全文获取类型
收费全文 | 5422篇 |
免费 | 322篇 |
国内免费 | 414篇 |
专业分类
电工技术 | 71篇 |
综合类 | 167篇 |
化学工业 | 1931篇 |
金属工艺 | 188篇 |
机械仪表 | 82篇 |
建筑科学 | 81篇 |
矿业工程 | 22篇 |
能源动力 | 240篇 |
轻工业 | 900篇 |
水利工程 | 4篇 |
石油天然气 | 111篇 |
武器工业 | 10篇 |
无线电 | 472篇 |
一般工业技术 | 747篇 |
冶金工业 | 64篇 |
原子能技术 | 1039篇 |
自动化技术 | 29篇 |
出版年
2024年 | 12篇 |
2023年 | 77篇 |
2022年 | 112篇 |
2021年 | 188篇 |
2020年 | 127篇 |
2019年 | 133篇 |
2018年 | 158篇 |
2017年 | 175篇 |
2016年 | 202篇 |
2015年 | 171篇 |
2014年 | 232篇 |
2013年 | 526篇 |
2012年 | 289篇 |
2011年 | 454篇 |
2010年 | 314篇 |
2009年 | 334篇 |
2008年 | 266篇 |
2007年 | 327篇 |
2006年 | 326篇 |
2005年 | 253篇 |
2004年 | 221篇 |
2003年 | 222篇 |
2002年 | 144篇 |
2001年 | 136篇 |
2000年 | 111篇 |
1999年 | 86篇 |
1998年 | 83篇 |
1997年 | 66篇 |
1996年 | 45篇 |
1995年 | 70篇 |
1994年 | 43篇 |
1993年 | 43篇 |
1992年 | 52篇 |
1991年 | 26篇 |
1990年 | 32篇 |
1989年 | 20篇 |
1988年 | 23篇 |
1987年 | 11篇 |
1986年 | 12篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1959年 | 5篇 |
排序方式: 共有6158条查询结果,搜索用时 4 毫秒
31.
D. Peruško J. Kovač S. Petrović M. Obradović M. Mitrić V. Pavlović 《Materials and Manufacturing Processes》2017,32(14):1622-1627
Multilayers consisting of five (Al/Ti) bilayers were deposited on (100) silicon wafers. On top was deposited the Ti layer, aimed at preventing Al from diffusing to the surface upon laser treatment. The total thickness of the thin-film structure was 200?nm. Laser irradiations with Nd:YAG picoseconds laser pulses in the defocused regime were performed in air. Laser beam energy was 4?mJ and laser spot diameter on the sample surface was 3?mm (fluence 0.057?J?cm?2). The samples were treated with different numbers of laser pulses. Structural characterizations were performed by different analytical methods and nano-hardness was also measured. Laser processing induced layer intermixing, formation of titanium aluminides, oxidation of the surface titanium layer and enhanced surface roughness. Aluminum appears at the sample surface only for the highest density of laser irradiation. Laser processing induces increment of nano-hardness by approximately 20% and decrease of residual Young’s modulus for a few percentages from the starting value of the untreated samples. These results can be interesting toward achieving structures with a selective extent of Al-Ti reactivity in this multilayered system, within the development of biocompatible materials. 相似文献
32.
采用微波辐照法制备了以聚氯乙烯(PVC)为骨架,邻苯二甲酸二烯丙酯(DAP)为支链的接枝聚合物PVC-g-DAP。通过红外光谱、差示扫描量热分析对聚合物的结构进行了表征,同时对聚合物的流变性能、耐热性和力学性能进行了测试分析。结果表明,DAP在微波辐照下成功接枝到PVC大分子链上,PVC-g-DAP聚合物只有1个Tg,且略高于PVC。PVC-g-DAP聚合物的流变性能较PVC有大幅度改善,同时力学性能、耐热性得到提升。 相似文献
33.
研究了室温空气条件下电子束辐照剂量(范围0~1000 k Gy)对尼龙66纤维结构和力学性能的影响。利用广角X射线衍射仪、差示扫描量热仪、扫描电镜以及YG065型织物强力仪等测试方法研究了不同辐照剂量尼龙66的特性黏数、晶型结构、取向度、结晶和熔融行为,以及表面形貌和力学性能。研究结果表明,在设置的辐照剂量范围内,随着剂量的增加,纤维原有的晶型结构不变,但是,伴随辐照诱导非晶区分子链的重排,纤维的结晶度提高,取向有所改善,而结晶和熔融温度向低温偏移,熔融峰出现宽化。说明辐照主要导致尼龙66分子链氧化降解,降低其热稳定性,在电子束的撞击下,纤维表面产生了微裂纹,增加了应力集中,破坏了纤维的力学性能。 相似文献
34.
Jinlong Du Zaoming Wu Yanxiang Liang Xingjun Wang Peipei Wang 《Science and Technology of Advanced Materials》2018,19(1):212-220
The mechanism of radiation-induced detwinning is different from that of deformation detwinning as the former is dominated by supersaturated radiation-induced defects while the latter is usually triggered by global stress. In situ Kr ion irradiation was performed to study the detwinning mechanism of nanotwinned Cu films with various twin thicknesses. Two types of incoherent twin boundaries (ITBs), so-called fixed ITBs and free ITBs, are characterized based on their structural features, and the difference in their migration behavior is investigated. It is observed that detwinning during radiation is attributed to the frequent migration of free ITBs, while the migration of fixed ITBs is absent. Statistics shows that the migration distance of free ITBs is thickness and dose dependent. Potential migration mechanisms are discussed. 相似文献
35.
Han‐Wen Cheng Jie Wang Jing Li Shan Yan Shiyao Shan Lingyan Wang Chuan‐Jian Zhong 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(20)
The ability to harness the optical or electrical properties of nanoscale particles depends on their assembly in terms of size and spatial characteristics which remains challenging due to lack of size focusing. Electrons provide a clean and focusing agent to initiate the assembly of nanoclusters or nanoparticles. Here an intriguing route is demonstrated to lace gold nanoclusters and nanoparticles in string assembly through electron‐initiated nucleation and aggregative growth of Au(I)‐thiolate motifs on a thin film substrate. This size‐focused assembly is demonstrated by controlling the electron dose under transmission electron microscopic imaging conditions. The Au(I)‐thiolate motifs, in combination with the molecularly mediated alignment, facilitate the interstring electrostatic and intrastring aurophilic interactions, which functions as a molecular template to aid electron‐initiated 1D lacing. The findings demonstrate a hierarchical route for the 1D assemblies with size and spatial tunable catalytic, optical, sensing, and diagnostic properties. 相似文献
36.
W. P. Ponce J. L. Nation T. C. Emmel B. J. Smittle P. E. A. Teal 《Journal of chemical ecology》1993,19(12):3045-3056
Pheromonal volatiles emitted by irradiated and control 5- to 11-day-old Caribbean fruit flies,Anastrepha suspensa (Loew), were collected on Tenax adsorbent filters and quantified by gas chromatography (GC). The components released were identified by comparison of retention times on GC and by mass spectrometry (MS) with authentic synthetic standards. Pharate adults were irradiated with gamma rays from a60Co source at a dose rate of 10.3 Gray (Gy)/min. The total dosages given were 30, 50, 70, and 100 Gy. Pheromone volatiles were collected from adult males when they were between 5 and 11 days of age. The compounds quantified were (Z)-3-nonenol and (Z, Z)-3,6-nonadienol, which eluted from the GC column together and were quantified as one peak,-bisabolene, suspensolide, anastrephin, and epianastrephin. Irradiation with 30 Gy did not significantly reduce any pheromonal components, nor did it change the pheromonal blend. In contrast, suspensolide and bisabolene were significantly reduced in flies irradiated with 50 Gy, while the nonenols and epianastrephin were reduced at the 70-Gy dose. Irradiation with the 100-Gy dose reduced all components with the exception of suspensolide.University of Florida Agric. Exper. Sta. Journal Series No.R-03156. 相似文献
37.
38.
采用微波法制备了交联壳聚糖,与活性炭复配得到复合吸附剂,并研究其对水中卤化物的吸附效果。结果表明,微波法制备复合交联壳聚糖吸附剂简化了制备工艺,且吸附效果较好。 相似文献
39.
将稀土固体超强酸与微波辐射技术相结合研究蔗糖酯的合成,考察了微波辐射功率、反应时间、催化剂、乳化剂对反应的影响。结果表明,当辐射功率为390W、反应时问为20min时,稀土固体超强酸Gd^3+(Y^3+)-SO4^2-/ZrO2对合成蔗糖酯的催化活性优于常规催化剂无水碳酸钾。并且微波辐射使反应时间从传统减压加热4~8h缩短到常压反应20min。 相似文献
40.
Shengying Li Wu Yang Miao Chen Jinzhang Gao Jingwan Kang Youli Qi 《Materials Chemistry and Physics》2005,90(2-3):262-269
Nanosized lead oxide particles were prepared by thermal decomposition of lead hydroxycarbonate synthesized under microwave irradiation. Urea and lead nitrate were used as the starting materials. Microstructure and morphology of the products were investigated by means of XRD, AFM, TEM, and IR absorption spectra. The results indicated that well crystallized, finely dispersed and spherical -PbO nanoparticles with a size of ca. 30 nm were obtained. Meanwhile, an orthogonal phase β-PbO with a size of ca. 38 nm was also obtained when the calcinations temperature was up to 600 °C. In addition, a Pb(II)-selective electrode based on cellulose acetate was prepared using nanosized -PbO powders synthesized. The electrode exhibited a Nernstian slope of 29±1 mV per decade in a linear range of 2.5×10−5 mol L−1 to 1.0×10−1 mol L−1 for Pb2+ ion. The detection limit of this electrode is down to 8.0×10−6 mol L−1. This sensor has a short response time of about 10 s and could be used in a pH range of 2.0–8.0. High selectivity was obtained over a wide variety of metal ions. 相似文献