含葡萄糖基水溶性硫化黑的合成

本文以C.I.硫化黑1为原料,经葡萄糖还原成隐色体后,再与葡萄糖缩合,合成出含葡萄糖基水溶性硫化黑。合成方法分别采用了焙烘法和水介质中合成。结果表明,水介质中合成的含葡萄糖基水溶性硫化黑溶解度好于焙烘法。     

佛山市中心组团桥梁群对河道影响的数值分析

在不同频率流量和阻水程度条件下,采用一维明渠非恒定流网河数学模型,分析规划中的佛山市桥梁群对区间河道洪季行洪、枯季水环境的影响,计算洪季不同频率洪峰流量下规划桥梁群对区间河道行洪洪水位、分流比的影响,枯季时规划桥梁群对区间河道过流量、分流比的影响,结果表明,利用一维网河数学模型计算佛山市中心组团规划桥梁群对区间河道断面平均水位、流量和流速的影响,结果有足够的数值精度,是可信的。     

SIMULATION STUDIES OF THE REMOVAL OF WATER FROM ETHANOL BY A CATALYTIC DISTILLATION PROCESS

A new approach based on catalytic distillation (CD) technology was proposed to remove water from ethanol. Isobutylene was introduced to react with water in the CD column. The commercial software simulation tool Aspen Plus was used to investigate the effects of key design factors such as operating pressure and temperature, reactant ratios, reflux and distillate to feed ratios, number of separation and reaction stages, and feed and reaction zone location. It was found that the CD technology offers potential advantages of reduced energy consumption and reduced capital cost over traditional approaches for the removal of water from ethanol.     

Fluorescence and IR characterization of epoxy cured with aliphatic amines

Cure reactions of the stoichiometric mixtures of diglycidyl ether of bisphenol A (DGEBA) and two very low molecular weight aliphatic polyether diamines (PED) were studied by using fluorescence and mid- and near-IR spectroscopic techniques. As the cure proceeded, the primary amine groups in PED are converted to the secondary and the tertiary amines. Near-IR spectral analysis was used to calculate the concentration of the three amine groups as a function of cure time. The decrease in the fluorescence intensity of DGEBA at about 307 nm was observed due to more effective quenching of the tertiary amine groups in PED, in comparison to the primary and the secondary amine groups. A large decrease in fluorescence intensity at 75 and 95 °C cure was observed. The amount of all the amine species was estimated from NIR spectra to shed light on the cure kinetics of PPO (polypropylene oxide) in comparison with PEO (polyethylene oxide) epoxy, as well as to explain their fluorescence behavior.The fluorescence intensity changes were correlated to the extent of epoxy reaction obtained by mid- and near-IR spectroscopy.     

月桂醇聚氧乙烯醚硝酸酯助燃降污性能的研究

通过柴油发动机台架试验证明 ,月桂醇聚氧乙烯醚硝酸酯用作柴油添加剂 ,既可提高柴油的燃烧性能 ,又可降低排放尾气中的一氧化碳 (CO)、未燃碳氢化合物 (HC)、氮氧化物 (NOx)含量及烟度等多种功能 ,是一种良好的多功能柴油助燃消烟添加剂。     

横向各向同性介质中的初至波旅行时计算

本文直接采用Thomsen导出的横向各向同性介质中的相速度、群角与相角、群速度与相速度的精确函数关系,提出了一种新的具有任意各向异性强度的横向各向同性介质中的初至波旅行时计算方法,它不同于Faria等人给出的采用群速度近似公式(Byun)的仅适应弱各向异性的初至波旅行时计算方法。该新算法在计算具有任意各向异性强度的横向各向同性介质中的初至波旅行时时,并不显著地增大计算时间。分析对比由新算法得到的初至波旅行时的等值线图和由交错网格有限差分波场模拟得到的波场快照表明,无论是对弱各向异性还是对强弱各向异性,新算法都具有较高的精度;随着各向异性强度的增大,新算法的计算结果与采用近似公式计算结果的差值也随之增大。     

镁钴铝类水滑石催化合成安息香甲醚

采用共沉淀法制备了镁钴铝类水滑石化合物(MgCoAl-HTLcs),并用 X 射线衍射、扫描电子显微镜、NH_3程序升温脱附等方法对 MgCoAl-HTLcs 进行了表征,并以 MgCoAl-HTLcs 为催化剂催化苯甲醛与甲醇反应合成安息香甲醚,研究了n(Mg):n(Co):n(Al)、催化剂用量、原料配比、反应温度、反应时间对合成反应的影响。表征结果显示,MgCoAl-HTLcs 的晶相完整,表面主要为弱酸、弱碱性。催化合成安息香甲醚的适宜条件为:MgCoAl-HTLcs 催化剂用量0.10 g(约为原料总质量的0.23%),n(Mg):n(Co):n(Al)=0.4:1.6:1.0,V(苯甲醛):V(甲醇)=3:50,反应温度50℃,反应时间150 min。在此条件下,苯甲醛的平衡转化率达77.49%,安息香甲醚选择性接近100%。为洁净合成安息香甲醚开辟了一条新的途径。     

汽车代用燃料的应用和发展

评述了汽车代用燃料的现状和未来，压缩天然气和液化石油气将率先大量使用，其次是醇燃料，合成燃料和二甲醚将主要用于某些混合动力车，燃料电池因为能源效率高是最有吸引力的车用能源，将于2010-2015年开始在汽车上实际使用，我国石油工业在提升汽油和柴油质量的同时，应与汽车工业联手开发代用燃料，特别要注意发展燃料电池技术。     

The ability of the Millon Clinical Multiaxial Inventory--Third Edition to detect malingering.

This study investigated the ability of the Millon Clinical Multiaxial Inventory--Third Edition (MCMI-III) to discriminate students malingering psychopathology (n=106) from bona fide psychiatric inpatients (n=202). Students were randomly assigned to a fake-bad or an honest-responding condition. Analyses investigated the ability of the modifier indices to discriminate fake-bad group participants from the psychiatric inpatients. Scale X raw cutoff score >178 yielded a positive predictive power (PPP) of 0.0, a negative predictive power (NPP) of 63.1, and a hit rate of 63.1%. Optimal cutoff scores were developed. Scale X Base Rate (BR) >84 provided a PPP of 55.6, an NPP of 72.1, and a hit rate of 65.2%. Scale Y BR     

Single axioms for odd exponent groups

With the aid of automated reasoning techniques, we show that all previously known short single axioms for odd exponent groups are special cases of one general schema. We also demonstrate how to convert the proofs generated by an automated reasoning system into proofs understandable by a human.Authors supported by NSF Grant DMS-9100665