钙钛石及类钙钛石型复合氧化物研究进展

介绍了钙钛石及类钙钛石型复合氧化物在催化及其它功能材料等方面的应用及存在的 发展趋势。     

LaCrMnNiO系热敏陶瓷的微观结构控制

通过对不同配方、工艺下的ＬａＣｒＭｎＮｉＯ系热敏陶瓷的微观结构研究，指出材料的相组成对其宏观电性能的影响，并提出了通过复合工艺利用“过渡相”的形成，对材料的“最终相”加以控制的方法。文中列出了使用ＸＲＤ及ＸＰＳ手段对材料微观结构的分析结果及有关电性能的测试数据。     

SHS法陶瓷衬管的研究现状及应用前景

回顾了自蔓延高温合成陶瓷衬管的发展历史，对国内外的研究现状进行归纳总结，介绍了离心ＳＨＳ法生产陶瓷衬管的工艺特点及产品性能，展望了离心ＳＨＳ陶瓷衬管的应用前景。     

高频脉冲电铸Ni-Co纳米复合块体微观结构分析

采用高频脉冲电铸工艺制备出了镍钴纳米复合块体材料，利用场发射扫描电镜、能谱和X射线衍射的方法，重点研究了复合块体沉积层的表面形貌、相结构和结晶取向。结果表明．高频率和润湿剂的添加对沉积层的细化有重要影响，高频脉冲电铸能够获得微观组织致密、均匀的复合块体材料。     

Thermal Expansion Behavior of La1—xSrxMn1—yCoyO3—δ Perovskites

The thermal expansion behavior of La1-xSrxMn1-yCoyO3-δ (x=0.2-0.4, y=0.1-0.3) perovskites in air has been investigated. The average linear thermal expansion coefficients increased with increasing Sr content up to 40 mole fraction or Co content up to 30 mole fraction. The expansion is generally attributed to an increase in the average cation radius as some of the cations in the perovskite are reduced in valence when oxygen ions are removed from the structure.     

日研制成铸铁与钢材的复合铸件

据外刊报道 ,日本一家造船公司研制成一种新型的复合铸件。它是由铸铁与钢材复合制成的 ,兼有铸铁和钢的优点 ,适用于制造连接活塞的大型船舶用柴油机的汽缸。用作汽缸材料的铸铁 ,里面含有的碳具有润滑的作用 ,能减少摩擦力 ,但含碳量过多则会降低材料的强度。如采用强度较高的钢材制造汽缸 ,对一些大型柴油机来说 ,活塞的磨损又不合要求。该公司为此研究出内侧用铸铁、外侧用钢材的复合铸件一体成型的方法。复合铸件是这样制造的 :先将铸模 (圆筒形 ,用特殊钢制成的 ,内部涂有特殊的陶瓷粉末 ,可防止材料因高温而熔化 )用喷烧器加热后 ,倒…     

Lattice Effects and Irreversible Magnetoresistance in Gd Doped La—Ca—Mn—O

The Gd substituting effects for La in La0.67Ca0.33MnO3 has been studied .With increasing the substituting amount of Gd,the phase transition temperature of metal-isolator for the samples decreases,the corresponding peak resistivity increases,the Curie temperature decreases monotonically.The substitution of La-Ca-Mn-O with 11% Gd for La improved the magnetoresistance ratio by an order of magnitude.The effects of substituting Gd can be explained in terms of the lattice effects.An irreversible MR behaviour was observed in Gd-substituting compounds.This effect became marked when the substituting amount of Gd was greater than 7%.A maximum irreversible increment of MR ratio as large as 91% was obtained when Gd substituting amount was 11%.