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1.
可生物降解的钻井液降滤失剂SPS的合成与性能研究 总被引:4,自引:0,他引:4
以淀粉为主要原料合成了一种可生物降解的钻井液滤失剂SPS,考察了SPS的生物降解性及其在淡水泥浆,盐水泥浆和海水泥浆中的性能。结果表明,SPS具有良好的降滤失与抗温、抗污染性能,在海水中可被生物降解。 相似文献
2.
John Karkalas 《Journal of the science of food and agriculture》1985,36(10):1019-1027
An improved method for the determination of starch by sequential hydrolysis with thermostable bacterial α-amylase and fungal amyloglucosidase is described. Glucose was determined colorimetrically by a glucose oxidase-peroxidase-chromogen system at pH 7. Native normal and waxy starches, and distarch phosphate, gave quantitative yields of glucose with a high degree of precision (coefficient of variation less than 1%). Acetylated distarch phosphate, high-amylose starch and retrograded amylose were initially treated with 1M NaOH for 30 min, then neutralised and analysed successfully as normal starch. Oxidised starch did not give a quantitative yield of glucose because of the presence of dicarboxylic groups in the polymer. For samples containing normal and waxy starch the analysis was carried out in about 4 h. The method was applied to a range of starch-containing foodstuffs and the results are reported. 相似文献
3.
瓦楞纸板用抗水淀粉胶配方及性能研究 总被引:2,自引:1,他引:1
简要分析了玉米淀粉胶的组成及对其质量的影响,重点对粘合剂的防水性进行了研究,叙述了瓦楞纸板用抗水粘合剂的配制及工艺过程,并与常规方法制备的粘合剂进行了性能比较,测定了抗水时间,得出了瓦楞纸板用抗水粘合剂的最佳配制比例。 相似文献
4.
Thermoplastic starch (TPS), as opposed to dry starch, is capable of flow and hence when mixed with other synthetic polymers can behave in a manner similar to conventional polymer-polymer blends. This paper presents an approach to preparing polyethylene/thermoplastic starch blends with unique properties. A one-step combined twin-screw/single screw extrusion setup is used to carry out the melt-melt mixing of the components. Glycerol is used as the starch plasticizer and its content in the TPS is varied from 29 to 40%.Under the particular one-step processing conditions used it is possible to develop continuous TPS (highly interconnected) and co-continuous polymer/TPS blend extruded ribbon which possess a high elongation at break, modulus and strength in the machine direction. The PE/TPS (55:45) blend prepared with TPS containing 36% glycerol maintains 94% of the elongation at break and 76% of the modulus of polyethylene. At a composition level of 71:29 PE/TPS for the same glycerol content, the blend retains 96% of the elongation at break and 100% of the modulus of polyethylene. These excellent properties are achieved in the absence of any interfacial modifier and despite the high levels of immiscibility in the polar-nonpolar TPS-PE system. The 55:45 blend possesses a 100% continuous or fully interconnected TPS morphology, as measured by hydrolytic extraction. This highly continuous TPS configuration within the blend should enhance its potential for environmental biodegradation. The elongation at break in the cross direction of these materials, although lower than the machine direction properties, also demonstrates ductility at high TPS concentrations. At a glycerol content of 36% in the TPS, the blends demonstrate only very low levels of sensitivity to moisture. A high degree of transparency is maintained over the entire concentration range due to the similar refractive indices of PE and TPS and the virtual absence of interfacial microvoiding.Effective control of the glycerol content, TPS concentration and processing conditions can result in a wide variety of morphological structures including spherical, fiber-like, highly continuous and co-continuous morphologies. These various blend morphologies are shown to be the determining parameters with respect to the observed mechanical properties.This material has the added benefit of containing large quantities of a renewable resource and hence represents a more sustainable alternative to pure synthetic polymers. 相似文献
5.
讨论了淀粉、粗玉米粉及可以被淀粉所依附的纤维素框架的化学结构及性质,它们可能成为一系列用途广泛的干燥剂。 相似文献
6.
热塑性淀粉加工过程的控制参数及塑化程度的表征方法 总被引:2,自引:0,他引:2
在介绍热塑性淀粉塑料加工原理的基础上,提出特殊机械能可以作为描述热塑性淀粉塑化过程的控制参数;并对表征热塑性淀粉塑化程度的各种方法进行了总结和评述。 相似文献
7.
8.
The effect of carbon precursor on the pore size distribution of mesoporous carbon during templating synthesis process 总被引:1,自引:0,他引:1
Wenzhong Shen Xiangping Yang Qingjie Guo Yihong Liu Yanru Song Zhongxiang Han Qinglei Sun Jian Cheng 《Materials Letters》2006,60(29-30):3517-3521
The starch and cyclodextrin were selected as the precursors and the mixture of surfactant and tetraethyl orthosilicate (TEOS) as template to prepare mesoporous carbon. The result showed that a bimodal pore size distribution in mesoporous carbon derived from starch appeared; one was around 3.4 nm and the other ranged from 3.8 to 16.2 nm. However, there existed a concentrated pore size distribution from 3.2 to 4.2 nm in mesoporous carbon derived from cyclodextrin. The different molecular structure of starch and cyclodextrin and their polymerization process in the presence of sulfur acid were responsible for the resulted mesoporous carbon structure; the starch could polymerize by head to head or side by side, but the cycleodextrin was only polymerized by head to head. 相似文献
9.
分光光度法测定卵磷脂中磷 总被引:1,自引:0,他引:1
微量磷的测定,常采用磷钼兰光度法,近年来有报道应用极谱分析法[1] 。磷钼兰光度法利用P(V) 与钼酸铵形成磷钼杂多酸,应用不同还原剂还原为磷钼杂多兰,测定吸光度。应用NaF- SnCl2 作还原剂,基于酸性介质中磷钼兰光度法,以淀粉作稳定剂,在室温下(15 ~25 ℃) 显色。该方法具有颜色稳定、试剂易得、酸度范围大的特点。用于具有重要生物功能的保健性药物卵磷脂中磷的测定,结果与传统方法测定结果相一致。摩尔吸光系数ε= 2 .2 ×104 L/(mol·cm) ,相对标准偏差0 .5 % ~1 .1 % ,加标回收率在96 .6 % ~106 .7 % 之间,结果满意。 相似文献
10.
淀粉—丙烯酸接枝效率的测定 总被引:3,自引:0,他引:3
田桂芝 《石油化工高等学校学报》1996,9(4):34-36
通过测定淀粉-丙烯酸接枝共聚物的接枝效率和吸水率,提出了一种以丙酮为溶剂,用电热套直接加热回流萃取均聚物代替常温搅拌萃取均聚物的方法.可使萃取时间从24h缩短到3~4h,使分析速度提高6~8倍,该法同样适合于其它淀粉乙烯基共聚物的分析. 相似文献