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101.
根据生产实践 ,结合PLC的技术特点和 385m2 凯利式叶滤机的电气联锁特性 ,阐述了应用PLC技术 ,可进一步提高 385m2 凯利式叶滤机的运转率和自动化水平。 相似文献
102.
F.A. Rodrigues 《Cement and Concrete Research》2003,33(6):823-827
This paper describes the synthesis of cements, chemically and structurally related to Ca2SiO4. Silica was obtained from rice hull after heating at 600 °C. Calcium oxide and small amounts of barium chloride were mixed in order to obtain a final (Ca/Si) or (Ca+Ba)/Si ratio equal to 1.95, 1.90, and 1.80, which is lower than in the conventional cement. The solids were mixed and ultrasonically treated for 1 h with a water/solid ratio of about 20. After drying and grinding, the mixtures were heated up to 1100 °C. It was possible, in some cases, to obtain a cementitious material. These cements are structurally related to β-Ca2SiO4 and the lower (Ca+Ba)/Si ratio obtained was 1.95. The initial chemical compositions of these cements are: (Ca1.83+Ba0.12)SiO4 and (Ca1.79+Ba0.16)SiO4. A further lowering in the (Ca+Ba)/Si ratio changes the nature of the silicates. 相似文献
103.
MoSi2-based intermetallics containing different volume fractions of MoB or Mo5Si3 were fabricated by hot-pressing MoSi2, MoB, and Mo5Si3 powders in vacuum. Both classes of alloys contained approximately 5 vol.% of dispersed silica phase. Additions of MoB or Mo5Si3 caused the average grain size to decrease. The decrease in the grain size was typically accompanied by an increase in flexure strength, a decrease in the room temperature fracture toughness, and a decrease in the hot strength (compressive creep strength) measured around 1200 °C, except when the Mo5Si3 effectively became the major phase. Oxidation measurements on the two classes of alloys were carried out in air. Both classes of alloys were protected from oxidation by an in-situ adherent scale that formed on exposure to high temperature. The scale, although not analyzed in detail, is commonly recognized in MoSi2 containing materials as consisting mostly of SiO2. The MoB containing materials showed an increase in the scale thickness and the cyclic oxidation rate at 1400 °C when compared with pure MoSi2. However, in contrast with the pure MoSi2 material, oxidation at 1400 °C began with a weight loss followed by a weight gain and the formation of the protective silica layer. The Mo5Si3 containing materials experienced substantial initial weight losses followed by regions of small weight changes. Overall, the MoB and Mo5Si3 additions to MoSi2 tended to be detrimental for the mechanical and oxidative properties. 相似文献
104.
Five new salts based on 1-alkyl-2-methyl pyrrolinium ion are reported, two involving the iodide ion and three involving the bis(trifluoromethanesulfonyl) amide ion. The iodide salts have melting points around 100 °C, while the amide salts have melting points around room temperature. Two of the amide salts can be easily quenched into the glassy state and exhibit glass transition temperatures around −70 °C. The 2-methyl pyrrolinium cation bears structural similarities to the aromatic imidazolium cations on one hand and the cyclic ammonium cation family based on the pyrrolidinium cation on the other. The properties of the salts reported here are compared within these two related families of salts. 相似文献
105.
106.
On the basis of new concept using a solid disperse phase we have developed an efficient catalytic solid-phase-system for epoxidations of alkenes using urea–hydrogen peroxide (urea–H2O2) complex and cetylpyridinium dodecatungstate ((CetylPy)10[H2W12O42]) catalyst on fluorapatite (FAp). The recovered solid catalyst phase was reused to keep the catalytic activity after several times. In the conceptual idea it is a key point that in situ solid-phase-activation of the catalyst with urea–H2O2 proceeds to form microcrystals of the active species dispersed on the solid phase. The dispersion of the catalyst on FAp in the case of tungstic acid (H2WO4) was suggested by EPMA analysis. We proposed the peroxo type of species keeping the parent polyoxometalate framework as novel active species from FT-IR spectroscopic studies. FAp phase plays important roles of dispersing the active species on its surface to have high catalytic activity and of stabilizing the active species to lead to high reusability. 相似文献
107.
Alleviation Effect of Lanthanum on Cadmium Stress in Seedling Hydroponic Culture of Kidney Bean and Corn 总被引:4,自引:0,他引:4
Since1970s,rare earths(RE)have been exten-sively used as micro-fertilizers for crops in China.Ithas already been proved that REcani mprove the pro-duction and quality of crops.However,there havebeen a fewinvestigations about using RE as regulatorin pollution ecology.For example,An et al[1]studiedthe effects of O3on wheat growth and the protectiveeffect of RE.Yan and Zhou et al[2,3]discussed theprotective effect of RE on plants under acid rainstress.Jia et al[4]and Hu et al[5]reported th… 相似文献
108.
As an alternative to previously developed catalytic FeCrAlloy fibre mat burners based on perovskite catalysts, new catalytic burners have been developed based on Pd catalyst on lantana-stabilised Al2O3 and different fibre structures (NIT100A, NIT100S and NIT200S by ACOTECH NV). All development steps are considered, shifting from catalyst preparation (based on combustion synthesis of γ-Al2O3) to the optimisation of lantana and Pd loadings, from the definitions of the best catalyst-deposition conditions (washcoating) to the catalytic burners performances, determined in an ad hoc developed combustion chamber. The results show almost half pollutants emissions and better performance compared to various non-catalytic counterparts, especially as far as CO and NOx emissions are concerned. Some flame instability problems were though registered, especially for one of the catalytic burner mattresses employed, at low specific power inputs and excesses of air (<375 kW/m2 and <12%, respectively). Further, PdO/Pd transition is shown to influence the dynamic behaviour of the catalytic burners. 相似文献
109.
The catalytic activity of fresh Pd and Pt catalysts supported on γ-alumina in the complete oxidation of CH4 traces under lean-burn conditions was studied in the presence or the absence of water or H2S. Steam-aged catalysts were also studied in order to simulate long-term ageing in real lean-burn natural gas fuelled vehicles (NGVs) exhaust conditions. Without water or H2S added to the feed, Pd catalysts exhibit a superior catalytic activity in methane oxidation compared to Pt ones, whatever the catalysts were fresh or aged. The addition of 10 vol.% water vapour to the feed strongly affects the activity of the fresh Pd catalyst, thus being only slightly more efficient than the fresh Pt one. H2S has a strong poisoning effect on the catalytic activity of Pd catalysts, while Pt catalysts are more resistant. The fresh H2S-poisoned Pd/Al2O3 catalyst was studied by TPD in O2/He. Poisoning species decompose above 873 K as SO2 and O2 in relative concentrations consistent with the decomposition of surface sulphate species. However, a treatment in O2/He at temperatures as high as 923 K does not allow the complete regeneration of the catalytic activity of H2S-poisoned Pd/Al2O3. A mechanism involving the poisoning of PdO by sulphate species is proposed. Different diffusion processes by which these sulphate species can migrate back and forth between PdO and the support, depending on the experimental conditions, are suggested. 相似文献
110.
In accord with the increasing concern about the global environmental issues, the absorption refrigeration heat-pump systems are currently being considered very promising and attractive. For the purpose of supporting the advanced R&D technology in this area, we have developed a novel correlation to represent the bubble-point pressures of LiBr H2O solutions. The developed correlation covers the most extensive range of validity ever proposed: 273–483 K for temperatures, 0.05 kPa to 1.0 MPa for pressures. and 29 76 wt% LiBr for concentrations.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994. Boulder, Colorado, U.S.A. 相似文献