全文获取类型
收费全文 | 1956篇 |
免费 | 65篇 |
国内免费 | 63篇 |
专业分类
电工技术 | 9篇 |
综合类 | 32篇 |
化学工业 | 488篇 |
金属工艺 | 379篇 |
机械仪表 | 72篇 |
建筑科学 | 144篇 |
矿业工程 | 21篇 |
能源动力 | 84篇 |
轻工业 | 32篇 |
水利工程 | 9篇 |
石油天然气 | 69篇 |
武器工业 | 9篇 |
无线电 | 111篇 |
一般工业技术 | 255篇 |
冶金工业 | 119篇 |
原子能技术 | 69篇 |
自动化技术 | 182篇 |
出版年
2023年 | 15篇 |
2022年 | 30篇 |
2021年 | 37篇 |
2020年 | 45篇 |
2019年 | 35篇 |
2018年 | 36篇 |
2017年 | 45篇 |
2016年 | 36篇 |
2015年 | 32篇 |
2014年 | 79篇 |
2013年 | 151篇 |
2012年 | 53篇 |
2011年 | 179篇 |
2010年 | 154篇 |
2009年 | 143篇 |
2008年 | 113篇 |
2007年 | 120篇 |
2006年 | 120篇 |
2005年 | 88篇 |
2004年 | 98篇 |
2003年 | 93篇 |
2002年 | 67篇 |
2001年 | 43篇 |
2000年 | 38篇 |
1999年 | 37篇 |
1998年 | 47篇 |
1997年 | 34篇 |
1996年 | 31篇 |
1995年 | 26篇 |
1994年 | 15篇 |
1993年 | 9篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 6篇 |
1985年 | 1篇 |
1984年 | 2篇 |
排序方式: 共有2084条查询结果,搜索用时 709 毫秒
41.
The two types of high-sulphur coals Mequinenza and Illinois No. 6, in the initial form and subjected to potassium/liquid ammonia reduction, were analysed by atmospheric pressure-temperature programmed reduction (AP-TPR) method. It has been shown that preliminary demineralisation was beneficial for AP-TPR measurements because of the removal of calcium compounds. The reduction of sulphides and disulphides in the potassium/liquid ammonia system was found to lead to formation of aromatic and aliphatic thiols. The presence of the latter is better manifested in the AP-TPR kinetograms when the measurements are performed in the presence of a special reducing mixture. It has been shown that the coal reduction in the potassium/liquid ammonia system apart from transformations of non-thiophene sulphur groups also leads to breaking up of the C-S bonds in some thiophene systems. 相似文献
42.
由于大气粒子对光的多散射作用非常显著,多散射的一般表现是在各种天气条件下光源周围的辉光现象。针对恶劣天气条件下的光源图像,采用辐射传输方程建立了点光源的多散射模型。根据所得到的点扩散函数对晴朗天气下带有光源的图像添加天气效果,并对恶劣天气条件下的光源图像进行复原,去除光源周围的辉光,从而得到清晰的光源图像。仿真结果证明了该方法的有效性. 相似文献
43.
观测几何对目标探测性能影响的仿真分析 总被引:1,自引:0,他引:1
在光电武器作战探测目标性能问题的研究中,不同大气/气溶胶模式、不同观测几何条件下的光电武器作战效能差异显著.针对上述问题,通过分析大气传输和观测几何对视在对比度的影响,建立了视在对比度传递模型,结合TIP准则提出了观测几何对目标探测性能的影响模型.利用Modtran软件离线计算的基础数据,提出了探测性能模型快速仿真计算方法,实现了典型地区、全天时、不同观测几何和观测距离条件下的成像系统探测性能的快速仿真计算.采用快速仿真计算方法,选取典型参数,计算并分析了不同大气/气溶胶模式、观测几何等因素对视在对比度、探测概率和探测距离等指标的影响.结果表明:观测几何对目标探测性能影响显著,50%探测概率条件下,顺光探测距离是逆光探测距离的1.38 ~1.7倍;不同大气/气溶胶模式条件下,观测几何对探测距离影响差异明显,海洋性气溶胶模式下影响较大,乡村型气溶胶模式下影响较小.文中提出了观测几何对目标探测性能的影响模型和快速仿真计算方法,为光电武器系统任务规划和作战效能评估提供了理论和技术支持. 相似文献
44.
The time dependency of the amounts of corrosion products and co-existing adsorbed water on copper in humid air containing SO2 was estimated from a series of in situ time-resolved IR-RAS spectra on the basis of the relations between the band intensities and the mass changes of the corrosion products, which were determined by simultaneous measurement of IR-RAS and QCM. The amounts of both corrosion products increased slowly at the initial stage and later increased rapidly. Although the relative humidity was kept constant, the amount of adsorbed water increased nearly the same behavior as that of corrosion products in the stage of relatively small amounts of corrosion products and later increased rapidly when the amounts of corrosion products increased. In humid air without SO2, sulfite gradually decomposed and some of it changed into sulfate. 相似文献
45.
46.
Hot dip fine Zn and Zn-Al alloy double coating for corrosion resistance at coastal area 总被引:1,自引:0,他引:1
A new hot dip Zn-7Al alloy coating was performed on a structural steel by double coating of fine Zn and Zn-7 wt.% Al alloy, to prevent severe corrosion in coastal area. The alloy-coated steels were exposed to seaside, quasi-industrial, and rural districts to compare with conventional Zn coating. Double coating was significantly effective in preventing corrosion, particularly in a seaside. It was estimated from the exposure test for 10 years that the life of the Zn-7Al alloy-coated steel would be almost four times that of the Zn-coated steel in the seaside. A bending test showed that no exfoliation occurred at the interface between the coated alloy and substrate steel. TEM observation revealed that the excellent adhesiveness of the doubly coated fine Zn and Zn-7Al alloy to the steel substrate was due to formation of the interface region consisting of heterogeneous fine phase mixture of zinc, aluminium and iron. 相似文献
47.
Hydrogen entry and permeation into iron were measured by an electrochemical method during atmospheric corrosion reaction. The hydrogen permeation was enhanced on passive films because the hydrogen adsorption increased by the hydrogen evolution mechanism which is different from that on a bear iron surface. The permeation rate during a wet and dry corrosion cycle showed a maximum in the drying process depending upon the surface pH and the corrosion potential. The pollutant such as Na2SO3 which decreases the pH and the corrosion potential causes an increase in the permeation rate. The mechanism of the change in the permeation rate during the wet and dry cycles is explained by the polarization diagram of the electrode covered by thin water layer. 相似文献
48.
Effect of the marine environment on reinforced concrete durability in Iberoamerican countries: DURACON project/CYTED 总被引:2,自引:0,他引:2
O. Trocónis de Rincón M. Sánchez R. Fernández C. Andrade M. Castellote F. Irassar R. Vera R.M. de Gutiérrez C. Guerrero A.C. Villalobos A. Torres-Acosta M. Martínez-Madrid P. Castro-Borges T. Pérez-López A.P. de Melo Miguel Pedrón 《Corrosion Science》2007,49(7):2832-2843
This work presents some of the results from the project: “Effect of the environment on reinforcement durability” (DURACON) in its first two-years period, which investigates the influence of urban and marine meteorochemical parameters on the performance of reinforced concrete structures. The results presented in this investigation are from 21 marine test sites only (no urban environments are included), distributed among 11 countries (Argentina, Bolivia, Brazil, Chile, Colombia, Costa Rica, Mexico, Spain, Uruguay, Portugal and Venezuela). The environment was evaluated using ISO Standard 9223 and the concrete was characterized by measuring compressive strength, elastic modulus, total and effective porosity, chloride permeability according to ASTM standards, as well as the effective porosity and resistance to water absorption using the Fagerlund method. To that effect, concrete specimens (with and without reinforcement) were prepared for electrochemical and physical/mechanical/chemical tests using the existing materials in each participating country, following strict procedures which enabled the preparation of similar concrete samples. Two water/cement (w/c) ratios (0.45 and 0.65) were selected, where the concrete with 0.45 w/c ratio had to have a minimum cement content of 400 kg/m3 and the one with 0.65 w/c ratio a compressive strength of 210 kg/cm2. Type I Portland cement, siliceous sand, and crushed rock as coarse aggregates (13-mm maximum nominal size) were used. After a one-year exposure, the results of the corrosion potentiality and probability analysis of the reinforcement in the different test stations showed that, for marine atmospheres, the most aggressive environment to induce steel corrosion was at Portugal’s Cabo Raso station, and the least aggressive one was at Chile’s Valparaíso station. These results are comparable with the ones found using electrochemical measurements, after a two-year exposure. 相似文献
49.
The extended X-ray absorption fine structure (EXAFS) method and transmission electron microscopy (TEM) have been used for characterizing the local structure and morphology of ferric oxyhydroxides, α-FeOOH and γ-FeOOH, with and without chromium. These ferric oxyhydroxide powders were prepared from aqueous solutions containing iron and chromium ions. Radial structural functions for iron obtained by Fe K edge EXAFS spectra showed that the linkage of structural units formed by FeO6 octahedra in γ-FeOOH is distorted by chromium addition, while such distortion in α-FeOOH is not clearly detected. On the other hand, Cr K edge EXAFS spectra showed that the local structure around chromium does not necessarily correspond to the local structure around of iron, which is observed by Fe K edge EXAFS spectra. This suggests that the structural units containing iron and chromium are heterogeneously distributed in these ferric oxyhydroxides. The local structural information was discussed coupled with morphological features of these ferric oxyhydroxides observed by TEM. 相似文献
50.