Comparison of co-current and counter-current flow in a bifunctional reactor containing ammonia synthesis and 2-butanol dehydrogenation to MEK

In this study, a multi-tubular thermally coupled packed bed reactor in which simultaneous production of ammonia and methyl ethyl ketone (MEK) takes place is simulated. The simulation results are presented in two co-current and counter-current flow modes. Based on this new configuration, the released heat from the ammonia synthesis reaction as an extremely exothermic reaction in the inner tube is employed to supply the required heat for the endothermic 2-butanol dehydrogenation reaction in the outer tube. On the other hand, MEK and hydrogen are produced by the dehydrogenation reaction of 2-butanol in the endothermic side, and the produced hydrogen is used to supply a part of the ammonia synthesis feed in the exothermic side. Thus, 30.72% and 31.88% of the required hydrogen for the ammonia synthesis are provided by the dehydrogenation reaction in the co-current and counter-current configurations, respectively. Also, according to the thermal coupling, the required cooler and furnace for the ammonia synthesis and 2-butanol dehydrogenation conventional plants are eliminated, respectively. As a result, operational costs, energy consumption and furnace emissions are considerably decreased. Finally, a sensitivity analysis and optimization are applied to study the effect of the main process parameters variation on the system performance and obtain the minimum hydrogen make-up flow rate, respectively.     

A new numerical algorithm to check the observability and bad-data processing ability of the metering scheme

This paper provides a unified approach for the optimization of measurements placements employed for power system online monitoring through state estimation. The proposed methodology, which can be suitable for the mixed measure system, preserves state estimation observability and bad-data processing capability by employing numerical algorithms for observability checking, critical measurements and critical couple identification. First, node injection radix measurements and measurement categories are defined. According to the above definitions, the coefficient matrix can be solved. The analysis on the column vectors of the coefficient matrix can determine each measurement classification. Furthermore, the numbers of each measurement class contains can determine bad-data processing capability. The observability can be checked by the type number of measurements. The proposed method is illustrated with the IEEE39-bus system and the IEEE118-bus system. Results from the case studies are presented to demonstrate that the approach adequately fulfills the desired properties related to observability, bad-data processing, cost, and robustness.     

基于三维胞元空间的MA双向并行路由算法

针对传统移动代理(MA)在监测无线传感器网络(WSNs)的感兴趣信息时产生的延迟较大和能耗较多问题,提出了基于三维胞元空间的MA双向并行(3D-BPMA)路由算法.3D-BPMA将MA与传统的客户/服务器(c/S)模式相结合,在胞元内利用C/S模式搜集信息,在单层胞元系统和路由器与路由器之间采用MA双向并行的策略进行传输.仿真结果表明:3D-BPMA与LCF,DSG-MIP算法相比减少了平均响应时间和网络平均能耗,提高了MA发送率.     

浅谈枪支(弹药)库室电子技防测试

一个完整枪支(弹药)库室的安全防范由管理要求、物防要求、技防要求及人防要求完美的结合而成,其中技防要求是需要根据枪支(弹药)库室现场实体情况采取的一项电子技术手段,是起到安全预报警的最佳方式。本文就枪支(弹药)库室安全防范在技防要求方面按现行GA 1016-2012标准在检测中存在的问题做一些探讨、建议,以期为需要枪支(弹药)库室的建设单位、施工单位提供参考。     

Reduction of waste biosolids by RAS-ozonation: Model validation and sensitivity analysis for biosolids reduction and nitrification

Biosolids reduction model by return activated sludge ozonation was validated by simulating nitrification data compiled from our pilot-scale and the literature studies. Then, a global sensitivity analysis (GSA) was performed to identify influential and non-influential parameters for biosolids reduction efficiency, change in specific nitrification activity (SNA), and alteration to expected nitrification stability. In general, the model outputs were sensitive to operational and ozone reaction parameters, but not to biochemical parameters. For operational parameters, mainly temperature and initial solids retention time (SRT) influenced all model outputs. For biosolids reduction, increase in the degradability of the influent COD decreased the reduction efficiency. For SNA, the changes were highly dependent on the influent TKN/COD ratio. Our findings also imply that the stability of the nitrification process in ozonated systems should be enhanced at constant MLVSS for warm temperatures, but could be reduced at temperatures below 12 °C and aerated SRTs below 10 days.     

Molecular structure and granule morphology of native and heat‐moisture‐treated pinhão starch

Pinhão seed is an unconventional source of starch and the pines grow up in native forests of southern Latin America. In this study, pinhão starch was adjusted at 15, 20 and 25% moisture content and heated to 100, 110 and 120 °C for 1 h. A decrease in λ max (starch/iodine complex) was observed as a result of increase in temperature and moisture content of HMT. The ratio of crystalline to amorphous phase in pinhão starch was determined via Fourier transform infra red by taking 1045/1022 band ratio. A decrease in crystallinity occurred as a result of HMT. Polarised light microscopy indicated a loss of birefringence of starch granules under 120 °C at 25% moisture content. Granule size distribution was further confirmed via scanning electron microscopy which showed the HMT effects. These results increased the understanding on molecular and structural properties of HMT pinhão starch and broadened its food and nonfood industrial applications.     

Effect of gums on viability and β‐galactosidase activity of Lactobacillus spp. in milk drink during refrigerated storage

The viability and β‐galactosidase activity of four Lactobacillus strains in milk drink containing gums during 28 days of refrigerated storage at 4 °C were assessed. The population of Lactobacillus rhamnosus GGB101 and Lactobacillus rhamnosus GGB103 were maintained, whereas the population of Lactobacillus reuteri DSM20016 and Lactobacillus reuteri SD2112 significantly decreased. The recommended level of 6 log CFU g^?1 was exceeded for all tested trains throughout storage. The highest viable number of Lactobacillus rhamnosus GGB103 (8.76 ± 0.03 log CFU mL^?1) was obtained in the product containing carrageenan–maltodextrin. The addition of guar–locust bean–carrageenan led to 20‐fold increase in the level of β‐galactosidase activity for L. rhamnosus GGB101 (1208 ± 2.12 Miller units mL^?1) compared to the control (61 ± 2.83 Miller units mL^?1). Our results suggested that gums could be added to milk to improve viability and enhance β‐galactosidase activity of Lactobacillus.     

Optimized PI+ load–frequency controller using BWNN approach for an interconnected reheat power system with RFB and hydrogen electrolyser units

This paper investigates a renewable energy resource’s application to the Load–Frequency Control of interconnected power system. The Proportional-Integral (PI) controllers are replaced with Proportional-Integral Plus (PI+) controllers in a two area interconnected thermal power system without/with the fast acting energy storage devices and are designed based on Control Performance Standards (CPS) using conventional/Beta Wavelet Neural Network (BWNN) approaches. The energy storing devices Hydrogen generative Aqua Electroliser (HAE) with Fuel cell and Redox Flow Battery (RFB) are incorporated to the two area interconnected thermal power system to efficiently damp out the electromechanical oscillations in the power system because of their inherent efficient storage capacity in addition to the kinetic energy of the generator rotor, which can share the sudden changes in power requirements. The system was simulated and the frequency deviations in area 1 and area 2 and tie-line power deviations for 5% step- load disturbance in area 1 are obtained. The comparison of frequency deviations and tie-line power deviations of the two area interconnected thermal power system with HAE and RFB designed with BWNN controller reveals that the PI+ controller designed using BWNN approach is found to be superior than that of output response obtained using PI+ controller. Moreover the BWNN based PI+ controller exhibits a better transient and steady state response for the interconnected power system with Hydrogen generative Aqua Electroliser (AE) unit than that of the system with Redox Flow Battery (RFB) unit.