. In the following, a literature survey covering earlier and recent developments of the various methods (e.g. reforming or partial oxidation or dehydrogenation of hydrocarbons, steam electrolysis) employed in the SEMRs for the production of hydrogen, is performed. Finally, the current status of this research field is analyzed and future research topics are proposed. 相似文献
The partial oxidation of methanol to formaldehyde was studied over YBa2Cu3O7-x catalyst in a flow reactor. The structural change of YBa2Cu3O7-x before and after the reaction was measured by means of XRD and iodometric titration method. The catalytic characteristics
of YBa2Cu3O7-x for the partial oxidation of methanol to formaldehyde was due to copper ions. It was found that Cu+2 was responsible for the higher selectivity for formaldehyde. 相似文献
A significant part of the theory of one-dimensional linear shift-invariant systems is based on the concept of weighting function
(or impulse response): the output is the convolution of the weighting function with the input. This paper introduces the concept
of linear translation-invariant systems and uses this notion in studying impulse response, z-transforms, and transfer functions
for multidimensional systems. 相似文献
It is shown that steady-state kinetic data do not allow the discrimination between the redox and associated mechanisms of the partial oxidation reactions. A discrimination between these mechanisms was performed using transient experiments. The obtained rate expressions are in agreement with experimental kinetic data for catalytic partial oxidation of o-xylene.
An influence of the conjugate oxidation of a catalyst surface on dynamics and kinetics of the heterogeneous catalytic oxidative reactions is considered. Computing simulation of methane oxidative coupling of methane reaction at lowered temperature and elevated pressure has been performed. It showed that the reaction order with respect to oxygen exceeding unity is consistent with the chain branching mechanism of the reaction in the presence of TiSi2 and TiB2 and showed the important role of the branching chain cycles in the low-temperature OCM reaction at elevated pressure. 相似文献
A promising catalytic system for the low temperature oxidation of methane to a methanol derivative has been investigated under both batch and semi-continuous operation in two different reactor types. The system comprises of a bimetallic palladium and copper(II) chloride catalyst contained in a trifluoroacetic acid (TFA) and an aqueous phase. Methane, oxygen and a co-reductant carbon monoxide constitute the gas phase. Typical operating conditions were a temperature of 85 °C and a pressure of 83 bar.
The yields of the methyl trifluoroacetate product observed in this present work were less than those obtained in other batch autoclave works, which employed only 4 ml of liquid phase, compared with 50 ml in this study. Furthermore, an encouraging initial product formation rate of ca. 40 mol/m3 h, quickly decreased after the first hour, and came to an apparent end after only 2 h. This observation had not been reported previously.
Work performed in a semi-continuous porous tube reactor (300 ml of re-circulating liquid phase) also showed the same reaction characteristics as in the batch reactor. Thus, the deteriorating product formation rate cannot be attributed to gaseous reactant depletion (batch operation). The results suggest problems associated with catalyst instabilities, e.g. with the previously elucidated Wacker chemistry. 相似文献
There is an effective and quite general method of manually deriving compilers from programming-language interpreters without dealing directly with machine language. The method is an implementation of the largely theoretical and under-appreciated concept of partial computation, but can be understood on its own terms. It involves the translation of a source program's intermediate form into the interpreter's implementation language. This paper shows how the method can be used to transform both a sample iterative interpreter and a sample recursive interpreter into compilers. The result can be a large gain in program execution speed. Other advantages of the method, including the ease and practicality of applying it, are discussed. 相似文献
As the result of vibration emission in air, a machine sound signal carries important information about the working condition
of machinery. But in practice, the sound signal is typically received with a very low signal-to-noise ratio. To obtain features
of the original sound signal, uncorrelated sound signals must be removed and the wavelet coefficients related to fault condition
must be retrieved. In this paper, the blind source separation technique is used to recover the wavelet coefficients of a monitored
source from complex observed signals. Since in the proposed blind source separation (BSS) algorithms it is generally assumed
that the number of sources is known, the Gerschgorin disk estimator method is introduced to determine the number of sound
sources before applying the BSS method. This method can estimate the number of sound sources under non-Gaussian and non-white
noise conditions. Then, the partial singular value analysis method is used to select these significant observations for BSS
analysis. This method ensures that signals are separated with the smallest distortion. Afterwards, the time-frequency separation
algorithm, converted to a suitable BSS algorithm for the separation of a non-stationary signal, is introduced. The transfer
channel between observations and sources and the wavelet coefficients of the source signals can be blindly identified via
this algorithm. The reconstructed wavelet coefficients can be used for diagnosis. Finally, the separation results obtained
from the observed signals recorded in a semi-anechoic chamber demonstrate the effectiveness of the presented methods . 相似文献