无机灰分对餐厨沼渣中有机质热解特性的影响

针对餐厨垃圾厌氧处理所产生的沼渣具有产量大、灰分质量分数高的特点,研究沼渣中无机灰分对其热解过程的影响. 通过热重分析和热裂解?气相色谱质谱联用技术（Py-GC/MS）分析沼渣热解动力学特性及其产物. 动力学分析结果表明,沼渣除灰后,失重速率显著提高,热解起始温度由180 ℃降至160 ℃. 除灰沼渣的总表观活化能比沼渣的略高,原因可能是除灰使沼渣内部孔隙增加,在促进挥发分析出的同时,削弱了部分组分在热解过程中的催化裂解作用. 产物分析结果表明,NaCl能够促进油相产物中烃类向酮类的转化,ZnCl₂通过促进酸类的脱羧作用,使烃类质量分数提高至66.8%;Fe₂O₃和Al₂O₃使烃类物质的质量分数分别提高至66.8%和72.7%,CaO和MgO可以促进酸类脱羧生成酮,使产物中酮类的质量分数高达46.5%和39.4%.     

唑螨酯的毒性及研究进展

唑螨酯是一种高效、广谱、非内吸性的苯氧基吡唑类杀螨剂,广泛用于果蔬害螨防治。但近年来因为不合理使用导致残留及安全性问题。笔者综述了唑螨酯的应用、残留、代谢降解及毒性研究进展,以期对后续研究提供参考。     

CCUS in a net-zero U.S. power sector: Policy design,rates, and project finance

Carbon capture utilization and storage is an important technology option to rapidly and profoundly decarbonize the power sector, but will not deploy without substantial incentives or regulation. Assessment of U.S. policy options reveals that current incentives only partially close the finance gap and are most sensitive to fuel type and ownership structure. Recent proposed legislation would in some designs attract private investment for many projects, leading to widespread deployment of CCUS in the power sector. Additional constraints and concerns (including technology options and presence of CO₂ infrastructure) could play an important secondary role. This study discusses the specific US incentive policies that can provide investors and lenders with net cash flows that are adequate to attract private capital to CCUS power projects in the US.     

Environmental and climate justice and technological carbon removal

Environmental justice (EJ) and climate justice are becoming central foci of climate policy. Awareness is also growing on the need for some amount of carbon dioxide removal (CDR) to curb warming to 1.5 °C. In this paper we map dimensions of environmental and climate justice that stakeholders and communities will need to consider -- from local to global scales. Mapping issues is a step towards developing frameworks to undertake CDR in an environmentally just way.     

电弧炉炼钢碳化硅白渣工艺的脱氧与脱硫

理论计算和实践表明，在电弧炉上采用碳化硅代替硅铁粉和碳粉的白渣还原工艺，可强化钢的脱氧和脱硫效果；提高电炉炼钢生产效率；降低吨钢电耗和生产成本。并指出，采用喷吹技术会进一步改善该工艺的炼钢技术经济效果。     

关于炭素厂阴极焙烧车间设计的探讨

根据近年来对国内炭素厂阴极焙烧车间设计中所作的优化和改进,提出了几个以增产、节能、节约投资和便于操作维修为目的的有效措施。     

Effect of laser fluences on the structure of carbon nitride films deposited by direct current plasma assisted pulsed laser ablation

Carbon nitride films were deposited by direct current plasma assisted pulsed laser ablation of a graphite target under a nitrogen atmosphere at room temperature. The surface morphology, composition and bonding structure of the deposited films were characterized by atomic force microscopy (AFM), Fourier transform infrared (FTIR) spectroscopy, Raman, and X-ray photoelectron spectroscopy (XPS). The effect of laser fluences in the range 0.5–3 J/cm² on the surface morphology, composition and bonding structure of the carbon nitride films were systematically studied. As laser fluence is increased, AFM results show a great decrease in the surface roughness of carbon nitride films. FTIR and XPS results indicate an increase in the N/C ratio and the content of N atoms bonded to sp³ C, as well as a decrease in the content of H atoms and the content of N atoms boned to sp² C in the deposited films, and Raman spectra indicate an increase in the content of disordered sp² C atoms and the sp² cluster size. The increase in the film density and the decrease in the particle fraction contribute to the decrease of surface roughness with increasing laser fluence.     

航空发动机积炭清洗剂初探

本文简介了积炭的形成过程及其危害，国内外现有去炭工艺水平，重点分析了有机积炭清洗剂各成份的作用和影响，确定了工艺配方，并对其性能和使用情况作了测试。     

粉煤灰基混凝剂的制备及在大麻废水中的应用

采用酸溶法以粉煤灰为基础原料 ,通过添加一定量的硫铁矿烧渣 ,制备成粉煤灰基复合混凝剂 ,确定了最佳工艺条件 .实验结果表明 ,影响混凝剂制备的主要因素是粉煤灰与硫铁矿渣的质量比、酸用量、浸取时间和温度 .此混凝剂对大麻废水中 CODcr去除率达 88% ,色度去除率可达 96.6%以上 ,具有沉淀快和污泥体积小等优点 .     

Well-dispersed single-walled carbon nanotube/polyaniline composite films

Single-walled carbon nanotube (SWNT)/polyaniline (PANI) composite films with good uniformity and dispersion were prepared by electrochemical polymerization of aniline containing well-dissolved SWNTs. The results of atomic force microscopy (AFM) and UV-Vis adsorption spectroscopy show that aniline can be used to solubilize SWNTs via formation of donor-acceptor complexes. The electrochemical deposition of SWNT-aniline solutions have been investigated by cyclic voltammetry. The results show that SWNT-based aniline solutions exhibit a drastic increase in peak current within the potential scanning region. The doping effect of SWNTs on PANI films was investigated by electrochemistry and FTIR spectroscopy. The results indicate that the enhanced electroactivity and conductivity of the SWNT/PANI composite films may be due to the strong interaction between SWNTs and PANI, which facilitates the effective degree of electron delocalization.