轧后穿水冷却工艺对棒材组织性能的影响

针对轧机产量提高后冷床冷却能力不足的问题 ,研制开发了棒材轧后穿水冷却技术。通过对小规格 2 0MnSiV热轧带肋钢筋进行轧后穿水冷却 ,钢材上冷床温度降低了 90～ 110℃ ,提高了产品质量 ,改善了各项力学性能 ,抗拉强度平均提高了 3 5～ 40MPa ,钢材性能合格率由 97.5 %提高到了 99.6% ,解决了冷床冷却能力不足、制约生产的瓶颈问题。     

A new method for the determination of wax precipitation from non-diluted crude oils by fractional precipitation

Wax precipitation is one of the most important flow assurance problems. Unfortunately, experimental data are very scarce to confirm existing models for prediction of such precipitation problem. This work reports a new experimental method. Multistage fractional wax precipitation was carried out by decreasing the temperature of crude oil. No solvent dilution was used, so the effect of solvent on temperature wax precipitation was avoided. The reproducibility of the method was tested with comparable results. The precipitation curve and the wax appearance temperature were obtained for two crude oils with different chemical nature using the reported method.     

Effect of high temperature alkali cooking on the constituents,structure and thermal degradation of hemp fiber

Degumming of hemp fiber by high temperature alkali cooking was investigated, and the effect of temperature and dosage of alkali on the constituents, structure, and thermal degradation of hemp fiber was also discussed in this work. The morphology, structure, and thermal degradation of hemp fiber after high temperature cooking were investigated through SEM, FTIR, WAXD, and TG analysis. The results indicated that the high temperature cooking process was effective for removing hemicelluloses and lignin and could also improve the thermal stability of cellulose. Crystallinity index of the treated hemp fiber was increased, which was related to the cooking temperature and NaOH dosage. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Functional copolymer of geraniol and acrylonitrile: Synthesis and characterization

The radical copolymerization of acyclic terpene namely geraniol [GER] with acrylonitrile [AN] in DMF at (70 ± 0.1)°C for 1 h, using benzoylperoxide (BPO) as an initiator has been carried out under inert atmosphere of nitrogen. The kinetic expression for reaction is R_p ∝ [BPO]^0.5 [AN]^1.0 [GER]^1.0. The IR spectrum of the copolymer shows bands at 3432 and at 2244 cm^?1 due to ? OH group of GER and ? CN group of AN, respectively. The ¹³C‐NMR spectrum shows peaks at 73–75 δ ppm and 116–120 δ ppm due to ? OH group of GER and ? CN group of AN, respectively. The thermogravimetric analysis and differential scanning calorimetry study shows that copolymer is thermally stable up to 407°C and has glass transition temperatures (T_g) 56°C. The reactivity ratios r₁ (AN) and r₂ (GER) have been calculated as 0.05 and 0.005, respectively. The Alfrey‐Price Q‐e parameter for GER has been calculated as 0.094 and ?2.0, respectively. The molecular weights of the copolymers have been evaluated by gel‐permeation chromatography. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

两种含水炸药动压下减敏作用的实验研究

用实验方法对两种含水炸药—水胶炸药和珍珠岩敏化的乳化炸药动压下的减敏作用进行了研究。为了更全面深入地研究这问题,提出了临界压死距离和临界距离两个概念。研究表明,含水炸药的减敏作用与药包间距和延期时差关系很大。水胶炸药的临界压死距离大于乳化炸药,而它们的临界距离相当,这表明两种炸药发生减敏的难易程度相近,但是乳化炸药的抗压死能力比水胶炸药大。采用5段延期电雷管引爆时两种含水炸药的减敏作用比采用2段延期电雷管引爆严重些。     

转炉脱磷效果影响因素分析

从氧气顶吹转炉脱磷的热力学分析入手,探讨了冶炼过程中温度、炉渣碱度、(FeO)对磷含量的影响,回磷的原因、影响因素及防止措施等,指出应控制炉渣碱度、终点温度、(FeO)在合理范围内,应重视钢水回磷问题。     

碳铬镍含量对高铬铸铁测温保护管性能的影响

通过高温氧化和高温磨损实验,研究了C、Cr、Ni 3个主要元素对高铬铸铁在高温条件下抗氧化和抗磨损性能的影响。结果表明:Cr含量越高,抗氧化性能和抗磨损性能越好;提高碳含量,明显提高高铬铸铁的高温抗磨性能;当w(Cr)=16％时,加入Ni能提高高铬铸铁的高温抗氧化性能;w(Cr)=30％时,Ni对高铬铸铁的抗氧化性能和抗磨损性能影响不明显.在1100℃以下,选用w(C)=2.8％,w(Cr)=30％、不加Ni的高铬铸铁铸造高温抗磨热电偶保护管,既有较好的使用寿命,又可降低成本.     

转炉入炉铁水温度低的原因分析及其对炼钢的影响

系统分析了新钢公司一钢厂转炉入炉铁水温度低的原因及铁水温度对炼钢的影响，提出了提高铁水温度的措施及转炉应对低温铁水的办法。     

CRITICAL POINTS IN THE SOLIDIFICATION OF A PURE MATERIAL

Patterns in the solidification of a pure material are dealt with in this article. Results, deduced from a simple model based on heat conduction in the two phases and the effect of surface tension on the equilibrium temperature at the moving front, present a guide for experimental work. By introducing far-field conditions imitating what can be achieved in an experiment, we explain how the depths of the phases and the width of the container influence the patterns that can be seen if one advances the control variable to the critical point and then just beyond. Our new result is the existence of a third critical point. It occurs at small wave numbers and it is independent of surface tension. It appears because we take the depths of the phases into account. These depths are input values that offer the possibility of controlling crest-to-trough conduction, stabilizing in the solid, destabilizing in the liquid. The new critical point, and the patterns attending its appearance, can be found in cells of easily attainable widths.     

Cu-Cr合金高温氧化行为分析

该文用热分析天平，结合金相、X射线衍射(XRD)、扫描电镜(SEM)和能谱(EXD)研究了Cu—Cr合金在不同温度下的氧化行为。结果表明，Cu—Cr合金在700℃-900℃氧化符合抛物线规律，其最外层氧化膜为CuO，内层为Cu2O和Cr2O3，铬有助于提高合金的抗氧化能力。