中国纳米碳酸钙工业生产现状及应用

介绍了纳米碳酸钙的理化性能,分析了中国纳米碳酸钙生产现状及发展趋势,同时对纳米碳酸钙在精细化工中的应用作了概述。     

尖晶石型纳米钴蓝陶瓷颜料的制备

采用化学共沉淀法作为钴蓝颜料的制备方法,探讨了主要工艺因素对制备钴蓝颜料性能的影响,对制备的样品进行了测试与表征。结果表明:Co2+和Al3+物质的量比为1∶2.5时,制备的钴蓝样品颜色饱和度与明度最高,沉淀剂为尿素时制得的样品的粒度最小,粒度分布比较均匀。前驱体的洗涤过程采取水洗加醇洗的方法可有效减少样品的硬团聚现象,且前驱体的最佳煅烧温度为950℃左右。     

Microstructure of Nano-Y203／Cobalt Based ,Alloy Composite Coating byLaser Cladding

Composite coatings made of nano-Y203/cobalt-based alloy and produced by crosscurrent CO2 laser on Ni-based superalloy are introduced. Cross-section or surface of the coatings was examined to reveal their microstructure using optical microscope, SEM, including EDS microanalysis, TEM and XRD. The results show that some equilibrium or non-equilibrium phases, such as γ-C0, Cr23C6, Y203 and ε-Co exist in the coatings. Fine and short dendritic microstructure andcolumnar to equiaxed transition (CET) occurred by adding nano-Y203 particles. With the increasing amount of nano-Y203(1%, mass fraction), fully equiaxed crystallization appeared. These are caused by nano-Y203 particles acting as new nucleation site and rapid solidification of the melt. The results also show that inhomogeneous dispersion of nano-Y203 resultsin the formation of ε-Co phase in the coatings. The sub-microstructure of the clad is stacking fault. The mechanism of theformation of equiaxed grains is also analyzed.     

稀土在光催化方面的应用

1972年日本Fujishima和Honda报道了TiO2电极上光电解水现象后，半导体光催化研究引起了国际化学、物理、材料等领域科学家的广泛关注。在纳米半导体TiO2制备、结构以及光催化理论等方面进行了尤为深入的研究，近5年光催化水分解功能提高了100倍，发现TiO2在环境保护和新能源开发方面具有广阔的应用前景，将成为下半世纪利用太阳能净化环境和开发新能源的最有效方法之一。     

单壁纳米碳管/纳米铝基复合材料的增强效果

用半连续氢电弧法和活性氢等离子蒸发法分别制备出单壁纳米碳管(SWNTs)和纳米A1粉体，然后用提纯后的SWNTs和纳米A1粉体制备出SWNTs含量(质量分数)分别为0、2．5％、5．0％、7．5％和10.0％的单壁纳米碳管／纳米铝基块体复合材料．SWNTs对高强度纳米A1基体具有显著的增强作用，当SWNTs含量小于5．0％时，材料的硬度随着SWNTs含量的提高线性上升．其中5％SWNTs和纳米A1的复合增强效果最好，其硬度可达2.89GPa，大约是粗晶A1(0．15GPa)的20倍．当SWNTs含量超过5．0％时，增强效果开始缓慢的下降．讨论了单壁纳米碳管增强纳米铝基复合材料的强化机制．     

Study on Adsorption Behavior of Rare Earth Complexes on Nanometer-Size Titanium Dioxide with ICP-AES

Inrecentyears ,rareearthelements (REEs)havebeenwidelyusedinfunctionalmaterials ,cata lystsandotherproductsinindustry ,diagnosisreagentsofmagneticresonanceimaging (MRI)inmedicineandsomefertilizersinagricultureespeciallyinChina .However,asaresultoftheirusage ,moreandmoreREEsaregettingintotheenvironment,andalsointohumanbodyviafoodchain[1,2 ] .Itisnotclearwhetherrareearthelementsareessentialforman ,soitisveryurgenttostudythebiologicaleffectofrareearthelementsinhumanhealthandenvironment .Inthes…     

我国纳米科技的现状与展望

本文概述了纳米科技的沿革，及其在国内外发展的情况，并就我国如何进一步发展纳米科技提出了自己的想法。     

小型微/纳米级三坐标测量机的研制

介绍一套低成本小型三维坐标测量机的研制过程，作为微/纳米级超精密测量设备，整体机台结构采用花岗岩材料；X／Y轴的移动平台利用压电材料摩擦驱动与挠性变形原理，长短两行程可达25mm范围及5nm的微位移，藉自行研发的衍射干涉激光尺，位置回馈测量系统可具有0．025nm的分辨率；测量探头在一般DVD光读取头的自动聚焦原理基础上改装，最佳分辨率可达2．5nm，该雏形机适于测量微机电组件、微型器件及膜厚等。