Development and simulation studies of an unsteady state biofilter model for the treatment of cyclic air emissions of an α‐pinene gas stream

This paper describes the development and simulation of an unsteady state biofilter model used to predict dynamic behaviour of cyclically‐operated biofilters and compares it with experimental results obtained from three, parallel, bench‐scale biofilters treating both periodically fluctuating concentrations and constant concentrations of an α‐pinene‐laden gas stream. The dynamic model, using kinetic parameters estimated from the constant concentration biofilter, was able to predict the performance of cyclic biofilters operating at short cycle periods (ie, in the order of minutes and hours). Steady state kinetic data from a constant concentration biofilter can be used to predict unsteady state biofilter operation. At a 24 h cycle period, the dynamic model compared well with experimental results. For long cycle periods (ie, hours and days), removal efficiency decreased after periods of non‐loading: the longer the period of non‐loading, the poorer the biofilter's performance at the re‐commencement of pollutant loading. At longer time scales the model did not effectively predict transient behaviour, as adsorption and changes in kinetic parameters were not accounted for. Modelling results showed that similar biofiltration performance for the cyclic and constant concentration biofiltration of α‐pinene is expected for biofilters operating solely in the first order kinetics regime. Poorer performance for cyclic biofilters following Monod kinetics spanning the entire kinetics range is expected as the cycle amplitude increases. The most important parameters affecting the performance of a cyclically‐operated biofilter with short cycle periods are: amplitude of cyclic fluctuations, C_{g, max}/C_g, relative value of the half‐saturation constant in the Monod expression, K_s, and effective diffusivity of α‐pinene in the biofilm, D_e. Copyright © 2005 Society of Chemical Industry     

Ultrasound‐activated Knoevenagel condensation of malononitrile with carbonylic compounds catalysed by alkaline‐doped saponites

α,β‐Unsaturated nitriles have been synthesized by Knoevenagel condensation of a carbonylic compound with malononitrile, assisted by sonochemical irradiation. Two alkaline‐promoted clays (Li⁺‐ and Cs⁺‐exchanged saponites) have been employed as catalysts. The influence of the carbonylic compound (benzaldehyde or cyclohexanone) and the use of a solvent on the catalytic activity have been studied. Remarkable increase in the conversion values has been found when the reaction is activated by ultrasound, as compared with the thermal activation. In this green, solvent‐free procedure, α,β‐unsaturated nitriles have been produced in very high yields (97%) when the Cs⁺‐saponite is used as catalyst. Copyright © 2004 Society of Chemical Industry     

喷射导管技术在深水钻井作业中的应用

深水油气日益成为海洋石油勘探开发的热点，但深水钻井作业面临着许多难题和挑战，喷射导管技术是解决深水浅层钻井难题的技术之一。该技术采用在喷射管柱内下动力钻具的方式，用钻入泥线以下的管串自身重力钻进，喷射到位后利用地层的粘附力和摩擦力稳固住导管，起出送入工具和管内钻具，完成导管的安装。喷射导管技术可避免因水泥浆密度过大而压破地层，也可避免深水由于低温等因素影响固井质量。我国第一口水深超千米的深水井——荔湾3-1-1井利用该技术成功完成了导管的安装，井口装置没有出现井口失稳的问题。随着我国深水勘探步伐的加快，越来越多的深水区块将投入勘探开发，喷射导管技术具有良好的应用前景。     

鞍钢1780mm热轧生产线"三电"工程施工概述

概述了鞍钢1780mm生产线技术改造工程中供电、传动及自动控制系统的构成、安装及调试技术要点,以及技术经济效果评述,可供同类工程施工参考.     

A geometry-based error estimation for cross-ratios

For choosing specific cross-ratios as 2D projective coordinates in various computer vision applications, a reasonable error analysis model is usually required. This investigation adopts the assumption of normal distribution for positioning errors of point features in an image to formulate the error variances of cross-ratios. Based on a geometry-based error analysis, a straightforward way of identifying the cross-ratios with minimum error variances is proposed. Simulation results show that the proposed approach, as well as a further simplified alternative, yield much better estimations of minimum error variances in terms of accuracy, cost, and stability compared with some other methods, e.g., the one based on the rule given by Georis et al. (IEEE Trans. Pattern Anal. Mach. Intell. 20 (4) (1998) 366). Some causes of the performance differences in the estimations are explained using a special configuration of point features.     

乙炔在磁稳定床中的选择性加氢研究

 制备了一种磁性Pd/Al₂O₃催化剂，采用磁稳定床考察了活性组分负载量、反应条件及CO浓度对乙炔加氢反应性能的影响。结果表明，当反应温度80℃、反应压力1.5MPa、空速9000h－1、磁场强度（H）25kA/m时，乙炔转化率为100％，乙烯选择性可达81％，具有优良的乙炔加氢活性和乙烯选择性，优于相同反应条件下的进口催化剂；250h稳定性实验结果表明，磁性Pd/Al2O3催化剂具有良好的初活性和乙烯选择性，催化剂性能稳定。     

负载化非茂单活性中心催化剂乙烯聚合的研究

在硅胶上负载了双(N-环己基-3-叔丁基水杨醛亚胺基)二氯化锆配合物,得到负载化非茂单活性中心催化剂。该催化剂用于乙烯聚合,考察了配合物用量、共聚单体1-己烯用量、聚合温度、聚合压力、聚合时间、三乙基铝用量对乙烯聚合性能的影响及对聚合物的相对分子质量、相对分子质量分布、熔体流动指数和密度的影响。实验结果表明,负载化非茂单活性中心催化剂保持了原均相催化剂的乙烯聚合性能;该催化剂在淤浆聚合工艺中聚合平稳,所得聚合物的颗粒形态良好。     

AlF3/N2/空气气氛中密封熔炼镁试验研究

在预先装入固态AlF3的密封熔炼炉中,研究了熔炼温度和炉内空气量对金属镁保护效果的影响,并对表面膜形貌、成分和成分分布进行了研究。研究结果表明,试验温度(≤800℃)下,熔炼温度和气氛中空气含量不影响金属镁的保护效果,金属镁很好被保护,熔炼温度和气氛中空气含量对表面膜成分和成分分布也没有明显影响;表面膜由MgF2区和MgF2 Al混合区域构成;所有表面膜致密,胞团直径小于0.5μm。固态AlF3在熔炼温度下蒸汽压高,汽化产物与金属镁反应生成MgF2和金属铝。     

Shape-Controlled Synthesis and Upconversion Luminescence of Y2O3:Yb, Er Microstructures

The Y2O3: Yb3 , Er3 microstructures were fabricated by a hydrothermal method without surfactants.The microstructures structure was characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM,KYKY 1000B).The up-conversion luminescence spectra were studied under 978 nm laser diode excitation.In Yb3 and Er3 codoped Y2 O3 microcrystals, the relative intensity of green emission became stronger as the morphology of sample changed from wires to films.     

棕刚玉粉中Al2O3含量分析方法的探讨

对耐火材料——棕刚玉粉的质量分析控制，提出了用实用性的检测方法测定其Al2O3含量。通过与国家标准分析方法的对比试验，证实快速实用分析方法测定棕刚玉粉中Al2O3含量是可行的。