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A. Tricoteaux E. Rguiti D. Chicot L. Boilet M. Descamps A. Leriche J. Lesage 《Journal of the European Ceramic Society》2011,31(8):1361-1369
Beta-tricalcium phosphate [Ca3(PO4)2, β-TCP] is a bioresorbable material showing an excellent biocompatibility. However, sintering of β-TCP is difficult and the material presents poor mechanical strength and a low resistance to crack-growth propagation. In this study, influence of the porosity on the hardness and the elastic modulus is studied by means of usual and instrumented microindentation tests. Nevertheless, indentation diagonals measurement by optical observations is not accurate due to the crack formation around the residual indent. That is why instrumented indentation test which allows deducing the hardness and the bulk modulus from the load-depth curve analysis is used as an alternative method. The corresponding hardness number can be calculated by using the maximum indentation depth (Martens Hardness) or the contact depth determined by Oliver and Pharr's method (Contact Hardness). But in order to give representative values when comparing classical and instrumented hardness measurements, Martens hardness is preferred because its value can be directly related to the value of the Vickers hardness number by simple geometrical considerations.In this work, bioceramics were produced by conventional sintering of β-TCP powders synthesized by aqueous precipitation. Different process conditions were chosen to obtain microporous ceramics with a porosity rate between 0 and 14% in volume. As main results, the elastic modulus is found decreasing between 166 GPa and 108 GPa and the hardness number from 4.4 GPa to 2.2 GPa when increasing the porosity rate. A model connecting mechanical properties to porosity rate and grain arrangement is validated for the elastic modulus whereas deviation is observed for the hardness number. However, we propose an original approach where the relative variation of the two mechanical properties can be expressed with a unique relation as a function of the porosity volume fraction. 相似文献
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This study has developed a novel route for the synthesis of the thermoresponsive core-shell nanoparticles that consist of the magnetite core and the poly(N-isopropylacrylamide) (poly(NIPAAm) shell in aqueous medium. Magnetic nanoparticles (MNPs) were coated first with oleic acid (OA) and then vinyl carboxylic acid-β-cyclodextrin (MAH-β-CD). The OA-MNPs and the MAH-β-CD-MNPs showed mono-dispersion in n-hexane and aqueous medium, respectively. NIPAAms were successfully polymerized from the vinyl double bonds of the MAH-β-CD MNPs and cross-linked with N, N-methylenebisacrylamide (MBA) to make the stable thermoresponsive core-shell morphology with the MNP core and the poly(NIPAAm) shell (poly(NIPAAm)-MNP). The aqueous solutions dispersed with poly(NIPAAm)-MNPs showed magnetic heating due to a superparamagnetic property, and the poly(NIPAAm) shell shrank above its LCST temperature. The combination of these properties are potentially important in the targeted delivery of therapeutic agents in vivo, hyperthermic treatment of tumors, magnetic resonance imaging (MRI) as a contrasting agents, tissue repair, immunoassay, cell separation, biomagnetic separation of biomolecules, etc. 相似文献
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乙烯基三(β-甲氧基乙氧基)硅烷的合成工艺研究 总被引:1,自引:0,他引:1
以乙烯基三氯硅烷(ViSiCl3)、甲醇(MeOH)及乙二醇甲醚为主要原料,采用醇解、酯交换两步反应合成了ViSi(OEtOMe)3。确定了其最佳醇解反应条件为:n(ViSiCl3):n(MeOH)为1:3.6,反应温度为80℃,在此条件下中间体ViSi(OMe)3收率在85%左右;最佳酯交换反应条件为:n(ViSi(OMe)3):n(乙二醇甲醚)为1:3.6,反应温度为100℃,反应时间为1.5~2.0h,产物ViSi(OEtOMe)3酯交换的单程收率可达到92%。最后采用GC-MS法对最终产物结构进行了表征。 相似文献
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锂铝硅系微晶玻璃是一种具有优异的光学、力学性能的微晶玻璃材料。本文制备了以透锂长石和二硅酸锂为主晶相的锂铝硅系透明微晶玻璃,并通过DSC、XRD与SEM研究了MgO含量对该微晶玻璃析晶行为及结构的影响,利用维氏硬度、抗弯强度等测试方法研究了MgO含量对该微晶玻璃力学性能的影响。结果表明,当MgO含量(质量分数)从0%增加至3%,基础玻璃的析晶温度从771 ℃降低至729 ℃,析晶能力增强,微晶玻璃的结晶度从62%增加至72%,晶粒尺寸从29 nm增大至33 nm。随着MgO含量的增加,微晶玻璃中会析出β-石英固溶体,抗弯强度增大。 相似文献