制备过程中对VO_2薄膜热致相变光电性能的控制

本文利用真空还原V2 O5的方法制备出优质对VO2 薄膜 ;研究了不同真空还原时间VO2 薄膜热致相变过程中光电性能的影响 ;利用XPS、XRD对薄膜的化学状态和结晶状态进行了研究。制备的薄膜高 /低温电阻变化最大达到三个数量级 ,90 0nm处的光学透过率在相变前后改变了 40 %左右 ,热致相变性能优良。讨论了不同的真空还原时间下VO2 薄膜热滞回线的宽度、相变温度点以及高低温光透射性能。最后给出了最佳真空还原时间。     

大功率CO2混合模激光束传输参数的精确测量

根据大功率 CO2 混合模激光束横截面强度分布的变化规律 ,任选两个横截面的强度分布 ,采用数值迭代方法 ,精确计算出混合模传输的光学参数。     

CSCW中可靠有序的群组通信算法

可靠有序的群组通信是实现计算机支持协同工作基础,文中提出了一个P2P模式下采用UDP协议实现可靠有序的群组通信算法,保证节点发送和接收信息顺序和内容一致,并且提高了节点间通信效率;通过设计节点失败后的恢复算法,确保群组内的节点出现故障后恢复到最近的正确状态,最后以点组内节点协同编辑例证了该算法的有效性.     

TiO_2可见光光催化的研究进展

扩展TiO2催化的响应光谱范围,已成为目前TiO2光催化最具挑战性的课题之一。从TiO2体相掺杂、表面敏化等方面对近年来实现TiO2可见光光催化的途径和方法进行了简要总结。要进一步提高光催化效率还需:深入理解现有TiO2可见光体系的光催化机理;发现更高效的体相掺杂剂和表面敏化剂;设计和控制掺杂剂和表面敏化剂存在形态。     

基于数据共轭重排的修正二维MUSIC算法分析

在阐述二维MUSIC算法基本原理的基础上,通过将接收数据共轭重排的再利用、构造相关矩阵,提出一种基于正交阵列的修正二维MUSIC算法。在快拍次数有限时,此算法可以明显改善信号的波达方向估计性能,特别是相干信号波达方向(DOA)的估计性能,计算机仿真结果证明了该改进算法的有效性和可行性。     

基于神经网络技术的f0F2短期预报方法

利用神经网络技术并考虑太阳和地磁活动对电离层的影响,提出一种提前1h预报电离层临界频率f0F2的方法.网络的输入包括时间、季节、地磁指数、太阳黑子数.太阳射电流量F10.7以及f0F2偏离月中值的一阶和二阶有限差和相对偏差.分别用广州和兰州站的历史数据进行检验,预报结果与观测数据符合得较好,比国际参考电离层更具有实用性.     

半导体混合产品批间控制的理论与实验研究

提出了用一种半导体工业用双产品模型来研究基于机台和基于产品的控制方法.在此基础上,得到了闭环系统的输出,评估了控制性能.由于NH3的挥发类似于半导体工业的机台漂移,因此对纳米级SiO2粒子进行了实验研究.在氨溶液挥发的影响下制造不同大小的SiO2粒子,以模拟在机台干扰下生产不同产品.实验研究证实了理论结果,即基于机台的方法有时不稳定,而基于产品的方法是稳定的.     

（Zn1-xMgx）2SiO4基微波陶瓷的介电性能研究

对(Zn1-xMgx)2SiO4系统的微观结构和微波介电性能进行了研究。通过Mg取代硅锌矿Zn2SiO4中的Zn,用溶胶-凝胶法制得单一晶相的(Zn1-xMgx)2SiO4固溶体微波陶瓷。当Mg取代量超过其在硅锌矿Zn2SiO4中的最大溶解度时,分解为Zn2SiO4相和Mg2SiO4晶相;同时,通过调整x值(x=0.1~0.4,摩尔分数)可获得介电性能优良的微波瓷料。当x=0.2时,在1 170℃烧结,其微波介电性能为:介电常数rε=6.34,品质因数与频率之积Q×f=189 800 GHz(在f=15 GHz下测试的数据),谐振频率温度系数τf≈-62×10-6/℃。     

Ice‐Assisted Synthesis of Black Phosphorus Nanosheets as a Metal‐Free Photocatalyst: 2D/2D Heterostructure for Broadband H2 Evolution

A 2D/2D heterojunction of black phosphorous (BP)/graphitic carbon nitride (g‐C₃N₄) is designed and synthesized for photocatalytic H₂ evolution. The ice‐assisted exfoliation method developed herein for preparing BP nanosheets from bulk BP, leads to high yield of few‐layer BP nanosheets (≈6 layers on average) with large lateral size at reduced duration and power for liquid exfoliation. The combination of BP with g‐C₃N₄ protects BP from oxidation and contributes to enhanced activity both under λ > 420 nm and λ > 475 nm light irradiation and to long‐term stability. The H₂ production rate of BP/g‐C₃N₄ (384.17 µmol g^?1 h^?1) is comparable to, and even surpasses that of the previously reported, precious metal‐loaded photocatalyst under λ > 420 nm light. The efficient charge transfer between BP and g‐C₃N₄ (likely due to formed N? P bonds) and broadened photon absorption (supported both experimentally and theoretically) contribute to the excellent photocatalytic performance. The possible mechanisms of H₂ evolution under various forms of light irradiation is unveiled. This work presents a novel, facile method to prepare 2D nanomaterials and provides a successful paradigm for the design of metal‐free photocatalysts with improved charge‐carrier dynamics for renewable energy conversion.     

On the resilience of P2P botnet footprints in the presence of legitimate P2P traffic

Botnet is a distributed platform for illegal activities severely threaten the security of the Internet. Fortunately, although their complicated nature, bots leave some footprints during the C&C communication that have been utilized by security researchers to design detection mechanisms. Nevertheless, botnet designers are always trying to evade detection systems by leveraging the legitimate P2P protocol as C&C channel or even mimicking legitimate peer‐to‐peer (P2P) behavior. Consequently, detecting P2P botnet in the presence of normal P2P traffic is one of the most challenging issues in network security. However, the resilience of P2P botnet detection systems in the presence of normal P2P traffic is not investigated in most proposed schemes. In this paper, we focused on the footprint as the most essential part of a detection system and presented a taxonomy of footprints utilized in behavioral P2P botnet detection systems. Then, the resilience of mentioned footprints is analyzed using three evaluation scenarios. Our experimental and analytical investigations indicated that the most P2P botnet footprints are not resilient to the presence of legitimate P2P traffic and there is a pressing need to introduce more resilient footprints.