焦炉装煤烟尘治理的烟气量计算

通过对焦炉装煤烟尘治理的烟气量计算和研究,提出不同治理系统的烟气量计算方法及应采取的措施。     

Electrochemical improvement of low-temperature petroleum cokes by chemical oxidation with H2O2 for their use as anodes in lithium ion batteries

The electrochemical performance of non-graphitized petroleum cokes has been improved by mild oxidation using hydrogen peroxide, a procedure used for the first time in these materials. For this purpose, various carbonisation temperatures and H₂O₂ treatments were tested. For low sulfur content cokes, the aqueous oxidative treatment significantly increases the capacity values above 372 mAh/g during the first cycles. In contrast, cokes with a sulfur content of ca. 5%, did not shown a real improvement. The former results have been interpreted in terms of an effective oxidation of the particles surface, which removes unorganized carbon, where lithium can be irreversibly trapped. Moreover, a stable and less resistive passivating layer grows during the first discharge of lithium, as revealed by impedance spectroscopy. Therefore, chemical procedures, as mild oxidation, open an interesting field of research for the improvement of disordered carbons as anode materials in lithium ion batteries.     

Deposition and characterization of alumina films produced by combustion flame pyrolysis

Alumina coatings have been deposited by combustion flame pyrolysis on amorphous silica and stainless steel substrates with the objective to study the effect of solvent composition, Fe³⁺ addition and determine the thermal fatigue lifetime. The effect of solvent composition on crystallinity, transformation temperature and hardness are studied, three different solvent compositions are chosen for preparing the aluminium nitrate solution. Using 100% water, as-deposited films are amorphous and transform to α-alumina only upon annealing, while this equilibrium phase is directly obtained but with a porous microstructure by using 100% methanol. The hardness of the coatings varies with the flammability of the solvents. The effect of Fe³⁺ addition on the crystallization of alumina is studied by combustion pyrolysis of aqueous solutions of Al³⁺ and Fe³⁺ nitrates. Small amount of ferric nitrate reduced the transformation temperature by 100 °C. Thermal cycling of as-deposited amorphous alumina on stainless steel substrate is carried out at different temperatures to determine the thermal fatigue lifetime.     

第三代伞状喷雾的分布特性及多片喷雾系统的应用研究

为解决前两代伞状喷雾在高背压下贯穿距不足的问题,借鉴碰撞喷雾方式,提出了第三代伞状喷雾概念。通过高速摄影对喷雾的分布特性进行了研究,结果表明:喷雾具有贯穿距可设定、扩散度高、空间分布均匀等特点。为避免碰撞后二次油束雾线相互干涉,又提出了一种多片喷雾概念,并在单缸四气门135柴油机上对多片喷雾燃烧系统进行了初步的性能试验,结果显示:系统能够有效地促进缸内均质混合气的形成;在供油提前角为19°CA时,全负荷范围内柴油机的油耗和碳烟排放均较低。     

Near-wall porosity characteristics of fixed beds packed with wood chips

Packed beds of fuel wood chips are commonly found in thermal conversion processes such as combustion or gasification. Wood chips in particular are mostly used as fuel for small-scale domestic heating boilers but also for commercial-scale combustion units. The characterization of spatial voidage distribution inside the wood chip beds is of great importance for flow and reactor modelling. This study focuses on the radial porosity variations of cylindrical beds of three different types of commercially available wood chips including chips classified as G30 size class. The conventional technique of consolidating packed beds with a resin was chosen as the experimental procedure. The radial voidage distribution in different cylindrical beds is determined by image analysis of sections of the solidified packings. Additionally, a packing of monosized spheres was investigated in order to assess the selected procedure in comparison with widely available literature data for spheres. The results are discussed and summarized in a mathematical expression correlating the radial voidage distribution depending on average wood chip size, packing core porosity and dimensionless distance from the tube wall.     

燃料变化对气体燃烧器燃烧性能影响的数值模拟研究

该文以John Zink公司一种瓦斯燃烧器为几何原型,对燃烧器和稳焰旋流器附近三维复杂形状未作任何简化,生成了包括燃烧器和炉膛的结构化网格,换用甲烷、乙烷、丙烷和丁烷四种不同的气体燃料,用标准的k-ε湍流模型、k-ε-g湍流扩散燃烧模型和蒙特卡洛辐射换热模型对燃烧器内的流动及燃烧状况进行了全尺寸数值模拟,预报了燃烧器内流场和温度场,考察燃料变化对炉内温度场的影响规律及燃气射流特性参数(Re·D1)对火焰长度的影响,对进一步优化设计燃烧器、提高加热炉热效率有很好的指导意义。     

基于虚拟测试技术的柴油机燃烧分析系统

运用虚拟仪器技术,开发了一种柴油机燃烧分析仪。该分析仪由高速数据采集卡及自行开发的控制软件组成。本文介绍了此分析系统的软件开发方法,并探讨了上止点的修正、示功图的光顺处理等问题。     

材料合成新技术──自蔓延高温合成

自蔓延高温合成（ＳＨＳ）是目前被广泛开发用于工业陶瓷和其它先进材料制备的一种独特的先进工艺技术。本文对生产高科技材料的自蔓延高温合成技术方法进行了介绍，并分析了该工艺的特点及其理论基础，同时还讨论了影响材料合成的因素。     

高压氮气中自蔓延燃烧合成氮化钛

利用钛粉在高压氮气中的自蔓延燃烧合成（ＳＨＳ），制备了含氮量较高的ＴｉＮ，研究了反应物的松装密度、氮气压的改变与稀释剂的加入对燃烧波蔓延速率和产物转化率的影响，还观察到燃烧方式的改变。     

Sulfur distribution in coke and sulfur removal during pyrolysis

In order to investigate the mechanisms of coke desulfurization by blowing additional gas into coking chamber during pyrolysis process, some experiments were conducted to study the effects of some factors on the distribution of sulfur in coke. These factors include pyrolysis temperatures, the kinds of the blowing gases and the diameters of coking chamber. It was found that sulfur was mainly released at the range of 300–600 °C. Under this temperature range, the sulfur content in coke can be reduced by 0.05–0.06% by blowing N₂, CO or CH₄, and by 0.14% by blowing H₂ at a space velocity of 1.2 mm/s compared with the absolute sulfur content of 0.92% in the case without gas feeding. Obviously, H₂ is more effective on sulfur removal than N₂, CO or CH₄. The total, organic and inorganic sulfur contents in coke increase with increasing the diameter of coking chamber under identical pyrolysis conditions. Both organic and inorganic sulfur contents in coke increase regularly from the center to brim at identical height of a coke column for all the cases. In addition, the organic and inorganic sulfur contents at the cranny surface are higher than those in interior at the same sampling position. X-ray photoelectron spectroscopy (XPS) analyses suggest that the main contributions to the increase of inorganic and organic sulfur contents are due to the formation of negative bivalent sulfur and thiophenic compounds, respectively.