锈蚀钢筋混凝土结构防护与加固

根据锈蚀钢筋混凝土结构破坏的原因与机理 ,对加固工程界热点问题 ,锈蚀结构防护技术 :阴极保护法 ,设计特点、施工方法、应用范围、阴极电流密度、选择阳极材料等问题进行分析与对比 ;锈蚀结构加固技术 :碳纤维布加固 ,论述其技术要领及破坏特点 ,并推出锈蚀结构受弯构件碳纤维布加固的计算公式     

光纤拉丝生产中影响POD的因素

讨论了在光纤拉丝生产过程中，影响内涂层直径（POD）的几个重要因素。     

影响掺矿渣的钢纤维砼强度的主要因素

研究结果表明 :水胶比、胶凝材料用量、钢纤维掺量、矿渣代水泥量对钢纤维砼强度影响显著。当矿渣取代水泥 10 %时 ,钢纤维砼强度最高。经试验选择出一个具有良好和易性和较高强度 (118MPa)的钢纤维砼配合比 ,为掺磨细矿渣的中含量超短异形钢纤维砼的设计和施工提供了试验依据     

MEMS光开关及其与光纤组装方式的研究

光开关是一种在光路中应用极其广泛的光无源器件,可用于扫描、投影、通讯等多种不同的领域,其中用于全光通讯中连接光纤之间的光开关日渐成为人们关注的焦点.高性能、低成本、又能大量生产的MEMS光开关很好地满足了全光网络对器件的要求.本文对这种MEMS光纤光开关的类型、特点以及研究现状进行了介绍,并给出了MEMS光开关与输入输出光纤的组装与自组装以及主要方式.     

钢纤维喷射混凝土作为面板材料的可行性研究

钢纤维混凝土作为一种新型增强材料，以其较好的受力变形特性在水利水电，交通，海岸防护，港口及军事等诸多工程中得到了广泛的应用。针对混凝土面板堆石坝面板的受力变形特点，为改善水布垭面板堆石坝面板的受力条件，提高其防渗能力，同时方便施工，现提出采用钢纤维喷射混凝土作为水布垭面板堆石坝面板材料的新构想，并通过对钢纤维喷射混凝土的物理力学特性及堆石坝面板受力变形进行分析，为钢纤维喷射混凝土在水布垭面板堆石坝面板中的实际应用提出了建议方案。     

碳素材料超声检测的信号处理方法

针对碳素材料超声无损检测存在信噪比较低的问题,从自相关性出发分析了典型超声检测信号的组成成分,提出了在自相关分析的基础上的小波去噪思想,探讨了自相关分析和小波分析相结合的信号处理方法。利用此方法进行实际超声信号分析效果良好。     

Kinetic of CO2 absorption and carbamate formation in aqueous solutions of diethanolamine

The absorption rates of CO₂ into aqueous solutions of Diethanolamine (DEA) with varying concentrations from 0.2 to 4M and temperature range from 293 to 323 K were measured by using a laboratory stirred reactor. The CO₂ partial pressure was varied in a range that the reaction would occur in pseudo first order regime. Experimental data were analyzed and the kinetic parameters associated with the reaction were determined. The activation energy for the deprotonation of the intermediate zwitterion was estimated at about 11.4 kcal/mol. The contribution of carbamate formation to the overall absorbed CO₂ was experimentally evaluated and found to be of the order of 100%.     

Rare earth oxides as carbon oxidation catalysts

The behavior of a number of rare earth oxides as catalysts for the oxidation of graphite in air has been investigated by the methods of thermal analysis. Of the oxides studied, only CeO₂ showed significant activity in accelerating the gasification of graphite by oxygen between 500 and 1000°C. Cerium salts, which decompose to a finely dispersed oxide phase at low temperatures, e.g. Ce (III) nitrate and ammonium Ce (IV) nitrate, were found to be very active catalysts. The catalytic effect may be due to a redox process involving the cyclic conversion of the oxide from the Ce (IV) to the Ce (III) oxidation state, or the oxide particles may provide sites for the dissociative chemisorption of oxygen.     

Reaction scheme and kinetic modelling for the MTO process over a SAPO-18 catalyst

A kinetic model for simulation of the MTO process over SAPO-18 catalyst in a wide range of operating conditions has been proposed. The kinetic model predicts the experimental evolution of reaction products with time on stream, which follows three consecutive periods: initiation (where olefin production increases), a period of maximum olefin production and a period in which this production decreases. The kinetic scheme takes into account these three steps that evolve with time on stream: formation of active intermediate compounds, an step where olefins are formed by reaction of oxygenates (methanol/DME) with these intermediates and deactivation of intermediates by degradation to coke. The presence of water in the reaction medium attenuates the reaction rate of these steps. Discrimination of kinetic equations and calculation of the parameters of best fit have been carried out by solving the mass conservation equations of the individual components of the kinetic scheme together with the kinetic equation for deactivation and taking into account the effect of water on the kinetics of each step.