利用波形分析技术预测塔河油田碳酸盐岩储层

针对塔河油田盐体覆盖区下奥陶统碳酸盐岩埋深大,储层非均质性强的特征,利用地震波形变化特征半定量识别和预测优质储层分布。波形分析法是根据碳酸盐岩储层裂缝和孔洞结构特有的非均质性,建立地质模型,结合地震波形分析和反射机理研究,确定储层与地震响应之间的对应关系,根据建立的碳酸盐储集层地震识别模式,进而对未知区域作储层预测。     

复合白云石表面链状纳米CaCO_3的制备

在Ca(OH)_2-H_2O-CO_2反应体系中,根据非均匀成核原理,通过调整体系反应温度、Ca(OH)_2浓度、ZnSO_4添加量等反应参数,控制在白云石颗粒表面生成具有链状结构的纳米Ca-CO_包覆层.利用SEM,XRD等检测表征手段,分析了不同反应参数对纳米CaCO_3晶形的影响.结果表明:当反应温度为25℃,ZnSO_4加入量为Ca(OH)_2的4%,Ca(OH)_2浓度为0.3mol/L时,在白云石颗粒表面生成了长径比为7:1的链状纳米CaCO_3.提高体系的反应浓度能够减少ZnSO_4的加入量.     

Effect of Ca~(2+) on CO_2 corrosion properties of X65 pipeline steel

The effect of Ca~(2+) on CO_2 corrosion to X65 pipeline steel was investigated in the simulated stratum water of an oil field containing different concentrations of Ca~(2+). It is found that Ca~(2+) can enhance the corrosion rate,especially in the Ca~(2+) concentration from 256 to 512 mg/L,which can be attributed to the growing grain size and loosing structure of corrosion scales with increasing Ca~(2+) concentration. X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS) investigations reveal that a complex carbonate (Fe, Ca)CO_3 forms at high Ca~(2+) concentration due to the gradual replacement of Fe~(2+) in FeCO_3 by Ca~(2+).     

碳酸根含量对碳酸羟基磷灰石形貌和热处理的影响分析

采用沉淀法制备了两种不同碳酸根〈CO3^2-）含量的纳米碳酸羟基磷灰石（nanosized carbonated hydroxyapatite,CHA）,研究了碳酸根含量对CHA晶体形貌、烧结和热稳定性的影响,用X射线衍射和透射电镜表征了样品的物相组成与形貌．结果表明：随着碳酸根含量的减小,CHA晶粒尺寸和长径比增加;CHA坯体的烧结温度和粉体的热稳定性与初始的碳酸根含量有关,含量越高,烧结温度越低,热稳定性越差．     

塔中地区奥陶系储层特征及其与油气聚集关系

为了进一步研究塔里木盆地塔中地区不同储层间特征的对比及各储层在平面上的变化特征,通过收集和整理各单井储层岩心孔渗测试、平面沉积相、断裂分布、薄片分析和油气藏特征等资料,详细地描述了塔里木盆地塔中地区奥陶系碳酸盐岩3套油气储层的基本特征.分析表明:裂缝型储层是塔中地区主要的储层类型,各储层的孔隙度和渗透率之间均不存在线性关系,储层渗透率变化区间较大,裂缝发育控制了该区渗透率的变化.在此基础上,对目前比较关注的几个与油气聚集有关的储层问题进行了讨论,结果表明:塔中地区奥陶系碳酸盐岩储层的物性高值区均沿I号坡折带分布;沉积相是控制这些碳酸盐岩储层物性的主要因素;塔中地区奥陶系碳酸盐岩储层的油气分布与储层类型密切相关.     

缝洞型碳酸盐岩油藏水驱油机理物理模拟研究

为了更好地认识缝洞型碳酸盐岩油藏的特殊渗流机理,根据某油田缝洞型碳酸盐岩的实际情况设计制作了全直径缝洞型岩芯模型,实验岩样来源于油田的实际岩芯,采用油田实际油样和相似地层水进行了模型水平、倾斜30°、倾斜60°三种不同角度的水驱油机理物理模拟实验,分析实验结果,认为缝洞型碳酸盐岩采收率、含水率、无水采收期等与缝洞倾斜情况和缝洞结构有密切关系.并将实验数据应用于Cruz Hernandez J等人基于对流-扩散渗流理论建立的缝洞型油水两相流动系统数学模型的拟合中,讨论了数学模型中的空间系数、扩散系数和流动速度对模型拟合的影响情况,并提出了模型的改进应考虑重力作用、流体流速、孔洞配位数等影响因素.     

Reprint of “Suppressing propylene carbonate decomposition by coating graphite electrode foil with silver”

A method has been developed to suppress the decomposition of propylene carbonate (PC) by coating graphite electrode foil with a layer of silver. Results from electrochemical impedance measurements show that the Ag-coated graphite electrode presents lower charge transfer resistance and faster diffusion of lithium ions in comparison with the virginal one. Cyclic voltammograms and discharge-charge measurements suggest that the decomposition of propylene carbonate and co-intercalation of solvated lithium ions are prevented, and lithium ions can reversibly intercalate into and deintercalate from the Ag-coated graphite electrode. These results indicate that Ag-coating is a good way to improve the electrochemical performance of graphitic carbon in PC-based electrolyte solutions.     

Absolute measurement of the thermal conductivity of propylene carbonate by the AC transient hot-wire technique

The paper describes a new apparatus for measuring the thermal conductivity of liquids based on a transient hot-wire method. The apparatus has been used to measure the thermal conductivity of propylene carbonate (C₄H₆O₃). The measurements have been carried out in the temperature range 284–313 K and at saturation pressure. The accuracy of the data is within ±1.5%.     

Refinement mechanism of in-situ Al4C3 particles on AZ91 magnesium alloys

The effects of SrCO3 on the microstructure of AZ91 magnesium alloy were investigated by OM, SEM, EDS, XRD and DTA analyses. The results show that AZ91 magnesium alloy with 1.0% SrCO3 addition has the best refining effect at 730 ℃ for 20 min, the average size of the α-Mg grain in AZ91 matrix alloy is reduced from about 91 μm to 58 μm, with reduction of about 36%. Based on the analysis results of EDS, binding energy, and Gibbs free energy, it is evident that the grain is refined because of the generation of A14 C3 particles which can be used as the crystal nucleus of the magnesium alloy when SrCO 3 is added. Owing to the generation of A14C3 in AZ91 magnesium alloy, the grain boundary is pined and the grain growth is inhibited. In the accession to the Al4C3, small subcooling temperature difference leads to the formation of fine grain microstructure in alloy melt. Fine grain microstructure in AZ91 alloy melt with the addition of SrCO3 can be obtained on the condition of lower undercooling temperature according to the DTA analysis results.     

基于吲哚类半花菁染料的钯比率荧光探针

利用6-羟基萘-2-醛和碘化N-乙基-2,3,3-三甲基-3H-吲哚啉季铵盐的缩合反应生成的羟基半花菁染料2与氯甲酸烯丙酯的反应合成了荧光比率型钯探针1.研究表明:在含水介质中,探针1对钯(Pd0和Pd2+)显示出很高的敏感性、选择性和抗干扰性,其荧光比率增强大约72倍,对Pd2+的最低检测极限为0.23μmol/L.探针1对钯的作用机理是钯催化碳酸烯丙酯断裂导致比率荧光变化.