×Synergistic action of non-solvent induced phase separation in preparation of poly（vinyl butyral） hollow fiber membrane via thermally induced phase separation

A systematic study of air gap distance effects on the structure and properties of poly（vinyl butyral） hollow fiber membrane via thermally induced phase separation （TIPS） has been carried out. The results show that the hollow fiber membrane prepared at air gap zero has no skin layer; the pore size near the outer surface is larger than that near the inner surface; and the special pore channel-like structure near the outer surface is formed, which is quite different with the typical sponge-like structure caused by TIPS and the finger-like structure caused by non-solvent induced phase separation （NIPS）, because of the synergistic action of non-solvent induced phase separation at air gap zero. The pore size gradually decreases from outer surface layer to the intermediate layer, but increases gradually from intermediate layer to the inner surface layer. With the increase of air gap distance, the pore size near the outer surface gets smaller and a dense skin layer is formed, and the pore size gradually increases from the outer surface layer to the inner surface layer. Water permeability of the hollow fiber membrane decreases with air gap distance, the water permeability decreases sharply from 45.50× 10^-7 to 4.52× 10^-7 m^3/（m^2-s.kPa） as air gap increases from 0 to 10 mm at take-up speed of 0.236 m/s, further decreases from 4.52×10^-7 to 1.00×10 ^-8m^3/（m^2.s·kPa） as the air gap increases from 10 to 40 mm. Both the breaking strength and the elongation increase with the increase of air gap distance. The breaking strength increases from 2.25 MPa to 4.19 MPa and the elongation increases from 33.9% to 132.6% as air gap increases from 0 mm to 40 mm at take-up speed 0.236 m/s.     

Effects of coagulation bath temperature on structure and performance of poly （vinyl butyral） hollow fiber membranes via thermally induced phase separation

Poly （vinyl butyral） （PVB） hollow fiber membranes were fabricated via thermally induced phase separation （TIPS）. The effects of coagulation bath temperature （CBT） on the structure and performance of membranes were investigated in detail. The morphologies of the membranes were studied by scanning electron microscopy （SEM）, the performances of water permeability, rejection, breaking strength and elongation were measured, respectively. The results indicate that all the membranes have the asymmetric morphology and the thickness of the skin layer decreases and the pore size of the outer layer increases with the increase of CBT. The permeability of membranes prepared at air gap 1.0 cm and take-up speed 0.253 m/s increases from 1.047×10-7 to 5.909×10-7 m3/（m2·s-kPa） with the CBT increasing from 20 ℃ to 40℃, and sharply increases to 35.226×10 7 m3/（m2.s.kPa）once the CBT arrives at 50 ℃. While the carbonic ink rejections have no significant decrease, totally exceed 98%, but that of acid-maleic acid copolymer greatly decreases with the increase of CBT. Both the breaking strength and elongation decrease with the increase of CBT.     

Microstructure and properties of electronic packaging shell with high silicon carbide aluminum-base composites by semi-solid thixoforming

The electronic packaging shell with high silicon carbide aluminum-base composites was prepared by semi-solid thixoforming technique. The flow characteristic of the Si C particulate was analyzed. The microstructures of different parts of the shell were observed by scanning electron microscopy and optical microscopy, and the thermophysical and mechanical properties of the shell were tested. The results show that there exists the segregation phenomenon between the Si C particulate and the liquid phase during thixoforming, the liquid phase flows from the shell, and the Si C particles accumulate at the bottom of the shell. The volume fraction of Si C decreases gradually from the bottom to the walls. Accordingly, the thermal conductivities of bottom center and walls are 178 and 164 W·m-1·K-1, the coefficients of thermal expansion（CTE） are 8.2×10-6 and 12.6×10-6 K-1, respectively. The flexural strength decreases slightly from 437 to 347 MPa. The microstructures and properties of the shell show gradient distribution.     

大豆蛋白改性维纶纤维的电学性质研究

为了降低大豆蛋白改性维纶纤维在纺纱过程中的静电现象,通过测试不同温湿度状态下的大豆蛋白改性维纶纤维的比电阻,对大豆蛋白改性维纶纤维的质量比电阻与温湿度条件间的关系进行实验研究。实验结果表明,大豆蛋白改性维纶纤维和普通维纶纤维的质量比电阻随着相对湿度和温度的升高而降低;大豆蛋白改性维纶纤维和普通维纶纤维的质量比电阻对数,随着相对湿度和温度的升高而降低,而且相对湿度在60%以上及温度在30℃以内时,大豆蛋白改性维纶纤维的质量比电阻及质量比电阻对数低于普通维纶纤维,降低程度较明显。因此,适当提高温湿度条件,可以使纤维纺纱时的静电问题得到控制。该研究为大豆蛋白纤维纺织生产提供了理论依据。     

玄武岩纤维布加固框架结构抗震性能数值分析

利用玄武岩纤维布对九层框架的粱柱节点进行了加固,运用ANSYS有限元分析软件对不同加固方案下结构的整体抗震性能进行了动力分析．分析结果表明,在玄武岩纤维布用料相同的条件下,局部加固框架的角柱节点比边柱节点更有助于提高框架结构的抗震能力,且在地震作用下。采取整体加固的方案更有助于提高框架结构的安全性．     

活性炭纤维对凝结水中 Fe3＋的吸附研究

通过静态吸附和动态吸附实验,考察了活性炭纤维（ ACF）对Fe3＋的吸附性能,研究了不同实验条件下的动态吸附穿透曲线;通过扫描电镜,观察了吸附前后ACF的表面形貌。结果表明：ACF对Fe3＋的吸附既有物理吸附又有化学吸附;随着ACF比表面积增大或吸附溶液温度升高,对Fe3＋的吸附容量增大;动态吸附时,当流速为10 mL／min,最有利于出水达标。     

氯化锂对纤维素/离子液体浓溶液纺丝的影响

以离子液体1-烯丙基-3-甲基咪唑氯盐（[AMIM]Cl）为溶剂、氯化锂（LiCl）为添加剂,通过测定纤维素溶液的流变性能来考察LiCl对纤维素/[AMIM]Cl溶液纺丝性能的影响,发现纤维素/[AMIM]Cl/LiCl呈现切力变稀行为,当LiCl添加量为[AMIM]Cl质量的3%时,切力变稀行为最明显.使用双螺杆挤出机通过干湿法纺丝制备出了高浓度的纤维素纤维,通过XRD、偏光显微镜、SEM及单纤强力仪等表征了纤维的结构与性能,结果表明随着LiCl含量的增加,所得纤维的结晶度和双折射率增加,结构致密,纤维强度增加,当LiCl含量达3%时,纤维强度可达3.13 cN/dtex.     

麻赛尔/涤纶交织针织物服用性能的研究

根据麻赛尔纱线的特点,利用其与涤纶交织开发针织面料,对麻赛尔/涤纶交织针织物的透气性、透湿性、水洗尺寸变化、起毛起球性、硬挺度以及顶破强力进行了测试和分析,并利用模糊综合评价系统对3种试样的服用性能作了综合评价,结果显示麻赛尔与涤纶合理地进行交织时具有较好的服用性能.     

咖啡纤维结构与性能研究

介绍了咖啡纤维的生产过程和物理性能,通过红外光谱仪、X射线粉末衍射仪和扫描电子显微镜研究了咖啡纤维的亲水基团、吸湿性、结晶度和形态结构等,并与棉纤维和麻纤维进行了对比,证明了咖啡纤维的可纺性,有利于咖啡纤维的进一步开发和利用.     

废旧棉纺织品机械拉毛法回收纤维实验研究

废旧纺织品回收再利用是解决全球环境和资源问题的一种方法,机械拉毛法回收再利用废旧纺织品是使回收和再生变为现实的一种简单可行的方法.自制拉毛简易装置,经实验研究发现,在对废旧棉纺织品使用拉毛法回收纤维时,其排列间隔、钉子露出长度和钉子尺寸等对拉毛效果有一定的影响.