In—situ Composite Based on Poly （ethylene terephthalate）,Polyamide and Polyethylene with Microfibres Formed through Extrusion and Hot Stretching

In-situ composites based on dispersed poly (ethylene terephthalate) (PET) or polyamide (PA),and continuous Polyethylene (PE) were prepared through a single screw extruder of Haake rheometer system with a rod-die relatively small in diameter.The extrudate was drawn at a drawing ratio of 3.1,and then quickly cooled in cold water.The specimens were obtained by injection molding at processing temperatures less than 190℃，far below the melting temperature of PET (265℃) and PA (230℃),which can maintain the solid state of PET and PA microfiber phase in the composites.Morphological observation with scanning electron microscopy (SEM) indicated that PET and PA can more or less form in-situ microfibers at compositions studied (0-20 wt pct PET or PA),and especially,PET and PA were almost deformed into fibers at the concentration of 15wt pct.Eensile strength and especially.PET and PA were almost deformed into fibers at the concentration of 15wt pct.Tensile strength and modulus of the blends reinforced by PET or PA microfibers showed to be increased from the tensile test results.The most noticeable improvement of the tensile properties occurred at 15wt pct of PET in PET/PE system,corresponding to the highest microfiber content,where the tensile strength reached 32.5 MPa,whereas only 19.5 MPa for the pure PE.     

氨荒酸盐抑制铜在NaCl溶液中腐蚀的电化学研究

通过电化学极化曲线和失重实验,研究了氨荒酸盐对铜在氯化钠溶液中的缓蚀性能,并与相应胺的缓蚀性能进行了对比。结果表明:氨荒酸盐对铜具有较好的缓蚀性能。     

尿素对以硝酸铝和葡萄糖为原料合成氮化铝粉末反应过程中相变及反应速率的影响

以硝酸铝(Al(NO3)3·9H2O)和葡萄糖(C6H12O6·H2O)为原料,利用碳热还原法制备氮化铝粉末,研究了尿素对前驱物的制备及前驱物氮化反应的影响,研究发现添加尿素合成的前驱物和未添加尿素合成的前驱物在氮化反应过程中相变和反应速率存在较大差异。在没有添加尿素合成的前驱物的氮化反应过程中,出现了γ-Al2O3、α-Al2O3、AlON和AIN相,该前驱物的反应速率慢,完全氮化需要在1600℃下才能完成。对于添加尿素合成的前驱物而言,在其氮化反应过程中仅出现了γ-Al2O3和AIN相,没有α-Al2O3和AlON的生成,AIN直接由γ-Al2O3氮化生成,该前驱物的氮化反应速率快,氮化反应温度低,在1400℃下即可实现完全氮化。分析讨论了两种前驱物的氮化反应速率不同的主要原因,并利用XRD、SEM等分析方法对粉末进行了表征。     

Ce3+离子对掺Er3+碲酸盐玻璃光谱性质的影响

研究了Ce3 + 对掺Er碲酸盐玻璃荧光光谱性质的影响 ,比较了不同的Ce3 + 掺杂浓度下Er3 + 离子荧光发光强度的变化 ,分析了Ce3 + 离子对Er3 + 离子作用的原理 ,应用经典方程计算了Er3 + 离子 4I1 1 / 2 能级的荧光寿命及其变化     

OCA99的吸附行为及其浓度测定

OCA99是一种锌酸盐镀锌的添加剂,由美国Udylite公司引进的产品,它包括辅助光亮剂OCA991和主光亮剂0CA992。本文通过测定微分电容曲线和极谱曲线研究它们的吸附行为和电化学氧化还原性。根据实验结果,提出控电位微分电容法测定OCA992浓度的方法。     

升频转换光纤激光器产生可见光输出

德国Lumics GmbH公司开发出一种基于升频转换氟锆酸盐(ZBLAN)光纤激光器(发射谱线可与氩离子激光器的谱线相媲美)的可见波长光源，这种光源利用氟化物玻璃中稀土离子的吸收，将红外光辐射转换成可见光。     

腐植酸盐同常用水处理剂复合用于氨冷循环水系统

邯郸钢铁总厂化肥厂尿索车间氨气冷却器材质为1Cr18Ni9Ti,封头为A_3钢,φ2.5mm管道为铁质。氨冷循环水系统的循环水量为1200吨/时,循环冷却水一直未进行水处理。由于水质硬度较高,因此结垢严重,运行一年垢层厚达2～2.5mm,凉水塔上结垢更严重,可达3mm,严重降低冷却效率。为了除垢,每30天就需酸洗一次,除酸耗外,每酸洗一次还要少产尿素80吨。近两年来,