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951.
正A simple method has been developed for the fabrication of a silicon microlens array with a 100%fill factor and a smooth configuration.The microlens array is fabricated by using the processes of photoresist(SU8- 2005) spin coating,thermal reflow,thermal treatment and reactive ion etching(RIE).First,a photoresist microlens array on a single-polished silicon substrate is fabricated by both thermal reflow and thermal treatment technologies. A typical microlens has a square bottom with size of 25μm,and the distance between every two adjacent microlenses is 5μm.Secondly,the photoresist microlens array is transferred to the silicon substrate by RIE to fabricate the silicon microlens array.Experimental results reveal that the silicon microlens array could be formed by adjusting the quantities of the reactive ion gases of SF_6 and O_2 to proper values.In this paper,the quantities of SF_6 and O_2 are 60 sccm and 50 sccm,respectively,the corresponding etch ratio of the photoresist and the silicon substrate is 1 to 1.44.The bottom size and height of a typical silicon microlens are 30.1μm and 3μm,respectively. The focal lengths of the microlenses ranged from 15.4 to 16.6μm. 相似文献
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954.
Generalized model for the simulation of food refrigeration. Development and validation of the predictive numerical method 总被引:1,自引:0,他引:1
A generalized mathematical model was developed to simulate food refrigeration in air. The model takes into account surface water evaporation. It allows food physical properties to be considered as functions of temperature and/or composition, while providing means for including internal heat generation, composite materials (for instance, flesh and skin) and time-varying external temperature and humidity. Wetted surfaces and packaging can also be accounted for by the model, which can be used for spheres, infinite or finite cylinders, slabs. The numerical method was developed using the Crank-Nicolson scheme, and compared with exact analytical solutions as well as with experimental data on the refrigeration of various foods. 相似文献
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957.
《Ceramics International》2022,48(17):24346-24354
The borided layer was prepared on the surface of the Ti–5Mo–5V–8Cr–3Al alloy by powder-pack boriding at 1000°C-10h. SEM, EPMA and TEM were used to investigate the effects of alloying elements (Al, V, Mo and Cr) on the growth of TiB whiskers in the borided Ti–5Mo–5V–8Cr–3Al alloy. Wear properties of borided Ti–5Mo–5V–8Cr–3Al alloy were investigated using dry reciprocating friction tests. SEM results show that the thickness of boride layer in Ti–5Mo–5V–8Cr–3Al alloy is thinner than that in the Cp-Ti. This is attributed to the enrichment of alloying elements especially V in TiB/substrate by TEM, which hinders the diffusion of B atoms, thus resulting in the short and thick TiB whiskers in Ti–5Mo–5V–8Cr–3Al alloy. Borided Ti–5Mo–5V–8Cr–3Al alloy has the better wear resistance than as-received alloy. 相似文献
958.
《International Journal of Hydrogen Energy》2022,47(56):23787-23796
Microbial electrosynthesis (MES) is an electrochemical reduction technology through which microorganisms attached to a cathode are driven by electricity to reduce carbon dioxide (CO2) into industrial chemicals. However, the limited contact time with biocatalysts affects the performance of MES because of low CO2 solubility. In this study, zeolitic imidazolate framework-8 (ZIF-8) particles with different pore diameters modified cathodes were prepared. Results showed that the ZIF-8 modified electrode obtained the maximum acetate production rate (0.13 g L?1 d?1), which was 1.4 times that of bare CF, and the accumulated acetate concentration reached 4.04 ± 0.1 g L?1 within 30 days. Brunauer–Emmett–Teller test and CO2 adsorption characteristic evaluation indicated that ZIF-8 had a high specific surface area and an excellent CO2 adsorption capacity. Scanning electron microscopy and microbial community analysis revealed that ZIF-8 modified electrodes were beneficial to biofilm formation and increased the enrichment of Acetobacterium and Arcobacter. Therefore, CO2-adsorbing materials modified electrodes are effective in improving the performance of MES. 相似文献
959.
Wei-Fei Hu Shuo Chen Hong-Chao Hao Hong Jiang 《American Institute of Chemical Engineers》2022,68(11):e17879
Herein, we propose a novel method to enhance the photoreactivity of an MOF catalyst by grafting isocyanate bonds ( NCO) and sulfhydryl-complexed copper ( SCu) onto ZIF-8 (NIF-SCu). The grafting process intercalated interlayer bands between the conduction and valence bands of ZIF-8, thereby providing a “ladder” for facile electron transition. The extreme improvement in the photoreactivity of NIF-SCu could be attributed to the enhancement in light responses in the range of 350–450 nm by NCO groups and the widening of the visible light range of the MOF by SCu groups. The formation of staggered energy levels in NIF-SCu could also narrow the band gap, lower the resistance, and facilitate the transfer of photogenerated carriers, thereby generating electrons with strong reduction potential in the SCu conduction band. This study provides a new strategy for improving or even endowing the photoactivity of environmental functional materials with wide bandgaps. 相似文献
960.
《Ceramics International》2022,48(2):2377-2384
Bi2O3, Y2O3 and MgO co-doped BaTiO3 (BT)-based X8R ceramics were synthesized successfully for the first time. The effects of the sintering temperature and Bi2O3, Y2O3 and MgO dopants on the dielectric properties were investigated systematically. Bi2O3 doping can increase the Curie temperature (Tc), but reduces the overall dielectric permittivity. On the other hand, Y2O3 doping is beneficial to the formation of core-shell microstructure and the increase of Tc, whereas MgO can prevent excessive Y2O3 from diffusing into grain core, and thereby further contributes to the generation of the core–shell microstructure. The generation of the typical core-shell microstructure was confirmed and investigated in detail by using transmission electron microscopy (TEM). It is argued that the synergistic effects of Bi2O3, Y2O3 and MgO co-doping in terms of the formation of the core-shell structure and the increase of Tc, can help improve the temperature stability of the dielectric permittivity effectively. Increasing the sintering temperature leads to an increase in the grain size, which in turn leads to an increase in the overall dielectric permittivity due to the grain size effect. 相似文献