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It is demonstrated that glassy carbon powder can be thermochemically activated. During activation, a film with open pores is created on the glassy carbon particles. This film has a large internal surface area, which is accessible to liquids and gases. A simple model for the evolution of the internal surface area in glassy carbon powder during thermochemical gas-phase oxidation is also presented and compared with experimental data. Experimental results are in qualitative agreement with the model. We found that a sharp particle size distribution is desirable with regard to potential technical applications. 相似文献
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No authorship indicated 《Canadian Metallurgical Quarterly》1992,47(4):479a
The Early Career Awards recognize the large number of excellent young psychologists. Recipients of this award may not have held a PhD for more than nine years. The areas considered in 1991 were animal learning and behavior, developmental, and personality. The winners for 1991 were Kent C. Berridge, Susan A. Gelman, and Randy J. Larsen. For each winner a citation, biography, and selected bibliography of their works are presented. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
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Coatings derived from organofunctional silanes have been investigated as possible replacements for the chromate-based systems used in the aerospace industry. In this study, organofunctional silanes [bis-(triethoxysilylpropyl)ethane and bis(triethoxysilylpropyl) tetrasulfide] were reacted with commercially available acrylate (ECO-CRYL™ 9790) and epoxy (EPI-REZ™ WD-510) resins, resulting in a one-step, low-VOC, chromate-free primer. Liquid-state 29Si and 13C NMR were used to determine structural characteristics of various optimized formulations. 相似文献
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Ali Hassanzadeh 《Corrosion Science》2007,49(4):1895-1906
In our previous works, the corrosion inhibition properties of propylamine (PA), iso-propylamine (i-PA), butylamine (BA), tert-butylamine (t-BA), hexylamine (HA), ethylenediamine (EDA), diethanolamine (DEA), 3-amino-1-propanol (3-AP), 2-dimethylethanolamine (2-DEA), cyclohexylamine (CHA), N-methylcyclohexylamine (N-MCA) and dicyclohexylamine (DCHA) have been investigated by means of electrochemical impedance spectroscopy (EIS) with a carbon steel rotating disc electrode in some petroleum/water corrosive mixtures containing acetic acid and NaCl at 25 °C. In this work, the Kramers-Kronig transformations (KKTs) were applied to evaluate the validity of the impedance data of these amine compounds in hydrodynamic condition. The results obtained showed that experimental impedance data did not satisfy in K-K relations completely viz. indicated some errors. These errors were related to stray capacitances, external transmission line effects, pits formation and change in interface during data acquisition at high and low frequencies regions. In addition, the selection of a suitable equivalent circuit strongly emphasized to better interpret of EIS data which in turn cause better resulted KKTs spectra. With considering obtained transformations, more effective inhibitor was selected with regard to its charge transfer resistance, the corrosion capacitance and well satisfying in K-K relations. 相似文献
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J. Zhu L. Zhao G. -J. Cui M. Wei H. -Y. Wei H. -Y. Wang J. Ma 《Petroleum Science and Technology》2007,25(10):1305-1311
Catalytic properties of different content of ZnO and P2O5 supported on HZSM-5 zeolites were studied in the conversion of FCC gasoline (75°C-120°C) into aromatic hydrocarbons with a temperature of 430°C, a liquid hourly space velocity of 1.0 hr-1, and a pressure of 0.1 MPa. In the reaction, when the contents of ZnO and P2O5 are 2% and 4%, respectively, Zn-P/HZSM-5 showed the highest selectivity and activity to aromatic hydrocarbons and conversion of olefins. The content of aromatics in the liquid product and the yield of aromatics reached as high as 94.53%, 68.87%, and 51.74%, respectively. 相似文献