The influence of gas velocity, salt type and concentration on transition concentration for bubble coalescence inhibition and gas holdup

The influence of gas velocity (3.5, 10, and 18 mm/s), salt type (NaCl, NaF, NaBr, NaI and CsCl) and salt concentration (0.001-3 M) on bubble coalescence in a small bubble column were studied. The bubble coalescence was determined by the relative change in the measured light intensities passing through the salt solutions and clean deionised water. It was shown that the transition salt concentration for bubble coalescence inhibition (determined at 50% of bubble coalescence) of all investigated salts decreases with increasing superficial gas velocity. The difference in the transition concentration between NaCl, NaF, NaBr and CsCl does not significantly change with the gas velocity. However that difference between NaI and the other salts significantly decreases with increasing the gas velocity. The gas holdup significantly increases with NaCl, NaF, NaBr and CsCl concentrations but does not significantly change with NaI concentration. These new results imply that the transition salt concentration for bubble coalescence and gas holdup depend not only on the salt properties (i.e. the ion type and their combination) as previously reported, but also on the hydrodynamic conditions.     

Experimental and modelling study of gas dispersion in a double turbine stirred tank

Gas dispersion in a double turbine stirred tank is experimentally characterised by measuring local gas holdups and local bubble size distributions throughout the tank, for three liquid media: tap water, aqueous sulphate solution and aqueous sulphate solution with PEG. For all these media, bubble coalescence generally prevails over breakage. Where average bubble size decreases, this can be attributed to the difference in slip velocity between different sized bubbles. Most of the coalescence takes place in the turbine discharge stream.A compartment model that takes into account the combined effect of bubble coalescence and breakage is used to simulate gas dispersion. The model predicts spatial distribution of gas holdup and of average bubble size, with average bubble size at the turbines as an input. Reasonable agreement between experiment and simulation is achieved with optimisation of two parameters, one affecting mainly the slip velocity, the other related mainly to the bubble coalescence/breakage balance. Different sets of parameters are required for each of the three liquid systems under study, but are independent of stirring/aeration conditions. The model only fails to simulate the smaller average bubble diameters at the bottom of the tank.     

Experimental analysis of bubble mode in a plate-type absorber

An experimental analysis of ammonia-water absorption was performed in a plate-type absorber. The flow of water and ammonia gas was performed in the bubble mode. The experiments were made to examine the effects of solution flow rate and gas flow rate on the performance of the absorber. It was found that the increase of solution flow rate rarely affected the mass transfer, but improved the heat transfer. As the gas flow rate increased, slugging occurred in the bubble mode and influenced the thermal boundary layer. Finally, the results were converted into dimensionless numbers to elucidate physical phenomena and plotted as Sherwood number versus Reynolds number for mass transfer performance and Nusselt number versus Reynolds number for heat transfer performance.     

免疫亲和柱法测定小麦中黄曲霉毒素

本文研究了用正相高效液相色谱仪附荧光检测器测定小麦中黄曲霉毒素B1、B2、C1、C2。黄曲霉毒素用甲醇－水（70＋30）提取，提取液经免疫亲和柱富集、净化，于液相色谱仪上测定。本实验采用添加法测定回收率，添加水平为0.11-3.9μg/kg时，其平均回收率为87.9%-102.5%。本方法的最低检测限为0.1μg/kg。     

Bubble size modeling approach for the simulation of bubble columns

The constant bubble size modeling approach (CBSM) and variable bubble size modeling approach (VBSM) are frequently employed in Eulerian–Eulerian simulation of bubble columns. However, the accuracy of CBSM is limited while the computational efficiency of VBSM needs to be improved. This work aims to develop method for bubble size modeling which has high computational efficiency and accuracy in the simulation of bubble columns. The distribution of bubble sizes is represented by a series of discrete points, and the percentage of bubbles with various sizes at gas inlet is determined by the results of computational fluid dynamics (CFD)–population balance model (PBM) simulations, whereas the influence of bubble coalescence and breakup is neglected. The simulated results of a 0.15 m diameter bubble column suggest that the developed method has high computational speed and can achieve similar accuracy as CFD–PBM modeling. Furthermore, the convergence issues caused by solving population balance equations are addressed.     

ACOUSTIC STUDIES OF INTERFACIAL EFFECTS IN AIRLIFT REACTORS

Rational design of airlift reactors for the culture of plant and animal cells is impeded by a lack of understanding of the causes of loss of viability. Some recent speculations in the literature suggest that gas-liquid interfacial phenomena have played prominent roles in observed instances of loss of viability in both insect and animal cell cultures. The important interfacial events may include bubble formation and detachment at the sparger, bubble coalescence and breakage, and bubble disengagement at the free surface-entailing film thinning, film rupture, and film droplet ejection.

We have carried out an experimental investigation of interfacial phenomena using macrovideography and acoustic signals recorded at both the sparger and the free surface. Data have been collected for several liquid media including distilled water, distilled water with electrolyte (NaCl), and aqueous solutions of glycerol (μ = 3 to 9.5 cP). The studies were conducted in a 3-liter, acrylic plastic, split-column airlift reactor, and air was introduced through interchangeable sieve plates (with hole diameters of 1, 2, and 3 mm). Time-series data collected from the microphone were processed for mean and root-mean-square values, and Fourier transforms were computed to identify important signal energies. A sequence of experiments was also conducted that was designed to relate specific interfacial phenomena to the frequencies of the noises produced.     

气—液鼓泡塔中流动域和气含率的分布

利用压力传感器测定了气、液两相鼓泡塔内不同轴、径向位置上压强的脉动信号,分析了压强的脉动特征,计算了各种操作条件下塔内不同轴向位置截面上的平均气含率,发现在不同操作条件下,塔内可能出现不同的流动域分布,即全塔均匀鼓泡域、全塔过渡域、全塔湍动鼓泡域以及均匀鼓泡域,过渡域和湍动鼓泡域中的相邻2种或3种流域同时出现在塔内不同高度上。提出了不同轴向位置流域转变的判据。并发现,同一截面的不同径向位置基本处于同一流域内。同时研究了鼓泡塔内气含率在轴向上的分布规律,给出了不同流动域内气含率的关系式。     

微孔膜气体分布器对气液传质的影响

本文开发了一种新型微孔膜气体分布器,并对使用该分布器时鼓泡塔反应器内气液传质性能进行了研究。实验结果表明,使用这种新型膜气体分布器可以得到细小均匀的气泡,较大幅度地增大了气液传质比表面积,从而大大强化了反应器的传质能力。     

GFRP对不同断面形状混凝土柱约束性能试验研究

在文献研究和工程调查的基础上，本文选用方形、圆形、八边形、直边加圆弧形和空心的配筋混凝土模型柱为研究对象，通过轴心受压试验所得到的荷载-轴向变形、荷载-纤维应变、荷载-箍筋应变关系曲线以及相应对比分析，研究了GFRP对不同断面形状混凝土柱的约束性能。研究表明，断面形状对混凝土柱约束性能起着决定性作用。在其它条件相同的情况下，约束性能按照圆形、八边形、直边加圆弧形、方形、空心断面形状的顺序递减。