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排序方式: 共有427条查询结果,搜索用时 18 毫秒
31.
Dal Kyoung Youn Hong Kyoon No Witoon Prinyawiwatkul 《International Journal of Food Science & Technology》2013,48(3):571-577
Squid (Todarodes pacifica) pen was an excellent source of β‐chitin with 25.5% yield. The optimal condition to prepare squid pen β‐chitin was established: deproteinisation with 3% NaOH for 30 min at 15 psi/121 °C and a solid/solvent ratio of 1:10 (w/v) and a subsequent demineralisation with 1 N HCl for 30 min at room temperature and a solid/solvent ratio of 1:10 (w/v). Squid pen β‐chitin contained 6.29% nitrogen, 0.25% ash, and negligible fat with degree of acetylation of 94.02%, residual amino acid of 0.499 g/100 g and bulk density of 0.28 g mL?1. Depending on its particle size, squid pen β‐chitin visually looked white (L* = 82.82, a* = ?0.67, b* = 6.31; particle size of 0.15–0.18 mm) or light grey (L* = 62.88, a* = 0.33, b* = 10.66; particle size of 0.425–0.841 mm). Water, fat and dye‐binding capacity of squid pen β‐chitin was 694.67%, 194.03% and 79.81%, respectively. 相似文献
32.
Confined states of a positronium (Ps) in the spherical and circular quantum dots (QDs) are theoretically investigated in two size quantization regimes: strong and weak. Two-band approximation of Kane’s dispersion law and parabolic dispersion law of charge carriers are considered. It is shown that electron-positron pair instability is a consequence of dimensionality reduction, not of the size quantization. The binding energies for the Ps in circular and spherical QDs are calculated. The Ps formation dependence on the QD radius is studied. 相似文献
33.
Although the existence of Lewis acid–base interactions between CO2 and electron donating functional groups in polymers can be determined from the vibrational spectra of the polymers in question, only a few quantitative estimates of the strength of such interactions have been reported. We have previously reported values of the enthalpy of association between CO2 and the carbonyl group in polymers from the bending vibrations of CO2. In the present work, we extend these measurements to other functional groups and relate the strength of these interactions to the structure of the polymer. 相似文献
34.
We give a general category theoretic formulation of the substitution structure underlying the category theoretic study of
variable binding proposed by Fiore, Plotkin, and Turi. This general formulation provides the foundation for their work on
variable binding, as well as Tanaka’s linear variable binding and variable binding for other binders and for mixtures of binders
as for instance in the Logic of Bunched Implications. The key structure developed by Fiore et al. was a substitution monoidal
structure, from which their formulation of binding was derived; so we give an abstract formulation of a substitution monoidal
structure, then, at that level of generality, derive the various category theoretic structures they considered. The central
construction we use is that of a pseudo-distributive law between 2-monads on Cat, which suffices to induce a pseudo-monad on Cat, and hence a substitution monoidal structure on the free object on 1. We routinely generalise that construction to account
for types.
This work has been done with the support of EPSRC grant GR/586372/01, A Theory of Effects for Programming Languages. 相似文献
35.
Frank U. Axe Scott D. Bembenek Sndor Szalma 《Journal of molecular graphics & modelling》2006,24(6):456
Molecular modeling was used to analyze the binding mode and activities of histamine H3 receptor antagonists. A model of the H3 receptor was constructed through homology modeling methods based on the crystal structure of bovine rhodopsin. Known H3 antagonists were interactively docked into the putative antagonist binding pocket and the resultant model was subjected to molecular mechanics energy minimization and molecular dynamics simulations which included a continuum model of the lipid bilayer and intra- and extracellular aqueous environments surrounding the transmembrane helices. The transmemebrane helices stayed well embedded in the dielectric slab representing the lipid bilayer and the intra- and extracellular loops remain situated in the aqueous solvent region of the model during molecular dynamics simulations of up to 200 ps in duration. A pharmacophore model was calculated by mapping the features common to three active compounds three-dimensionally in space. The 3D pharmacophore model complements our atomistic receptor/ligand modeling. The H3 antagonist pharmacophore consists of two protonation sites (i.e. basic centers) connected by a central aromatic ring or hydrophobic region. These two basic sites can simultaneously interact with Asp 114 (3.32) in helix III and a Glu 206 (5.46) in helix V which are believed to be the key residues that histamine interacts with to stabilize the receptor in the active state. The interaction with Glu 206 is consistent with the enhanced activity resulting from the additional basic site. In addition to these two salt bridging interactions, the central region of these antagonists contains a lipophilic group, usually an aromatic ring, that is found to interact with several nearby hydrophobic side chains. The picture of antagonist binding provided by these models is consistent with earlier pharmacophore models for H3 antagonists with some exceptions. 相似文献
36.
张笑非 《数字社区&智能家居》2007,3(7):51-52
本文通过研究IETF在RFC2571中制定的SNMP管理框架,并利用Microsoft提供的WinSNMP API来设计并实现网络管理系统。内容包括SNMP实体的实现,模块间的协作,以及针对表示被管对象的变量绑定的处理方法。 相似文献
37.
无线局域网采用移动IP实现移动性管理.移动IP切换存在切换时延大,数据包易丢失的问题.切换时延由移动检测时延和注册时延组成,而移动检测时延在其中占主要部分.文章提出了一种移动检测优化方案,采用了自适应绑定的算法,同时充分考虑了域内小范围高频度切换的情况,使移动节点在无线局域网环境中进行快速有效的切换. 相似文献
38.
Min‐Jung Bae Takeshi Ishii Kanako Minoda Yukiko Kawada Tatsuya Ichikawa Taiki Mori Miya Kamihira Tsutomu Nakayama 《Molecular nutrition & food research》2009,53(6):709-715
(–)‐Epigallocatechin gallate (EGCg) is the major component of green tea and is known to show strong biological activity, although it can be easily oxidized under physiological conditions. In this study, we indicate that EGCg is stable in human serum and that human serum albumin (HSA) stabilizes EGCg under aerobic condition. Although EGCg is usually decomposed within 1 h in aqueous solution at neutral pH, EGCg in serum and phosphate buffer (pH 7.4) containing HSA was stable over 1 h, even at neutral and slightly alkaline pH. Under these conditions, EGCg binds to HSA non‐covalently. The sulfhydryl group acts as an antioxidant for EGCg oxidation. Incubation of EGCg with HSA is accompanied by the oxidation of a free sulfhydryl group in HSA. These results suggest that the antioxidant property and the binding capacity of HSA contribute to the stabilization of EGCg in human serum. 相似文献
39.
Continuum and atomistic models of strongly coupled diffusion, stress, and solute concentration 总被引:1,自引:0,他引:1
Poor cyclic performance of electrodes in lithium-ion rechargeable cell batteries is calling for efforts to develop continuum models of diffusion under very large stresses and high solute concentrations. The present work is aimed to develop such a model based on input from atomistic simulations. We consider four fundamental features of highly nonlinear behavior associated with diffusion at high solute concentrations. First, the effect of solute-induced stresses on the activation energy of solute diffusion could be important. Second, the solute concentration may be subject to an upper limit if there exists a stoichiometric maximum concentration. Third, the strong influence of the change in local chemical environment on the interaction energy between solute and host atoms could play a significant role. Fourth, we include the effect of the solute concentration on the Young's modulus of the host material. A continuum model is developed and validated based on atomistic simulations of hydrogen diffusion in nickel. The influences of each feature above are clearly discussed through parametric studies. 相似文献
40.
Modeling of chloride diffusivity coupled with non-linear binding capacity in sound and cracked concrete 总被引:4,自引:0,他引:4
Tetsuya Ishida Prince O'Neill Iqbal Ho Thi Lan Anh 《Cement and Concrete Research》2009,39(10):913-923
The objective of this research is to establish a model that can predict chloride transport phenomena in sound and cracked concrete. The chloride diffusivity is formulated based on computed micro-pore structure, which considers tortuosity and constrictivity of porous network as reduction factors in terms of complex micro-pore structure and electric interaction of chloride ions and pore wall. In the real environment, concrete structures are not always crack-free, therefore chloride transport in cracked concrete is also simulated by section large void spaces in a control volume to represent the crack and by proposing a model of chloride diffusivity through the cracked region The proposed models are implemented into a finite-element computational program DuCOM, which simulates the early-age development process of cementitious materials. The calculated concentration profiles of total chloride ions are verified through a comparison with experiments results. 相似文献